Registration Dossier
Registration Dossier
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EC number: 212-415-6 | CAS number: 814-95-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
- General advice:
As a general rule, in case of doubt or if symptoms persist, always seek medical advice.
If the person is unconscious, she must not ingest anything.
- Following inhalation:
Take the patient in the open air and consult a doctor.
If breath is stopped or irregular, practice artificial respiration and call a doctor. Give nothing by mouth.
- Following skin contact:
Remove contaminated clothing and wash skin thoroughly with soap and water.
- Following eye contact:
Wash with water and consult an ophthalmologist.
- Following ingestion:
Consult a doctor and showing him the label to judge the appropriate of monitoring and subsequent treatment in hospital if necessary.
- Most important symptoms and effects:
Ingestion : Accidental ingestion of salts of oxalic acid soluble cause systemic poisoning by hypocalcaemia (tremors, convulsions, coma, bleeding disorders) and especially acute nephritis with precipitation in renal tubules insoluble calcium oxalate.
Indication of any immediate medical attention and special treatment necessary : Rinse thoroughly with water area in contact with the substance. Consult a doctor.
If the person is unconscious, she must not ingest anything.
- Following inhalation:
Take the patient in the open air and consult a doctor.
If breath is stopped or irregular, practice artificial respiration and call a doctor. Give nothing by mouth.
- Following skin contact:
Remove contaminated clothing and wash skin thoroughly with soap and water.
- Following eye contact:
Wash with water and consult an ophthalmologist.
- Following ingestion:
Consult a doctor and showing him the label to judge the appropriate of monitoring and subsequent treatment in hospital if necessary.
- Most important symptoms and effects:
Ingestion : Accidental ingestion of salts of oxalic acid soluble cause systemic poisoning by hypocalcaemia (tremors, convulsions, coma, bleeding disorders) and especially acute nephritis with precipitation in renal tubules insoluble calcium oxalate.
Indication of any immediate medical attention and special treatment necessary : Rinse thoroughly with water area in contact with the substance. Consult a doctor.
Fire-fighting measures
- Suitable extinguishing media:
CO2, foam, powder or spray water.
- Unsuitable extinguishing media: Fountain to not scatter the product.
- Special hazards arising from the substance or mixture: The thermal decomposition product is a source of toxic gas emission,CO and CO2
- Advice for fire fighter:
Protective measures : Avoid contact with skin or eyes. Isolate area.
Special protective equipment : Wear a autonomous respiratory apparatus.
- Unsuitable extinguishing media: Fountain to not scatter the product.
- Special hazards arising from the substance or mixture: The thermal decomposition product is a source of toxic gas emission,CO and CO2
- Advice for fire fighter:
Protective measures : Avoid contact with skin or eyes. Isolate area.
Special protective equipment : Wear a autonomous respiratory apparatus.
Accidental release measures
- Personal precautions, Protective equipment and emergency procedures:
To the non-rescuers
Protection equipment : Goggles, chemical protective gloves (EN374-3), workwear.
Flame, ventilation, dust : Avoid dust formation. Avoid dust inhalation. Ensure adequate ventilation. Wearing dust-mask type P2 P3 (EN143).
Emergency procedures : If spilled quantities are important, evacuate all personnel and involving only trained operators equipped with protective equipment.
To the rescuers
Appropriate clothing : Respirator protection in case of aerosol : adequate protective mask type P2 or P3, in accordance with regulation EN143.
Hands protection : protective gloves with chemical resistance in accordance with regulation EN374-3.
Eyes protection : wear protective goggles in all case of industrial use. Water station near.
Skin protection : Clothing waterproof and covering.
- Environmental precautions:
Prevent any penetration into sewers or waterways.
Pick up spilled product, putting it in plastic bags or drums.
Use drums to dispose of waste recovered in accordance with applicable regulation.
If the product contaminates waterways, rivers or sewers, alert the relevant authorities in accordance with statutory procedures.
- Methods and material for containment and cleaning up:
If spilling : Pick up spilled product, put it in plastic bags or drums. Place in containers for disposal of waste recovered in accordance with existing regulations.
Cleaning procedures : Pick up the product by sweeping in hermetic container and evacuate it from appropriate landfill.
Cleaning in preference with water, do not use solvent and wood sawdust.
To the non-rescuers
Protection equipment : Goggles, chemical protective gloves (EN374-3), workwear.
Flame, ventilation, dust : Avoid dust formation. Avoid dust inhalation. Ensure adequate ventilation. Wearing dust-mask type P2 P3 (EN143).
Emergency procedures : If spilled quantities are important, evacuate all personnel and involving only trained operators equipped with protective equipment.
To the rescuers
Appropriate clothing : Respirator protection in case of aerosol : adequate protective mask type P2 or P3, in accordance with regulation EN143.
Hands protection : protective gloves with chemical resistance in accordance with regulation EN374-3.
Eyes protection : wear protective goggles in all case of industrial use. Water station near.
Skin protection : Clothing waterproof and covering.
- Environmental precautions:
Prevent any penetration into sewers or waterways.
Pick up spilled product, putting it in plastic bags or drums.
Use drums to dispose of waste recovered in accordance with applicable regulation.
If the product contaminates waterways, rivers or sewers, alert the relevant authorities in accordance with statutory procedures.
- Methods and material for containment and cleaning up:
If spilling : Pick up spilled product, put it in plastic bags or drums. Place in containers for disposal of waste recovered in accordance with existing regulations.
Cleaning procedures : Pick up the product by sweeping in hermetic container and evacuate it from appropriate landfill.
Cleaning in preference with water, do not use solvent and wood sawdust.
Handling and storage
- Precautions for safe handling:
Handling : Handle in well ventilated places. Collect dust if necessary. Don’t smoke. Prohibit access to unauthorized persons.
Avoid contact of product with skin and eyes. Water station near.
Hygiene : Wash hands before and after handling. Do not smoke, drink and heat in premises where product is used.
- Conditions for safe storage, including any incompatibilities: Keep container tightly closed and in dry place (product sensitive to light).
For any particular use, consult the supplier.
Handling : Handle in well ventilated places. Collect dust if necessary. Don’t smoke. Prohibit access to unauthorized persons.
Avoid contact of product with skin and eyes. Water station near.
Hygiene : Wash hands before and after handling. Do not smoke, drink and heat in premises where product is used.
- Conditions for safe storage, including any incompatibilities: Keep container tightly closed and in dry place (product sensitive to light).
For any particular use, consult the supplier.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- NA
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- NA
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Marine transport (UN RTDG/IMDG)
- UN number:
- NA
Shipping information
- Proper shipping name and description:
- NA
- Chemical name:
- NA
- Labels:
- NA
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- NA
Shipping information
- Proper shipping name and description:
- NA
- Chemical name:
- NA
- Labels:
- NA
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Exposure controls / personal protection
1. Technical protection measures and organisational protection measures :
Engineering controls : Provide ventilation/or sufficient suction in the workshops. Install devices for not exceed the exposure limits.
Individual protective measures : Wearing protective clothing for body, the hands, eyes, in advised materials : PVC, neoprene…
Water station near.
2. if necessary, hand protection Gloves chemical resistant according to EN374-3.
3. Feet protection Workshoes
4. Body protection : Workwear. Shower nearby.
5. Eye protection : In case of activity generating dust, wear protective goggles in all industrial operation. If risk of splashing, chemical proof goggles/face shield. Eyewash station nearby.
6. Respiratory protection : if necessary, dust mask type P2 P3 (EN143).
Engineering controls : Provide ventilation/or sufficient suction in the workshops. Install devices for not exceed the exposure limits.
Individual protective measures : Wearing protective clothing for body, the hands, eyes, in advised materials : PVC, neoprene…
Water station near.
2. if necessary, hand protection Gloves chemical resistant according to EN374-3.
3. Feet protection Workshoes
4. Body protection : Workwear. Shower nearby.
5. Eye protection : In case of activity generating dust, wear protective goggles in all industrial operation. If risk of splashing, chemical proof goggles/face shield. Eyewash station nearby.
6. Respiratory protection : if necessary, dust mask type P2 P3 (EN143).
Stability and reactivity
1. Reactivity
: Reaction with oxidizing and strong acid.
2. Chemical stability : Stable in recommended conditions of storage and handling.
3. Possibility of hazardous reactions : Hazard reaction with oxidizing and acid. Release CO2.
4. Conditions to avoid : avoid presence of oxidizing and strong acid
5. Incompatible materials : oxidizers
6. Hazardous decomposition products : in case of fire, decomposes in CO2 or CO
2. Chemical stability : Stable in recommended conditions of storage and handling.
3. Possibility of hazardous reactions : Hazard reaction with oxidizing and acid. Release CO2.
4. Conditions to avoid : avoid presence of oxidizing and strong acid
5. Incompatible materials : oxidizers
6. Hazardous decomposition products : in case of fire, decomposes in CO2 or CO
Disposal considerations
Suitable containers : Put in hermetic container in plastic material.
Waste substance treatment : Treat the waste to an authorized center in accordance with local and national regulations.
Substance treatment : Pick up the product.
Treat it in accordance with local and national regulations.
Packaging treatment : Wash the container plenty with water and neutralized. Treat it in accordance with local and national regulations.
Elimination and environment : Do not discharge into sewers, watercourse, and natural environment.
Waste substance treatment : Treat the waste to an authorized center in accordance with local and national regulations.
Substance treatment : Pick up the product.
Treat it in accordance with local and national regulations.
Packaging treatment : Wash the container plenty with water and neutralized. Treat it in accordance with local and national regulations.
Elimination and environment : Do not discharge into sewers, watercourse, and natural environment.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
