Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures
General information
In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth, place in recovery position and seek medical advice.
In case of inhalation
Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial respiration. In case of respiratory tract irritation, consult a physician.
Following skin contact
Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do not use solvents or thinners. In case of skin irritation, consult a physician.
After eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice immediately.
After ingestion
Rinse mouth immediately and drink plenty of water. Seek medical advice immediately. Keep victim calm. Do NOT induce vomiting.
Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
Alcohol resistant foam, carbon dioxide, powder, spray mist, (water), sand.
Extinguishing media which must not be used for safety reasons:
strong water jet
Special hazards arising from the substance or mixture:
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
Advice for firefighters
In case of fire: Wear self-contained breathing apparatus, Full protection suit. Cool closed containers that are near the source of the fire. Do not allow water used to extinguish fire to enter drains, ground or waterways.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Ventilate affected area. Do not breathe vapours. Special danger of slipping by leaking/spilling product. See protective
measures in section "Handling and storage" as well as "Expsoure controls/personal protection".
Environmental precautions:
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent authorities in accordance with local regulations.
Methods and material for containment and cleaning up:
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations. Clean using cleansing agents. Do not use solvents.

Handling and storage

Precautions for safe handling
Advices on safe handling
Avoid contact with skin, eyes and clothes. When using do not eat, drink or smoke. Advice on personal protection is given in section "Exposure controlös/personal protection"
Personal protection equipment as recommended in section pesronal protection.
Do not empty containerswith pressure - no pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal protection and safety regulations.
Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels:
Storage in accordance with the Ordinance on Industrial Safety and Health. Keep container tightly closed. Do not empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store carefully closed containers upright to prevent any leaks.
Hints on joint storage:
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 5 °C and 30 °C. Protect
from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
only for authorised persons. Store carefully closed containers upright to prevent any leaks.
Specific end use(s)
Observe safety data sheet. Observe instructions for use.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Control parameters
Occupational exposure limit values: not applicable
Exposure controls
Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and
solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.
Occupational exposure controls
Respiratory protection
If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection
must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection
apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number.
Hand protection
For prolonged or repeated handling the following glove material must be used:
Thickness of the glove material > 0,4 mm ; Breakthrough time (maximum wearing time) > 480 min. Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended glove articles DIN EN 374. Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
Eye protection:
Wear closely fitting protective glasses in case of splashes.
Protective clothing:
Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.
Protective measures:
After contact clean skin thoroughly with water and soap or use appropriate cleanser.
Environmental exposure controls:
Do not allow to enter into surface water or drains. See also section "Handling and storage". No additional measures necessary.

Stability and reactivity

Reactivity
Chemical stability:
Stable when applying the recommended regulations for storage and handling.
Further information on correct storage: refer to section "Handling and storage"
Possibility of hazardous reactions:
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
Conditions to avoid:
Stable when applying the recommended regulations for storage and handling.
Further information on correct storage: refer to section "Handling and Storage". Hazardous decomposition byproducts may form with exposure to high temperatures.
Incompatible materials:
Hazardous decomposition products:
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke.

Disposal considerations

Waste treatment methods
Appropriate disposal / Product Recommendation:
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste disposal according to Directive 2008/98/EC, covering waste and dangerous waste.
List of proposed waste codes/waste designations in accordance with EEC:
No: 070699 : Wastes not otherwise specified
Packaging Recommendation
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste