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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
10 July 2018 to 09 August 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: Sponsor and UL18401660
- Expiration date of the lot/batch: 15 April 2020
- Purity test date: 30 May 2018
Key result
Auto-ignition temperature:
345 °C
Atm. press.:
1 011 hPa

Preliminary Test

The estimated auto-ignition temperature was 380°C.

Main Study

The results of the main study on the determination of the auto-ignition temperature of the test item are given inTable 6.

Ignition of the test item within 5 minutes after introduction was observed with each sample volume and with each test a minimum auto-ignition temperature was obtained. The maximum deviation between the three values was < 20°C. According to the guidelines, no further testing was required.

The lowest temperature at which ignition of the test item occurred was 347°C. This temperature was rounded down to the nearest multiple of 5°C giving an auto-ignition temperature of the test item of 345°C

.

Test

Volume


[μL]

Auto-ignition
temperature

[°C]

Ignition delay



[s]

Colour of the flame

Minimum auto-ignition
temperature
[°C]

1

70

377

9

orange/blue

347

 

150

369

6

 

 

 

250

347

8

 

 

 

450

360

12

 

 

2

170

357

7

orange/blue

354

 

200

354

11

 

 

 

280

361

9

 

 

3

120

375

5

orange/blue

355

 

220

355

13

 

 

 

320

368

12

 

 

Conclusions:
Commercially available auto-ignition temperature apparatus was used for the determination of the degree of auto-ignitability of 1-(bis(2-(1,3-dimethylbutylideneamino) ethyl)amino)-3-phenoxypropan-2-ol.
The test item is auto-ignitable with an auto-ignition temperature of 345°C.
The atmospheric pressure was 1011 and 1012 hPa.

Description of key information

Commercially available auto-ignition temperature apparatus was used for the determination of the degree of auto-ignitability of 1-(bis(2-(1,3-dimethylbutylideneamino) ethyl)amino)-3-phenoxypropan-2-ol.

The test item is auto-ignitable with an auto-ignition temperature of 345°C.

The atmospheric pressure was 1011 and 1012 hPa.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
345 °C

Additional information