Registration Dossier

Administrative data

First-aid measures

General advice:
Immediately remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, induce vomiting, seek medical attention.
Note to physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

Fire-fighting measures

Suitable extinguishing media:
dry extinguishing media, foam
Unsuitable extinguishing media for safety reasons:
carbon dioxide
Specific hazards:
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions:
Breathing protection is mandatory. Use personal protective clothing.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Methods for cleaning up or taking up:
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Contain with dust binding material and dispose of.
Avoid raising dust.

Handling and storage

Handling:
Open container with care, using adequate ventilation and avoid ignition sources.
Protection against fire and explosion:
Avoid dust formation. Take precautionary measures against static discharges.
Storage:
Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.

Transport information

Land transport (ADR/RID)

UN number:
UN 2811
Shippingopen allclose all
Class:
6.1
Classification code:
6.1
Packaging group:
2
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 2811
Shippingopen allclose all
Class:
6.1
Classification code:
6.1
Packaging group:
2
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. (contains METHYLGLYCINNITRILEDIACETONITRILE)
Chemical name:
METHYLGLYCINNITRILEDIACETONITRILE
Class:
6.1
Packaging group:
2
Labels:
6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 2811
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S. (contains METHYLGLYCINNITRILEDIACETONITRILE)
Chemical name:
METHYLGLYCINNITRILEDIACETONITRILE
Class:
6.1
Packaging group:
2
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Combination filter for
gases/vapours of organic, inorganic, acid inorganic, alkaline compounds and toxic particles (e. g. EN
14387 Type ABEK-P3) Suitable respiratory protection for higher concentrations or long-term effect:
Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

Substances to avoid:
alkalies
Hazardous reactions:
No hazardous reactions when stored and handled according to instructions. Evolution of ammonia
under influence of alkalies.
Hazardous decomposition products:
hydrogen cyanide, acetaldehyde, 2-Butenal, ammonia

Disposal considerations

Must be dumped or incinerated in accordance with local regulations.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.