Registration Dossier
Registration Dossier
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EC number: 232-167-2 | CAS number: 7789-45-9
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
- Inhalation : Assure fresh air breathing. Consult a physician.
- Skin contact : Wash off with plenty of water. + Polyethylene glycol 400 Remove immediately
soaked or soiled clothing. Call a physician immediately.
- Eye contact : Wash off with plenty of water. Consult an ophthalmologist immediately.
- Ingestion : Drink two glasses of water. Avoid : Vomiting -> Danger of perforation of esophagus.
Call a physician immediately. Avoid attempts of neutralization.
4.2. Most important symptoms and effects, both acute and delayed
Irritation. Corrosion. Irritating effect. Cough. Shortness of breath. Danger of loss of vision.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.
Fire-fighting measures
5.1. Extinguishing media
- Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
- Unsuitable extinguishing media : None.
5.2. Special hazards arising from the substance or mixture
Not combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.
In the event of fire the following can be released : Hydrobromic acid.
5.3. Advice for fire-fighters
Special protective equipment for firefighting :
Do not stay in dangerous zone without self-contained breathing apparatus. Wear suitable protective clothing.
Other data :
Knock down dust cloud with water spray.
Don't allow extinguishing water to enter surface and subsoil waters.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : For personal safety, see § 8.
For non-emergency personnel : Avoid contact with the product. Avoid breathing dust. Ensure adequate ventilation.
Evacuate area. Observe emergency procedures. Consult a physician.
6.2. Environmental precautions
Do not allow product to reach sewage system.
6.3. Methods and material for containment and cleaning up
Cover drains. Collect, bind and pump the spilled material.
Observe any restrictions on materials (see Section 7.2 and 10.5).
Take up dry. Forward for disposal. Clean. Avoid dust formation.
6.4. Reference to other sections
See Section 13 for information on disposal.
Handling and storage
7.1. Precautions for safe handling
Observe precautions stated on label.
7.2. Conditions for safe storage, including any incompatibilities
Keep container tightly closed. Keep container dry.
Storage temperature : +15 °C - +25 °C
7.3. Specific end use(s)
See Heading 1. . 2
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1759
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1759
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1759
Shipping information
- Proper shipping name and description:
- CORROSIVE SOLID, N.O.S. Copper bromide
CORROSIVE SOLID, N.O.S. (Copper bromide)
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1759
Shipping information
- Proper shipping name and description:
- CORROSIVE SOLID, N.O.S. Copper bromide
CORROSIVE SOLID, N.O.S. (Copper bromide)
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- 14.5. Environmental hazards:
Yes.
Exposure controls / personal protection
8.1. Control parameters
Contains no substances with occupational exposure limits.
8.2. Exposure controls
Personal protection : Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier.
- Respiratory protection : Required when dusts are generated. Recommended filter device : P2
The Contractor shall ensure that maintenance, cleaning and control of respiratory protective devices are applied according to manufacturer's instructions. These measures must be properly documented.
- Skin protection : Protective clothing.
- Eye protection : Tightly fitting safety goggles.
- Hand protection :
Direct contact : Material of gloves : Nitrile rubber.
Layer thickness of gloves: 0.11 mm
Break through time : > 480 min
Splashing : Material of gloves : Nitrile rubber.
Layer thickness of gloves: 0.11 mm
Break through time : > 480 min
Protective gloves used must meet the specifications of EC directive 89/686/EEC and the resultant standard EN374, for example KCL 741 Dermatril ® (full contact), KCL 741 Dermatril ® L (splash contact).
The breakthrough times stated above were determined by KCL in laboratory measurements according to EN 374 on samples of materials for the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet that we provide and only for the purpose specified. When dissolving in or mixing with other substances and / or conditions different from those of EN 374, contact the supplier of CE-approved gloves (eg KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Hygiene measures : Take off immediately all contaminated clothing. Preventive skin protection. Wash hands and face thoroughly after handling.
Environmental exposure controls : Do not allow product to reach sewage system.
Technical measures : Favor the use of engineering and operations over the appropriate use of personal protective equipment.
See Heading 7. 1
Stability and reactivity
10.1. Reactivity
Corrosive effects.
10.2. Chemical stability
Stable at normal storage temperature.
10.3. Possibility of hazardous reactions
Violent reaction with Alkali metals.
10.4. Conditions to avoid
No data available.
10.5. Incompatible materials
No data available.
10.6. Hazardous decomposition products
In case of fire: See Heading 5.
Disposal considerations
13.1. Waste treatment methods
Dispose in a safe manner in accordance with local/national regulations.
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste
Keep in original containers.
No mixing with other waste.
Packaging that cannot be cleaned should be disposed of as for product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
