Registration Dossier

Administrative data

First-aid measures

Description of first aid measures

General notes:
Do not leave affected person unattended.
Remove victim out of the danger area.
Keep affected person warm, still and covered.
Take off immediately all contaminated clothing.
In all cases of doubt, or when symptoms persist, seek medical advice.
In case of unconsciousness place person in the recovery position.
Never give anything by mouth.

Following inhalation:
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions.
Provide fresh air.

Following skin contact:
Wash with plenty of soap and water.

Following eye contact:
Remove contact lenses, if present and easy to do.
Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.

Following ingestion:
Rinse mouth with water (only if the person is conscious).
Do NOT induce vomiting.

Most important symptoms and effects, both acute and delayed:
Symptoms and effects are not known to date.

Indication of any immediate medical attention and special treatment needed:
none

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:
Dry extinguishing powder, Foam, Carbon dioxide (CO2), Water spray

Unsuitable extinguishing media:
Water jet

Special hazards arising from the substance or mixture:
In case of insufficient ventilation and/or in use, may form flammable/explosive vapour-air mixture.
Develops toxic and irritant vapours during strong heating or fire.
The vapours may be invisible and are heavier than air.
Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures.
The exposure of containers to heat leads to an increase in pressure with a risk of bursting and subsequent explosion.

Hazardous combustion products:
Carbon monoxide (CO), Carbon dioxide (CO2), Siliconoxides

Advice for firefighters:
In case of fire and/or explosion do not breathe fumes.
Wear self-contained breathing apparatus.
Fight fire with normal precautions from a reasonable distance.
Co-ordinate firefighting measures to the fire surroundings.
Do not allow firefighting water to enter drains or water courses.
Collect contaminated firefighting water separately.
Remove undamaged containers from heat radiation.
Keep containers cool with water spray.
Precipitate combustion gases with water spray if possible.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel:
Remove persons to safety.

For emergency responders:
Wear breathing apparatus if exposed to vapours/dust/spray/gases.

Environmental precautions
Keep away from drains, surface and ground water.
Retain contaminated washing water and dispose of it.
If substance has entered a water course or sewer, inform the responsible authority.

Methods and material for containment and cleaning up
Advice on how to contain a spill:
Covering of drains

Advice on how to clean up a spill:
Wipe up with absorbent material (e.g. cloth, fleece).
Collect spillage: sawdust, diatomite, sand, universal binder.

Appropriate containment techniques:
Use of adsorbent materials.

Other information relating to spills and releases:
Place in appropriate containers for disposal.
Ventilate affected area.

Reference to other sections:
Hazardous combustion products: refer to sections on personal protective equipment, incompatible materials and disposal considerations.

Handling and storage

1. Precautions for safe handling

Recommendations:
- Measures to prevent fire as well as aerosol and dust generation:
Use local and general ventilation.
Avoidance of ignition sources.
Keep away from sources of ignition - No smoking.
Take precautionary measures against static discharge.
Use only in well-ventilated areas.
Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools.

- Specific notes/details:
Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures.
Vapours are heavier than air, spread along floors and form explosive mixtures with air.
Vapours may form explosive mixtures with air.

- Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures.
Vapours are heavier than air, spread along floors and form explosive mixtures with air.
Vapours may form explosive mixtures with air.

Advice on general occupational hygiene:
Wash hands after use.
Do not eat, drink and smoke in work areas.
Remove contaminated clothing and protective equipment before entering eating areas.
Never keep food or drink in the vicinity of chemicals.
Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feeding stuffs.

2. Conditions for safe storage, including any incompatibilities

Managing of associated risks
- explosive atmospheres:
Keep container tightly closed and in a well-ventilated place.
Use local and general ventilation.
Keep cool.
Protect from sunlight

- flammability hazards:
Keep away from sources of ignition - No smoking.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Take precautionary measures against static discharge.
Protect from sunlight.

- ventilation requirements:
Use local and general ventilation.
Ground/bond container and receiving equipment.

- packaging compatibilities:
Only packagings which are approved (e.g. acc. to ADR) may be used.

Transport information

Land transport (ADR/RID)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
Chemical name:
Allyltrimethylsilane
Language:
English
Class:
3
Classification code:
F1
Packaging group:
II
Labels:
3, fish and tree
Special Provisions:
Special provisions (SP): 274, 601, 640D
Remarks:
Excepted quantities (EQ): E2
Limited quantities (LQ): 1 L
Transport category (TC): 2
Tunnel restriction code (TRC): D/E
Hazard identification No: 33
Emergency Action Code: 3YE

Inland waterway transport (ADN(R))

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
Chemical name:
Allyltrimethylsilane
Language:
English
Class:
3
Classification code:
F1
Packaging group:
II
Labels:
3
Remarks
Special provisions (SP): 274, 601, 640D
Excepted quantities (EQ): E2
Limited quantities (LQ): 1 L
Transport category (TC): 2
Tunnel restriction code (TRC): D/E
Hazard identification No: 33
Emergency Action Code: 3YE

Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
Chemical name:
Allyltrimethylsilane
Class:
3
Packaging group:
II
EmS code:
F-E, S-E
Labels:
3, fish and tree
Remarks
Special provisions (SP): 274
Excepted quantities (EQ): E2
Limited quantities (LQ): 1 L
Stowage category: B

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
Flammable liquid, n.o.s.
Chemical name:
Allyltrimethylsilane
Class:
3
Packaging group:
II
Labels:
3
Remarks
Special provisions (SP): A3
Excepted quantities (EQ): E2
Limited quantities (LQ): 1 L
ERG Code: 3H

Additional transport information

Additional transport information
Special precautions for user:
Provisions for dangerous goods (ADR) should be complied within the premises.

Transport in bulk according to Annex II of MARPOL and the IBC Code:
The cargo is not intended to be carried in bulk.

Exposure controls / personal protection

Exposure controls
Appropriate engineering controls
Local and general ventilation.
Individual protection measures (personal protective equipment)

Eye/face protection:
Splash goggles.

Skin protection:

- Hand protection:
Wear suitable gloves.
Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use.
In the case of wanting to use the gloves again, clean them before taking off and air them well.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

- Type of material
IIR: isobutene-isoprene (butyl) rubber
NBR: acrylonitrile-butadiene rubber

- Breakthrough times of the glove material
IIR: >480 minutes (permeation: level 6)
NBR: >120 minutes (permeation: level 4)

- other protection measures:
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
In the case of wanting to use the gloves again, clean them before taking off and air them well.
Take recovery periods for skin regeneration.
Preventive skin protection (barrier creams/ointments) is recommended.
Wash hands thoroughly after handling.
Protective clothing against liquid chemicals.
Footwear protecting against chemicals.

Respiratory protection:
In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls:
Use appropriate container to avoid environmental contamination.
Keep away from drains, surface and ground water.

Stability and reactivity

Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
It's a reactive substance.
Risk of ignition.

If heated:
Risk of ignition

Chemical stability
See below "Conditions to avoid".

Possibility of hazardous reactions
No known hazardous reactions

Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.

Hints to prevent fire or explosion
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.

Incompatible materials
strong acids, strong bases, strong oxidising agents

Hazardous decomposition products
Hazardous combustion products: refer to section on firefighting measures.

Disposal considerations

Waste treatment methods
Waste treatment-relevant information
Dispose of contents/container in accordance with local/regional/national/international regulations.

Sewage disposal-relevant information
Do not empty into drains.
Avoid release to the environment.
Refer to special instructions/safety data sheets.

Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
Completely emptied packages can be recycled.
Handle contaminated packages in the same way as the substance itself.

Remarks
Please consider the relevant national or regional provisions.
Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.