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First-aid measures

DESCRIPTION OF FIRST AID MEASURES

General Information
Remove contaminated soaked clothing immediately.
In the event of persistent symptoms receive medical treatment.

After Inhalation
Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion.
In the event of symptoms refer for medical treatment.

After Contact With Skin
Wash with water and soap as a precaution.
In case of irritation consult a physician.

After Contact With Eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
If eye irritation persists consult a specialist.

After Ingestion
Rinse out mouth and give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
Induce vomiting only upon the advice of a physician.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Product dust may be irritating to eyes, skin and respiratory system.
Inhalation of dust may cause cough and difficulties in breathing.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED

Treat symptoms.

Fire-fighting measures

EXTINGUISHING MEDIA

Suitable Extinguishing Media
Foam, carbondioxide, dry chemical, water-spray.

Extinguishing Media Which Must Not Be Used For Safety Reasons
Full water jet.

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Fire may produce : hydrogen chloride gas, carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and sulphur oxides.
Dust may form explosive mixture in air.

ADVICE FOR FIREFIGHTERS
Use breathing apparatus with independent air supply.
Protective suit.

Additional Information
Cool containers at risk with water spray jet.
Do not release chemically contaminated water into drains, soil or surface waters. Sufficient measures must be taken to retain water used for extinguishing.
Fire residues and contaminated firefighting water must be disposed of in accordance with local regulations.

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

Respirator must be worn if exposed to dust.
Ensure adequate ventillation.
Use personal protective clothing.
Remove all sources of ignition.

ENVIRONMENTAL PRECAUTIONS

Do not discharge into the drains/surface waters/groundwater.

METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP

Pick up mechanically, avoiding dust, and provide disposal in suitable recipients.

Handling and storage

PRECAUTIONS FOR SAFE HANDLING

Advice On Safe Handling
Keep container tightly closed.
Provide appropriate exhaust ventilation at machinery and at places where dust can be generated.
Do not breathe dust.
Avoid contact with skin, eyes and clothing.

Advice On Protection Against Fire And Explosion
Avoid the formation and deposition of dust.
Keep away from sources of ignition.
Dust may form explosive mixture in air.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Requirements For Storage Rooms And Vessels
Keep containers tightly closed in a dry, well ventilated place.

Further Information On Storage Conditions
Keep away from food, drink and animal feeding stuffs.

SPECIFIC END USE(S)
Hair colouring component.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

CONTROL PARAMETERS
Additional Advice On Limit Values
Obey TLV for common dust, if applicable.

EXPOSURE CONTROLS
Occupational Exposure Controls
Ensure adequate ventilation especially in confirmed areas.

Protective And Hygiene Measures
Do not breathe dust.
Wash hands before breaks and immediately after handling the product.
When using, do not eat, drink or smoke.
Do not wear contact lenses when handling the product.

Respiratory Protection
Respirator must be worn if exposed to dust.

Hand Protection
Protective gloves resistant to chemicals made of nitrile, minimum coat thickness 0.4mm, permeation resistance (wear duration) approx. 480 minutes.
This recommendation refers exclusively to the chemical compatibility and the test conforming to EN 374 carried out under laboratory conditions.
Therefore it is necessary to adhere additionally to the recommendations given by the manufacturer of protective gloves.

Eye Protection
Eye wash bottle with pure water.
Tightly fitting goggles.

Skin Protection
Long sleeved clothing.

Stability and reactivity

REACTIVITY
No decomposition if stored and applied as directed.

CHEMICAL STABILITY
Stable under normal conditions.

POSSIBILITY OF HAZARDOUS REACTIONS
Risk of dust explosions.

CONDITIONS TO AVOID
To avoid thermal decomposition, do not overheat.
Avoid development of dust.

INCOMPATIBLE MATERIALS
No materials to be especially mentioned.

HAZARDOUS DECOMPOSITION PRODUCTS
Hydrogen chloride gas, carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and sulphur oxides.

Disposal considerations

WASTE TREATMENT METHODS

Advice On Disposal
Can be incinerated, when in compliance with local regulations.
Where possible recycling is preferred to disposal.

Waste disposal number of waste from residues/unused products
070799
Wastes from organic chemical processes ; wastes from the MFSU of fine chemicals and chemical products not otherwise specified ; wastes not otherwise specified.

Contaminated Packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse.
Packaging that cannot be cleaned should be disposed of like the product.

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