Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.


4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible


4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
dry powder, foam, water spray, carbon dioxide

5.2. Special hazards arising from the substance or mixture
hydrogen cyanide; hydrocyanic acid, acrylonitrile
The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions
Do not empty into drains.

6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
For large amounts: Dike spillage. Pump off product.
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Refill and handle product only in closed system. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion:
The product is combustible. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Temperature class: T2 (Autoignition temperature >300 °C).

7.2. Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place. Avoid direct sunlight.

Storage class according to TRGS 510 (originally VCI, Germany): (10) Combustible liquids

Storage stability:
Storage duration: 36 Months
Store at ambient temperature.
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

Protect from temperatures above: 30 °C
Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

The surveillance of the workplace by exposure measurements may be necessary, in order to proof the efficiency of safety measures, for example ventilation or the need of respiratory protection. Since this requires a specific competency, only accredited laboratories should be contracted.

124-40-3: di-methylamine (Content (W/W): <= 50 PPM)
TWA value 3,8 mg/m3 ; 2 ppm (OEL (EU))
indicative
STEL value 9,4 mg/m3 ; 5 ppm (OEL (EU))
indicative
OEL 3,7 mg/m3 ; 2 ppm (TRGS 900 (DE))
Ceiling limit value/factor: 2
The reaction with nitrosifying agents can lead to the formation of the respective carcinogenic N-Nitrosamines.
Short Term Exposure Classification: (TRGS 900 (DE))
Category I: Substances for which the localized effect has an assigned exposure limit or for substances with a sensitizing effect in respiratory passages
107-13-1: acrylonitrile (Content (W/W): <= 50 PPM)
Tolerance Concentration (risk 4:1000): 2,6 mg/m3 ; 1,2 ppm (TRGS 910)
Excursion factor (TRGS 910)
Ceiling limit value/factor: 8
Factor by which the average shift value (SMW) can be exceeded four times per shift during a maximum. period of 15 minutes each.
Acceptance concentration (risk 4:10000): 0,26 mg/m3 ; 0,12 ppm (TRGS 910)
Skin Designation (TRGS 910)
The substance can be absorbed through the skin.

PNEC
freshwater: 0,0519 mg/l

marine water: 0,00519 mg/l

intermittent release: 0,519 mg/l

sediment (freshwater): 32,5 mg/kg

sediment (marine water): 3,25 mg/kg

STP: 9,0 mg/l

No PNEC oral derived, as accumulation in organisms is not to be expected.

soil: 6,45 mg/kg


8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Take off immediately all contaminated clothing. Store work clothing separately.

Stability and reactivity

10.1. Reactivity
Strong exothermic reaction with acids.


Corrosion to metals:
Corrosive effects to metal are not anticipated.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.


10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions
Reacts with strong acids. Evolution of heat under influence of acids. Decomposes upon heating and/or on contact with acids.
The product is stable if stored and handled as prescribed/indicated.

10.4. Conditions to avoid
Avoid heat. Avoid direct sunlight.

10.5. Incompatible materials

Substances to avoid:
acids

10.6. Hazardous decomposition products

Possible decomposition products:
hydrogen cyanide; hydrocyanic acid, acrylonitrile

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.


Contaminated packaging:
Packs that cannot be cleaned should be disposed of in the same manner as the contents.

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.