Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

General advices

Alert a physician.

Show this safety data sheet to physician.

Exposure routes :

Eyes contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Alert a physician.

Skin contact

Remove contaminated clothing and shoes. Wash with soap and plenty of water.

Wash contaminated clothing before reuse.

Alert a physician.

Inhalation

If inhaled, move person into fresh air.

If not breathing give artificial respiration

Seek immediately medical advice.

Ingestion

Rinse mouth with water and drink plenty of water. Do not make the victim vomit.

Treat symptomatically.

Never give anything by mouth to an unconscious person.

If swallowed seek medical advice immediately and show the container or label.

Most important symptoms and effects, both acute and delayed:

no available data

Protection of first aid

Refer to Section 8.

Instructions for the physician

Treat according to symptoms. Keep the victim under medical surveillance.

Fire-fighting measures

Suitable extinguishing media:

CO2, powder, alcohol resistant foam, water spray (fog).

Special hazards arising from the substance

Toxic gases when in contact with fire :

COx, fluorhydric acid (HF).

Inadvisable media

Water jet

Special protective equipment for fire-fighting

Hold the product and empty container away from heat and ignition sources.

Do not flush into surface water or sanitary sewer system.

Collect contaminated firefighting water separately, must not be discharged into the drains.

Special protective equipment

Wear a complete protection equipment and a self-contained respiratory apparatus.

Other information:

Use water spray to cool closed containers exposed to fire.

Accidental release measures

Person related precautionary measures

refer to section 8.

Emergency Procedures

Avoid breathing dust. Ensure adequate ventilation. Remove all sources of ignition. Evacuate the staff to safe place.

Environmental-protection measures

Do not flush into sanitary sewer system nor in the natural environment.

Methods and materials for containment and cleaning

•       Mechanical pick, recover in airtight container.

•       Elimination: refer to section 13.

Handling and storage

HANDLING

Appropriate technical measures

•       Avoid breathing dust

•       Keep away from any flame or source of sparks

•       Do not smoking

•       Take measures to prevent static discharges

•       Airy studio with ventilation system

•       Have an eyewash nearby

Recommendations against fires and explosions

•       Connect containers to ground

•       Inert the installation.

•       Collect dust at the source.

•       Keep away from sources of ignition.

Advice on occupational health

•       Avoid contact with skin, eyes and mucous membranes.

•       Do not eat, drink and smoke in work areas.

•       Wash hands and face after each use

•       Remove contaminated clothing and protective equipment before entering eating areas

•       Avoid prolonged or repeated exposure.

STORAGE

Appropriate technical measures : keep container tightly closed.

Storage conditions : keep container tightly closed in a dry and well-ventilated place.

Incompatible materials

no available data

Packaging Materials

Store in the original packaging.

Avoid: Heat, flames and sparks.

Exposure Scenario : -

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Occupational exposure limit (mg/m3) : no available data

Appropriate engineering controls : General industrial hygiene practice.

Personal protective equipment:

•       Respiratory protection: When the risk assessment shows that wearing respirators are appropriate, use of tested and approved equipment by standards such as OSHA 29 CGR 190.134, ANSI Z88.2 or MSHA 30 CFR 72.710.

•       Hand protection: Suitable gloves (nitrile) adapted to chemical uses EN374 as specified in the Directive EU 89/686/CEE.

•       Skin and body other than the hands: full protective gear against chemicals, individual protection equipment must be selected depending on the concentration and quantity of the substance.

•       Eye/face protection: use eyes protection equipment, use of tested and approved equipment by standards such as NIOSH (US) or EN 166(EU).

Precautions to take : Avoid breathing vapors, spray mist or gaz. Ensure adequate ventilation. Remove all sources of ignition. Evacuate the staff to safe place. Beware of vapors accumulating to form explosive concentrations. Vapors may accumulate in low-lying areas.

Advice on occupational health:

•       Avoid contact with skin, eyes and mucous membranes.

•       Do not eat, drink and smoke in work areas.

•       Wash hands and face after use.

•       Remove contaminated clothing and protective equipment before entering eating areas.

Specific advice on protective equipment against fire and chemical hazards:

refer to section 5.

Exposure controls to protect the environment: avoid further leakage or spillage. Do not let product enter drains.

Stability and reactivity

Reactivity

no available data

Chemical stability

Stable in standard conditions of use.

Possibility of hazardous reactions

no available data

Conditions to be avoided

Heat, flame, sparks.

Products to be avoided

no available data

Hazardous decomposition products

COx, fluorhydric acid (HF).

These hazardous combustion products are described in section 5.

Disposal considerations

Product disposal method : PRODUCT MUST BE DISPOSED OF IN COMPLIANCE WITH THE COUNTRY-SPECIFIC REGULATIONS.

Contaminated packing : PRODUCT MUST BE DISPOSED OF IN COMPLIANCE WITH THE COUNTRY-SPECIFIC REGULATIONS.

Apply any relevant Community provisions relating to waste.