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Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
03 March 2004 to 09 March 2004
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU and ISO test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Version / remarks:
2002
Deviations:
not specified
GLP compliance:
yes
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
236.5 °C
Atm. press.:
102.6 kPa

Preliminary test

Estimated flash-points for test substance

Test substance

Estimated flash-point [°C]

Hatcol 2352

235

 

Main study

Summary of the measured flash-points and the lowest flash-point.

Test

Flash-point [°C]

Lowest flash-point [°C]

1

237

237

2

239

 

The lowest flash-point was corrected for the atmospheric pressure (i.e. 102.6 kPa).

Corrected flash-point = 237÷0.25(101.3-102.6)°C= 236.68°C

Rounded off to 0.5°C gives the flash-point for Hatcol 2352: 236.5°C.

Conclusions:
Rounded off to 0.5°C gives the flash-point for Hatcol 2352: 236.5°C.
Executive summary:

The determination of the flash-point was performed in accordance with EEC-Directive 92/69 EEC, A.9 "Flash-point" (1992) and DIN EN 22719: "Bestimmung des Flammpunktes Verfhrennach Pensky Martens im geschlossenen Tiegel"; December 1993.

 

The flash-point determined for Hatcol 2352, using the Pensky-Martens closed cup flash-point apparatus is 236.5°C.

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
16 October 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
not specified
GLP compliance:
yes
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
215.5 °C
Atm. press.:
100.1 kPa
Remarks on result:
other: Flash-point corrected for the atmospheric pressure

Preliminary test

Flash-point: 225°C

 

Main study

Table 1: Determined flash-points during the main study

Test number

Flash-point [°C]

Lowest Flash-point [°C]

1

215

215

2

215

 

The atmospheric pressure on the day of the test, was 100.10 kPa.

The lowest flash-point was corrected for the atmospheric pressure.

Corrected flash-point   = 215 + 0.25 (101.3-100.10)°C

= 215.30°C

Conclusions:
The flash-point of Hatcol 3331 is 215.5°C under the conditions of the test.
Executive summary:

The determination of the flash-point of Hatcol 3331 was performed using a Pensky-Martens closed cup flash-point apparatus, in accordance with EEC-Directive 92/69 EEC, A.9 "Flashpoint" (1992) and DIN EN 22719: "Bestimmung des Flammpunktes Verfahren nach Pensky-Martens imgeschlossenen Tiegel"; December 1993.

The flash-point of Hatcol 3331 is 215.5°C when using a Pensky-Martens closed cup flash-point apparatus.

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
08 October 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
not specified
GLP compliance:
yes
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
129 °C
Atm. press.:
101.76 kPa

Determined flash-points during the main study

Test number

Flash-point [°C]

1

198

2

195

 

Conclusions:
The flash point of Hatcol 3344 is 129°C.
Executive summary:

The determination of the flash-point of Hatcol 3344 was performed using a Pensky-Martens closed cup flash-point apparatus, in accordance with EEC-Directive 92/69 EEC, A.9 "Flashpoint" (1992) and DIN EN 22719: "Besummung des Flammpunktes Verfahren nach Pensky-Martens im geschlossenen Tiegel"; December 1993.

The flash-point of Halcol 3344, determined during the preliminary test is 129°C.

During the main study, the flash-point of Hatcol3344 is determined to be 198°C and 195°C in test 1 and 2, respectively.

For safety reasons, the lowest temperature at which the test substance vapour / air mixture could be ignited (determined during the preliminary test) will be taken as the flash-point of Hatcol 3344.

In conclusion, the flash-point of Hatcol 3344 is 129°C under the conditions of the test.

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
16 October 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study performed in accordance with EU test guidelines in compliance with GLP.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
not specified
GLP compliance:
yes
Type of method:
closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
120.5 °C
Atm. press.:
100.1 kPa

Determined flash-points during the main study

Test number

Flash-point [°C]

Lowest Flash-point [°C]

1

120

120

2

124

Conclusions:
The flash-point of Hatcol 5236 is 120.5°C under the conditions of the test.
Executive summary:

The determination of the flash-point of Hatcol 5236 was performed using a Pensky-Martensclosed cup flash-point apparatus, in accordance with EEC-Directive 92/69 EEC, A.9 "Flashpoint' (1992) and DIN EN 22719: "Beslimmung des Flammpunktes Verfhren nach Pensky-Martens im geslossenen liegel"; December 1993.

The flash-point of Hatcol 5236 is 120.5°C when using a Pensky-Martens closed cup flash-point apparatus.

Endpoint:
flash point
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
26 september 2006
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: non-GLP test
Qualifier:
according to guideline
Guideline:
ISO No., other: ASTM D-92
GLP compliance:
no
Type of method:
equilibrium method closed cup
Key result
Flash point:
249 °C
Atm. press.:
100.21 kPa
Remarks on result:
other: corrected flash point
Conclusions:
The flash point of the test item has been determined to be 249°C using a closed cup equilibrium method (Pensky-Martin Closed Cup apparatus) .
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Basic data given. Certificate of Analysis.
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Version / remarks:
2002
GLP compliance:
no
Type of method:
closed cup
Remarks:
ASTM D93 / IP 34 / EN22719
Key result
Flash point:
262.5 - 264.5 °C
Atm. press.:
1 013 hPa

Description of key information

The determination of the flash-point was performed in accordance with EEC-Directive 92/69 EEC, A.9 "Flash-point" (1992).

Key value for chemical safety assessment

Flash point at 101 325 Pa:
236.5 °C

Additional information

HATCOL 2352

The flash-point determined for Hatcol 2352, using the Pensky-Martens closed cup flash-point apparatus is 236.5°C.

 

HATCOL 3331

The flash-point of Hatcol 3331 is 215.5°C when using a Pensky-Martens closed cup flash-point apparatus.

 

HATCOL 3344

The flash-point of Hatcol 3344, determined during the preliminary test is 129°C.

During the main study, the flash-point of Hatcol 3344 is determined to be 198°C and 195°C in test 1 and 2, respectively.

For safety reasons, the lowest temperature at which the test substance vapour / air mixture could be ignited (determined during the preliminary test) will be taken as the flash-point of Hatcol 3344.

In conclusion, the flash-point of Hatcol 3344 is 129°C under the conditions of the test.

 

HATCOL 5236

The flash-point of Hatcol 5236 is 120.5°C when using a Pensky-Martens closed cup flash-point apparatus.

HATCOL 1510

The flash point of substance EC # 268-596-7 was determined to be 249 °C using the equilibrium method (Pensky-Martens closed cup).

HATCOL 1765

The flash point of the substance pentaerythritol tetraesters of n-decanoic, n-heptanoic, n-octanoic and n-valeric acids (CAS 68424 -31 -7) was deduced from a similar substance with a very similar specification using the ISO 2719:2002 Pensky-Martens closed cup method.