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Physical & Chemical properties

Auto flammability

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Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature, other
Remarks:
semi-solid (amorphous) gel tested according to Eu Method A.15
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016-12-09 (Study Plan Verification) - 2017-06-28 (final report)
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
version 2008-05-30
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Auto-ignition temperature:
>= 365 - <= 375 °C
Atm. press.:
>= 101 - <= 102.3 kPa

Results

Results of the auto-ignition temperature determination are shown in the following table:

Table 2

Test temperature (°C)

Test weight (g)

Ignition delay (s)

Observations

200 (clean flask)

0.2

>300

No ignition. No fumes emitted.

250 (clean flask)

0.2

>300

No ignition. Grey fumes were emitted.

300 (clean flask)

0.2

>300

No ignition. Grey fumes were emitted.

350

0.2

>300

No ignition. Grey fumes were emitted.

400

0.2

>300

No ignition. Grey fumes were emitted.

450

0.2

9

A red/orange flame. Grey fumes were emitted.

440

0.2

17

A red/orange flame. Grey fumes were emitted.

430

0.2

13

A red/orange flame. Grey fumes were emitted.

420

0.2

20

A red/orange flame. Grey fumes were emitted.

410 (clean flask)

0.2

17

A red/orange flame. Grey fumes were emitted.

400 (clean flask)

0.2

47

A red/orange flame. Grey fumes were emitted.

390 (clean flask)

0.2

>300

No ignition. Grey fumes were emitted.

396

0.2

>300

No ignition. Grey fumes were emitted.

398

0.2

>300

No ignition. Grey fumes were emitted.

398 (clean flask)

0.2

85

A yellow/orange flame. Grey fumes were emitted.

396 (clean flask)

0.2

81

A yellow/orange flame. Grey fumes were emitted.

394 (clean flask)

0.2

81

A yellow/orange flame. Grey fumes were emitted.

392 (clean flask)

0.2

20

A yellow/orange flame. Grey fumes were emitted.

390 (clean flask)

0.2

>300

No ignition. Grey fumes were emitted.

390 (clean flask)

0.4

24

An orange/yellow flame. Grey fumes were emitted.

388 (clean flask)

0.4

>300

No ignition. Grey fumes were emitted.

388 (clean flask)

0.6

23

An orange/yellow flame. Grey fumes were emitted.

386 (clean flask)

0.6

>300

No ignition. Grey fumes were emitted.

386 (clean flask)

0.8

28

A yellow flame. Grey fumes were emitted.

384 (clean flask)

0.8

>300

No ignition. Grey fumes were emitted.

384 (clean flask)

1.0

115

A yellow flame. Grey fumes were emitted.

382 (clean flask)

1.0

139

A yellow flame. Grey fumes were emitted.

380 (clean flask)

1.0

>300

No ignition. Grey fumes were emitted.

380 (clean flask)

1.2

129

A yellow flame. Grey fumes were emitted.

378 (clean flask)

1.2

>300

No ignition. Grey fumes were emitted.

378 (clean flask)

1.4

>300

No ignition. Grey fumes were emitted.

378 (clean flask)

1.6

30

A yellow flame. Grey fumes were emitted.

376 (clean flask)

1.6

>300

No ignition. Grey fumes were emitted.

376 (clean flask)

1.8

222

A yellow flame. Grey fumes were emitted.

374 (clean flask)

1.8

151

A yellow flame. Grey fumes were emitted.

372 (clean flask)

1.8

162

A yellow flame. Grey fumes were emitted.

370 (clean flask)

1.8

>300

No ignition. Grey fumes were emitted.

370 (clean flask)

2.0

>300

No ignition. Grey fumes were emitted.

370 (clean flask)

2.2

234

A yellow flame. Grey fumes were emitted.

368 (clean flask)

2.2

>300

No ignition. Grey fumes were emitted.

368 (clean flask)

2.4

>300

No ignition. Grey fumes were emitted.

368 (clean flask)

2.6

>300

No ignition. Grey fumes were emitted.

368 (clean flask)

2.8

>300

No ignition. Grey fumes were emitted.

368 (clean flask)

3.0

>300

No ignition. Grey fumes were emitted.

Room temperature: 18 to 22 °C

Atmospheric pressure: 101.0 to 102.3 kPa

Conclusion

The test item has been determined to have an auto-ignition temperature of 370 ± 5 °C.

Conclusions:
Conclusion: The test item has been determined to have an auto-ignition temperature of 370 ± 5 °C.
Executive summary:

Auto-Ignition Temperature (Liquids and Gases). 370 ± 5 °C, using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Description of key information

Auto-Ignition Temperature (Liquids and Gases). 370 ± 5 °C, using a procedure designed to be compatible with Method A.15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
370 °C

Additional information