1,1,2,3,3-pentafluoro-3-(heptafluoropropoxy)prop-1-ene

Flammability

Administrative data

Endpoint:

flammable liquids: obsolete as covered by section 'Flash point'

Data waiving:

study scientifically not necessary / other information available

Justification for data waiving:

the study does not need to be conducted because the substance is a liquid

Cross-reference

Cross-reference 1

Reason / purpose for cross-reference:

data waiving: supporting information

Reference

Endpoint:

flash point of flammable liquids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

05 Oct 2018

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Qualifier:

according to guideline

Guideline:

ASTM D93 (Standard test methods for flash point by pensky-martens closed cup tester)

Deviations:

no

Qualifier:

according to guideline

Guideline:

EU Method A.9 (Flash-Point)

Deviations:

no

GLP compliance:

no

Type of method:

closed cup

Flash point apparatus:

Pensky-Martens apparatus

Key result

Atm. press.:

990 hPa

Remarks on result:

other: Did not flash prior to boilingat 58 °C, however, flame enlargement and a color change of the flame were observed.

 Flame enlarged and flickered with a turquoise hue and promptly extinguished upon pilot flame application. This was first observed at 22°C. Boiled at 58°C.

Interpretation of results:

GHS criteria not met

Conclusions:

MA-3 did not flash prior to boiling at 58 °C by Penksy-Martens closed cup test (EU method A.9). Flame enhancement was observed.

Executive summary:

No flash-point could be determined using the Pensky-Martens closed cup method. Flame enlarged and flickered with a turquoise hue and promptly extinguished upon pilot flame application at 22 °C. The study was conducted in accordance with EU method A.9; therefore the study is considered reliable without restrictions and is suitable for Classification & Labeling and Risk Assessment.

Cross-reference 2

Reason / purpose for cross-reference:

data waiving: supporting information

Reference

Endpoint:

auto-ignition temperature (liquids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

02 - 18 Oct 2018

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Qualifier:

according to guideline

Guideline:

EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))

Deviations:

no

Qualifier:

according to guideline

Guideline:

DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)

Deviations:

no

GLP compliance:

yes

Specific details on test material used for the study:

SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: MA-3-HO-ANL 1600356
- Expiration date of the lot/batch: 31 Aug 2020
- Purity test date: 05 Feb 2018
- Purity: 96.9%

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: At room temperature container flushed with nitrogen
- Stability under test conditions: Yes

Key result

Auto-ignition temperature:

605 °C

Atm. press.:

1 014 hPa

Conclusions:

The autoignition temperature of MA-3 is 605 °C at 1014 hPa, EU method A.15

Executive summary:

The lowest observed autoignition temperature was 609 °C. This value was rounded down to 605 °C per guideline. The study was conducted in accordance with EU Method A.15 and was GLP compliant, therefore the study is considered reliable without restrictions.