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Physical & Chemical properties

Flammability

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Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
key study
Study period:
22 September 2003
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines and in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
not specified
GLP compliance:
yes
Key result
Remarks on result:
no reaction with water observed

The structure of Hatcol 2352 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities. Furthermore, no metals, transition metals,boron or silicon are present.

During the addition of a small quantity of the test substance to double distilled water (0.5 g/50 mL), no spontaneous ignition took place and no evolution of gas occurred.

Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
Hatcol 2352 is incapable of developing a dangerous amount of (flammable) gas(es) in contact with air, damp air or water.
Executive summary:

The procedure for the determination of the flammability (in contact with water) of a test substance is described in the following guideline:

European Economic Community (EEC), EEC directive 92/69 EEC, Part A, Methods for the determination of physico-chemical properties, A-12 "Flammability (contact with water), EEC Publication No. L383, December 1992.

 

Based on its molecular structure and on an experiment, it was concluded that Hatcol 2352 is incapable of developing a dangerous amount of (flammable) gas(es) in contact with air, damp air or water.

Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
key study
Study period:
23 September 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
not specified
GLP compliance:
yes
Key result
Test procedure:
other: structural formula analysis
Remarks on result:
not measured/tested

Results determined by structural formula analysis

Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
Hatcol 3331 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.
Executive summary:

The purpose of the study was to evaluate whether the reaction of the test substance with water or damp air leads to the development of dangerous amounts of gas or gases which may be highly flammable.

The procedure for the determination of the flammability (contact with water) is described in the following guideline: European Economic Community (EEC), EEC directive 92/69 EEC. Part A, Methods for the determination of physico-chemical properties, A-12 "Flammability (contact with water), EEC Publication No. L383, December 1992.

Substances which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities at a minimum rate of 1 litre/kg per hour are highly flammable.

Hatcol 3331 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.

Furthermore, no metals. transition metals, boron or silicon are present. Therefore, it can be concluded that the test substance is incapable of developing a dangerous amount of (flammable) gas in contact with air, damp air or water.

Moreover, during the addition of a small quantity of the test substance to double distilled water, it was observed that no spontaneous ignition took place and no evolution of gas occurred.

Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
key study
Study period:
23 September 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
not specified
GLP compliance:
yes
Key result
Remarks on result:
no reaction with water observed

Substances which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities at a minimum rate of 1 litre/kg per hour are highly flammable.

Hatcol 3344 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.

Furthermore, no metals, transition metals, boron or silicon are present. Therefore, it can beconcluded that the test substance is incapable of developing a dangerous amount of (flammable) gas in contact with air, damp air or water.

Moreover, during the addition of a small quantity of the test substance to double distilled water, it was observed that no spontaneous ignition took place and no evolution of gas occurred.

Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
Hatcol 3344 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.
Executive summary:

The purpose of the study was to evaluate whether the reaction of the test substance with water or damp air leads to the development of dangerous amounts of gas or gases which may be highly flammable.

 

The procedure for the determination of the flammability (contact with water) is described in the following guideline: European Economic Community (EEC), EEC directive 92/69 EEC, Part A, Methods for the determination of physico-chemical properties, A-12 "Flammability (contact with water), EEC Publication No. L383, December 1992.

 

Substances which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities at a minimum rate of 1 litre/kg per hour are highly flammable.

Hatcol 3344 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.

Furthermore, no metals, transition metals, boron or silicon are present. Therefore, it can beconcluded that the test substance is incapable of developing a dangerous amount of (flammable) gas in contact with air, damp air orwater.

Moreover, during the addition of a small quantity of the test substance to double distilled water, it was observed that no spontaneous ignition took place and no evolution of gas occurred.

Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
key study
Study period:
23 September 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordanc with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
not specified
GLP compliance:
yes
Key result
Remarks on result:
no reaction with water observed
Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
Hatcol 5236 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.
Executive summary:

The purpose of the study was to evaluate whether the reaction of the test substance with water or damp air leads to the development of dangerous amounts of gas or gases which may be highly flammable.

The procedure for the determination of the flammability (contact with water) is described in the following guideline: European Economic Community (EEC), EEC directive 92/69 EEC, Part A, Methods for the determination of physico-chemical properties, A-12 "Flammability (contact with water), EEC Publication No. L383, December 1992.

 

Substances which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities at a minimum rate of 1 litre/kg per hour are highly flammable.

Hatcol 5236 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.

Furthermore, no metals, transition metals, boron or silicon are present. Therefore, it can be concluded that the test substance is incapable of developing a dangerous amount of (flammable) gas in contact with air, damp air or water.

Moreover, during the addition of a small quantity of the test substance to double distilled water, it was observed that no spontaneous ignition took place and no evolution of gas occurred.

Endpoint:
pyrophoric liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
29 September 2003
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.13 (Pyrophoric Properties of Solids and Liquids)
Deviations:
not specified
GLP compliance:
yes
Key result
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition on contact with air (not further specified)

The molecular structure of Hatcol 2352 does not contain any chemical groups that might lead to spontaneous ignition a short time after coming into contact with air.

Furthermore, experience in handling shows that the test substance does not ignite after coming in contact with air at room temperature (circa 20°C).

Interpretation of results:
other: not pyrophoric
Conclusions:
Hatcol 2352 is not pyrophoric.
Executive summary:

The procedure for the determination of the pyrophoric properties is described in the following guideline:

European Economic Community (EEC), EEC directive 92/69 EEC, Part A, Methods for the determination of physico-chemical properties, A-13: "Pyrophoric properties of solids and liquids", EEC Publication No. L383, December 1992.

Based on its molecular structural and on experience in handling, it was concluded Hatcol 2352 is not pyrophoric.

Endpoint:
pyrophoric liquids
Remarks:
Pyrophoric liquids/solids (migrated from section 'Flammability')
Type of information:
experimental study
Adequacy of study:
key study
Study period:
03 October 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.13 (Pyrophoric Properties of Solids and Liquids)
Deviations:
not specified
GLP compliance:
yes
Key result
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition on contact with air (not further specified)
Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
From the structural formula of Hatcol 3331, it can be concluded that Hatcol 3331 is not pyrophoric.
Executive summary:

The purpose of the study was to evaluate the pyrophoric properties of the test substance.

The procedure for the determination of the pyrophoric properties is described in the following guideline:

European Economic Community (EEC), EEC directive 92/69 EEC, Part A, Methods for thedetermination of physico-chemical properties, A-13: "Pyrophoric properties of solids and liquids", EEC Publication No. L383, December 1992.

 

From the structural formula of Hatcol 3331, it can be concluded that Hatcol 3331 is not pyrophoric. The test substance does not contain any chemical group that might lead to spontaneous ignition a short time after coming into contact with air at room temperature (circa 20°C). Furthermore, experience in handling shows that the test substance does not ignite coming in contact with air.

Endpoint:
pyrophoric liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
03 October 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.13 (Pyrophoric Properties of Solids and Liquids)
Deviations:
not specified
GLP compliance:
yes
Key result
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition on contact with air (not further specified)
Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
Hatcol 3344 is not pyrophoric.
Executive summary:

The purpose of the study was to evaluate the pyrophoric properties of the test substance.

The procedure for the determination of the pyrophoric properties is described In the following guideline: European Economic Community (EEC), EEC directive 92169 EEC, Part A, Methods for thedetermination of physico-chemical properties, A-13: "Pyrophoric properties of solids and liquids", EEC Publication No. L383, December 1992.

From the structural formula of Hatcol 3344, it can be concluded that Hatcol 3344 is not pyrophoric. The test substance does not contain any chemical group that might lead to spontaneous Ignition a short time after coming Into contact with air at room temperature (circa 20°C). Furthermore, experience in handling shows that the test substance does not ignite coming in contact with air.

Endpoint:
pyrophoric liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
03 October 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.13 (Pyrophoric Properties of Solids and Liquids)
Deviations:
not specified
GLP compliance:
yes
Key result
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition on contact with air (not further specified)
Interpretation of results:
non flammable
Remarks:
Migrated information
Conclusions:
It is concluded that Hatcol 5236 is not pyrophoric.
Executive summary:

The purpose of the study was to evaluate the pyrophoric properties of the test substance.

The procedure for the determination of the pyrophoric properties is described in the following guideline: European Economic Community (EEC), EEC directive 92/69 EEC, Part A, Methods for the determination of physico-chemical properties, A-13: "Pyrophoric properties of solids and liquids", EEC Publication No. L383, December 1992.

From the structural formula of Hatcol 5236, it can be concluded that Hatcol 5236 is not pyrophoric. The test substance does not contain any chemical group that might lead to spontaneous ignition a short time after coming into contact with air at room temperature (circa 20°C). Furthermore, experience in handling show that the test substance does not ignite coming In contact with air.

Endpoint:
substances / mixtures which in contact with water emit flammable gases
Type of information:
experimental study
Adequacy of study:
key study
Study period:
08 July 2010- 30 July 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: This study has been performed according to OECD and EC guideline and according to GLP principles. Based on the molecular structure a statement rather than a full study was considered sufficient to cover this endpoint.
Qualifier:
according to guideline
Guideline:
EU Method A.12 (Flammability (Contact with Water))
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.4: Recommendations on the Transport of Dangerous Goods, Part III: Classification Procedures, Test Methods and Criteria Relating to Explosives of Class 3, Class 4, Division 5.1 and Class 9, Test N.5 ”, 2003
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.4: Recommendations on the Transport of Dangerous Goods, Appendix 6: “Screening Procedures”, 2003.
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Remarks on result:
no reaction with water observed

A test substance is considered highly flammable when it ignites spontaneously in contact with water, or evolves a flammable gas at a minimum rate of ≥ 1 litre/kg of the substance per hour.

None of the components of the test substance does contain groups that might lead to ignition in contact with water and/or to the evolution of a flammable gas. The molecular structures of impurities at =< 1% were not taken into account.

 

In conclusion, Decanoic acid, mixed esters with heptanoic acid, octanoic acid and trimethylolpropane is considered ‘not highly flammable’ in contact with water.

Interpretation of results:
other: not higly flammable in contact with water
Conclusions:
In conclusion, Decanoic acid, mixed esters with heptanoic acid, octanoic acid and trimethylolpropane is considered ‘not highly flammable’ in contact with water.
Endpoint:
pyrophoric liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
08 July 2010- 30 July 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: This study has been performed according to OECD and EC guideline and according to GLP principles. Based on the molecular structure a statement rather than a full study was considered sufficient to cover this endpoint.
Qualifier:
according to guideline
Guideline:
EU Method A.13 (Pyrophoric Properties of Solids and Liquids)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.4: Recommendations on the Transport of Dangerous Goods, Part III: Classification Procedures, Test Methods and Criteria Relating to Explosives of Class 3, Class 4, Division 5.1 and Class 9, Test N.3 , 2003.
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.4: Recommendations on the Transport of Dangerous Goods, Appendix 6: “Screening Procedures”, 2003.
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition on contact with air (not further specified)

A test substance is considered pyrophoric when it ignites within five minutes of coming in contact with air.

None of the components of the test substance does contain groups that might lead to ignition in contact with air. Moreover the test substance was handled under normal laboratory conditions during this project. It demonstrated that the test substance does not ignite in contact with air at room temperature. The molecular structures of impurities at =< 1% were not taken into account.

 

In conclusion, Decanoic acid, mixed esters with heptanoic acid, octanoic acid and dimethylolpropane has no pyrophoric properties.

Interpretation of results:
other: not pyrophoric
Conclusions:
In conclusion, Decanoic acid, mixed esters with heptanoic acid, octanoic acid and dimethylolpropane has no pyrophoric properties.

Description of key information

Result determined using EU Test Guidelines A12 and A13.

Key value for chemical safety assessment

Flammability:
non flammable

Additional information

HATCOL 2352

Based on its molecular structure and on an experiment, it was concluded that Hatcol 2352 is incapable of developing a dangerous amount of (flammable) gas(es) in contact with air, damp air or water.

 

Based on its molecular structural and on experience in handling, it was concluded Hatcol 2352 is not pyrophoric.

 

HATCOL 3331

The purpose of the study was to evaluate whether the reaction of the test substance with water or damp air leads to the development of dangerous amounts of gas or gases which may be highly flammable.

Substances which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities at a minimum rate of 1 litre/kg per hour are highly flammable.

Hatcol 3331 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.

Furthermore, no metals. transition metals, boron or silicon are present. Therefore, it can be concluded that the test substance is incapable of developing a dangerous amount of (flammable) gas in contact with air, damp air or water.

Moreover, during the addition of a small quantity of the test substance to double distilled water, it was observed that no spontaneous ignition took place and no evolution of gas occurred.

 

From the structural formula of Hatcol 3331, it can be concluded that Hatcol 3331 is not pyrophoric. The test substance does not contain any chemical group that might lead to spontaneous ignition a short time after coming into contact with air at room temperature (circa 20°C). Furthermore, experience in handling shows that the test substance does not ignite coming in contact with air.

 

HATCOL 3344

The purpose of the study was to evaluate whether the reaction of the test substance with water or damp air leads to the development of dangerous amounts of gas or gases which may be highly flammable.  

Substances which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities at a minimum rate of 1 litre/kg per hour are highly flammable.

Hatcol 3344 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.

Furthermore, no metals, transition metals, boron or silicon are present. Therefore, it can be concluded that the test substance is incapable of developing a dangerous amount of (flammable) gas in contact with air, damp air or water.

Moreover, during the addition of a small quantity of the test substance to double distilled water, it was observed that no spontaneous ignition took place and no evolution of gas occurred.

 

The purpose of the study was to evaluate the pyrophoric properties of the test substance.

From the structural formula of Hatcol 3344, it can be concluded that Hatcol 3344 is not pyrophoric. The test substance does not contain any chemical group that might lead to spontaneous Ignition a short time after coming Into contact with air at room temperature (circa 20°C). Furthermore, experience in handling shows that the test substance does not ignite coming in contact with air.

 

HATCOL 5236

The purpose of the study was to evaluate whether the reaction of the test substance with water or damp air leads to the development of dangerous amounts of gas or gases which may be highly flammable.  

Substances which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities at a minimum rate of 1 litre/kg per hour are highly flammable.

Hatcol 5236 does not contain groups that might lead to evolution of highly flammable gases in dangerous quantities.

Furthermore, no metals, transition metals, boron or silicon are present. Therefore, it can be concluded that the test substance is incapable of developing a dangerous amount of (flammable) gas in contact with air, damp air or water.

Moreover, during the addition of a small quantity of the test substance to double distilled water, it was observed that no spontaneous ignition took place and no evolution of gas occurred.

 

The purpose of the study was to evaluate the pyrophoric properties of the test substance.

From the structural formula of Hatcol 5236, it can be concluded that Hatcol 5236 is not pyrophoric. The test substance does not contain any chemical group that might lead to spontaneous ignition a short time after coming into contact with air at room temperature (circa 20°C). Furthermore, experience in handling show that the test substance does not ignite coming In contact with air.

HATCOL 1510

Flammability in contact with water

The structural features of the substance were evaluated and it was concluded that none of the components contains groups that might lead to the evolution of a dangerous amount of flammable gas when coming into contact with water or damp air. No metals, transition metals, boron or silicon are present.

In conclusion, the test substance is not highly flammable in contact with water or damp air.

 

Pyrophoric properties

The structural features of the components of the substance were evaluated and it was concluded that none of the components contain any chemical groups that might lead to spontaneous ignition a short time after coming into contact with air. Furthermore, experience from using this substance as a lubricant shows that the test substance does not ignite spontaneously after coming in contact with air at room temperature.

Justification for classification or non-classification