Registration Dossier

Diss Factsheets

Administrative data

Endpoint:
flammable liquids: obsolete as covered by section 'Flash point'
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is a liquid
Cross-referenceopen allclose all
Reason / purpose for cross-reference:
data waiving: supporting information
Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
24 May 2005
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ASTM D93 (Standard test methods for flash point by pensky-martens closed cup tester)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Deviations:
no
GLP compliance:
yes
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: PDC Lot 1, Pail 2
- Expiration date of the lot/batch: 23 Mar 2006
- Purity: 99.959%
- Synonyms: MTDID 665
STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: room temperature in the dark
Key result
Atm. press.:
102.1 kPa
Remarks on result:
no flash point - measurement carried out until boiling temperature
Remarks:
sample boiled at 97 °C

Boiling was confirmed visually.

Interpretation of results:
GHS criteria not met
Conclusions:
HFE s-601 has no flash point below its boiling temperature or 97 °C by Pensky-Martens closed cup test (EU method A.9).
Executive summary:

No flash-point could be determined using the Pensky-Martens closed cup method. No flammable vapour/air mixture was produced in the test vessel at temperatures below boiling, which was observed visually at 97 °C, 102.1 kPa. The study was conducted in accordance with EU method A.9 and was GLP compliant; therefore the study is considered reliable without restrictions and is suitable for Classification & Labeling and Risk Assessment.

Reason / purpose for cross-reference:
data waiving: supporting information
Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
30 May - 02 Jun 2005
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
GLP compliance:
yes
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: PDC Lot 1, Pail 2
- Expiration date of the lot/batch: 23 Mar 2006
- Purity: 99.959%
- Synonyms: MTDID 665
STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: room temperature in the dark
Key result
Auto-ignition temperature:
400 °C
Atm. press.:
101.66 kPa

Summary autoignition test results from three trials in the main test

Test number (atm pressure)

Test volume (µL)

Autoignition temperature (°C)

Time lag (s)

Test 1

70

418

15

(102.41 kPa)

125

410

24

 

250

418

23

Test 2

70

420

16

(102.48 kPa)

150

412

33

 

250

416

25

Test 3

50

418

12

(101.66 kPa)

140

411

24

 

250

404

22

 

300

407

19

Conclusions:
The autoignition temperature of HFE s-601 is 400 °C (EU A.15)
Executive summary:

In a test of HFE s-601 done per EU test method A.15 and DIN 51794, the lowest observed autoignition temperature was 404 °C. This value was rounded down to 400 °C per DIN 51794 practice. The study was conducted in accordance with accepted guidelines and was GLP compliant; therefore the study is considered reliable without restrictions.

Data source

Materials and methods

Results and discussion

Applicant's summary and conclusion