Registration Dossier

Administrative data

First-aid measures

If inhaled:
If breathed in, move person into fresh air.
If symptoms persist, call a physician.

In case of skin contact:
Take off contaminated clothing and shoes immediately.
Consult a physician. Wash off immediately with plenty of water.
Wash contaminated clothing before reuse


In case of eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses.
Consult a physician.

If swallowed:
If swallowed, rinse mouth with water (only if the person is conscious).
Call a physician immediately.

Most important symptoms and effects, both acute and delayed
Irritating to eyes.
Irritating to skin.
Sensitisation

Indication of any immediate medical attention and special treatment needed: Treat symtomatically.

Fire-fighting measures

Suitable extinguishing media:
Water mist
Dry powder
Foam
Carbon dioxide (CO2)
Sand
Aqueous film forming foam (AFFF).

Unsuitable extinguishing media: Water spray jet

Special hazards arising from the substance or mixture
Hazardous combustion products: Fluorine compounds Carbon oxides.

Advice for firefighters:
Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus.
Further information: In the event of fire, cool tanks with water spray.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions: Evacuate personnel to safe areas. Keep away from open flames, hot surfaces and sources of ignition. Ensure adequate ventilation

Environmental precautions: Should not be released into the environment. Do not flush into surface water or sanitary sewer system.

Methods for cleaning up:
Large spills: Dam up. Soak up with inert absorbent material. Keep in properly labelled containers.
Small spills: Gently cover the spill with an absorbent towel or pad.
Large spills + Small spills: Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".

Handling and storage

Precautions for safe handling:
Advice on safe handling :To avoid thermal decomposition, do not overheat.
Use personal protective equipment as required.
Avoid inhalation, ingestion and contact with skin and eyes.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.

Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers: To maintain product quality, do not store in heat or direct sunlight. Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store at room temperature.

Recommended storage temperature: 15 - 25 °C

Transport information

Land transport (ADR/RID)

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1benzopyran.)
Chemical name:
((+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1benzopyran.
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
Special Provisions:
Special Provision 375: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the ADR/RID/ADN/IMDG/IATA DGR provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Inland waterway transport (ADN(R))

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1benzopyran.)
Chemical name:
((+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1benzopyran.)
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
Remarks
Special Provision 375: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the ADR/RID/ADN/IMDG/IATA DGR provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Marine transport (IMDG)

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran.)
Chemical name:
(+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarks
2.10.2.7: Environmentally Hazardous Substances/Marine Pollutants, classified under UN 3077 or UN 3082, packaged in single or combination packagings containing a net quantity per single of inner packaging of 5L or less for liquids or having a net mass per single of inner packaging of 5kg or less for solids are not subject to the IMDG provided the packagings meet the general requirements of 4.1.1.1, 4.1.1.2, and 4.1.1.4 to 4.1.1.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Air transport ICAO/IATA

UN number:
UN 3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran.)
Chemical name:
(+)-[S-(R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran
Class:
9
Packaging group:
III
Labels:
9
Remarks
Packing instruction (passenger aircraft): 964
Packing instruction (LQ) : Y964
Special Provision A197: Environmentally hazardous substances, classified under UN 3077 or UN 3082, when transported in single or combination packagings containing a net quantity per single or inner packaging of 5 L or less for liquids or having a net mass of 5 kg or less for solids, are not subject to any other provisions of the IATA DGR provided the packagings meet the general provisions of IATA DGR 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8., This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of IATA DGR §2.6.10 are met.

Additional transport information

Additional transport information
ADN Environmentally hazardous : yes
ADR Environmentally hazardous : yes
RID Environmentally hazardous : yes
IMDG Marine pollutant : yes
IATA (Passenger) Marine pollutant : yes

Exposure controls / personal protection

Engineering measures
All personal protective equipment should be based on a risk assessment. Consult a Environment Health Safety expert if necessary. Engineering controls should be used as the primary means to control possible exposures. Use process enclosures, local exhaust ventilation or other engineering controls to keep exposure levels below recommended exposure limits.

Personal protective equipment:
Eye protection: Tightly fitting safety goggles

Hand protection material : Nitrile rubber
Remarks: Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Impervious gloves.

Skin and body protection : closed work clothing chemical resistant apron, coat or coverall

Respiratory protection : Engineering controls should always be the primary method of controlling exposures. If respiratory protective equipment is needed for certain activities, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present. Use only respiratory protection that conforms to international/ national standards. Respirator with a vapour filter ABEK

Protective measures : The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Stability and reactivity

Reactivity: None reasonably foreseeable.

Chemical stability: Stable under recommended storage conditions.

Possibility of hazardous reactions
Hazardous reactions: No dangerous reaction known under conditions of normal use.

Conditions to avoid: To avoid thermal decomposition, do not overheat. Heat, flames and sparks.

IMaterials to avoid: Strong oxidizing agents

Hazardous decomposition products: Carbon oxides, Fluorocarbons

Disposal considerations

Product : Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. In accordance with National, Federal, State and Local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.