Registration Dossier
Registration Dossier
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EC number: 231-119-8 | CAS number: 7440-09-7
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
Attention: Potassium reacts spontaneous with water to perform potassium hydroxide and hydrogen gas which burns spontaneous with air (possibility of explosion). The performed potassium hydroxide is a well known base which leads to aqueous solutions with a pH-value above 11.5. So keep in mind, that if contact via different routes occure first of all the reaction of potassium with water takes place. The described measures are in accordance with the reaction-product potassium hydroxide.
1 Description of first aid measures
General information:
· Take affected persons out of danger area and lay down.
· Immediately remove any clothing soiled by the product.
· In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
· Supply fresh air or oxygen; call for doctor.
· In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
· Immediately rinse with water.
· Call a doctor immediately.
After eye contact:
· IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
· Call a doctor immediately.
After swallowing:
· Rinse out mouth and then drink plenty of water.
· Do NOT induce vomiting.
· Call for a doctor immediately.
2 Most important symptoms and effects, both acute and delayed No further relevant information available.
3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
1 Description of first aid measures
General information:
· Take affected persons out of danger area and lay down.
· Immediately remove any clothing soiled by the product.
· In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
· Supply fresh air or oxygen; call for doctor.
· In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
· Immediately rinse with water.
· Call a doctor immediately.
After eye contact:
· IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
· Call a doctor immediately.
After swallowing:
· Rinse out mouth and then drink plenty of water.
· Do NOT induce vomiting.
· Call for a doctor immediately.
2 Most important symptoms and effects, both acute and delayed No further relevant information available.
3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
Attention: Potassium reacts spontaneous with water to perform potassium hydroxide and hydrogen gas which burns spontaneous with air (possibility of explosion).
1 Extinguishing media
Suitable extinguishing agents:
· Extinguish with dry agent.
· Use fire extinguishing methods suitable to surrounding conditions.
For safety reasons unsuitable extinguishing agents: Do not use water, foam or carbon dioxide to extinguish.
2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
· Carbon monoxide
· Carbon dioxide
· Potassium oxides
Remove undamaged containers away from heat radiation.
Use water spray to knock down fire fumes if possible.
1 Extinguishing media
Suitable extinguishing agents:
· Extinguish with dry agent.
· Use fire extinguishing methods suitable to surrounding conditions.
For safety reasons unsuitable extinguishing agents: Do not use water, foam or carbon dioxide to extinguish.
2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
· Carbon monoxide
· Carbon dioxide
· Potassium oxides
Remove undamaged containers away from heat radiation.
Use water spray to knock down fire fumes if possible.
Accidental release measures
Attention: Potassium reacts spontaneous with water to perform potassium hydroxide and hydrogen gas which burns spontaneous with air (possibility of explosion).
1 Personal precautions, protective equipment and emergency procedures
· Ensure adequate ventilation.
· Wear protective equipment. Keep unprotected persons away.
· Avoid formation of dust.
· Keep away from ignition sources.
2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
3 Methods and material for containment and cleaning up:
· Use neutralising agent.
· Pick up mechanically.
· Do not flush with water or aqueous cleansing agents
· Dispose of the material collected according to regulations.
1 Personal precautions, protective equipment and emergency procedures
· Ensure adequate ventilation.
· Wear protective equipment. Keep unprotected persons away.
· Avoid formation of dust.
· Keep away from ignition sources.
2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
3 Methods and material for containment and cleaning up:
· Use neutralising agent.
· Pick up mechanically.
· Do not flush with water or aqueous cleansing agents
· Dispose of the material collected according to regulations.
Handling and storage
Attention: Potassium reacts spontaneous with water to perform potassium hydroxide and hydrogen gas which burns spontaneous with air (possibility of explosion).
1 Precautions for safe handling
· Prevent formation of dust.
· Any unavoidable deposit of dust must be regularly removed.
· Ensure good ventilation/exhaustion at the workplace.
· Handle under inert gas or under other appropriate inert conditions.
Information about fire and explosion protection:
· Dust can combine with air to form an explosive mixture.
· Keep ignition sources away - Do not smoke.
· Protect against electrostatic charges.
2 Conditions for safe storage, including any incompatibilities
Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
· Information about storage in one common storage facility: Store away from oxidising agents.
· Store under inert gas or under other appropriate inert conditions.
Further information about storage conditions:
· Keep container tightly sealed.
· Store in cool, dry conditions in well sealed receptacles.
· Protect from heat and direct sunlight.
· Never allow product to get in contact with water during storage.
3 Specific end use(s) No further relevant information available.
1 Precautions for safe handling
· Prevent formation of dust.
· Any unavoidable deposit of dust must be regularly removed.
· Ensure good ventilation/exhaustion at the workplace.
· Handle under inert gas or under other appropriate inert conditions.
Information about fire and explosion protection:
· Dust can combine with air to form an explosive mixture.
· Keep ignition sources away - Do not smoke.
· Protect against electrostatic charges.
2 Conditions for safe storage, including any incompatibilities
Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
· Information about storage in one common storage facility: Store away from oxidising agents.
· Store under inert gas or under other appropriate inert conditions.
Further information about storage conditions:
· Keep container tightly sealed.
· Store in cool, dry conditions in well sealed receptacles.
· Protect from heat and direct sunlight.
· Never allow product to get in contact with water during storage.
3 Specific end use(s) No further relevant information available.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2257
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2257
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2257
Shipping information
- Proper shipping name and description:
- POTASSIUM
- Chemical name:
- Potassium
- Labels:
- 4.3
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2257
Shipping information
- Proper shipping name and description:
- POTASSIUM
- Chemical name:
- Potassium
- Labels:
- 4.3
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Attention: Potassium reacts spontaneous with water to perform potassium hydroxide and hydrogen gas which burns spontaneous with air (possibility of explosion).
1 Control parameters
Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
· Do not eat, drink, smoke or sniff while working.
· Keep away from foodstuffs, beverages and feed.
· Immediately remove all soiled and contaminated clothing.
· Store protective clothing separately.
· Do not inhale gases / fumes / aerosols.
· Avoid contact with the eyes and skin.
· The usual precautionary measures are to be adhered to when handling chemicals.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
· Protective gloves
· Only use chemical-protective gloves with CE-labelling of category III.
· The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
· Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
· The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
· Nitrile rubber
Penetration time of glove material
· The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· 480 min
Eye protection: Safety glasses
Body protection: Protective work clothing
1 Control parameters
Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
· Do not eat, drink, smoke or sniff while working.
· Keep away from foodstuffs, beverages and feed.
· Immediately remove all soiled and contaminated clothing.
· Store protective clothing separately.
· Do not inhale gases / fumes / aerosols.
· Avoid contact with the eyes and skin.
· The usual precautionary measures are to be adhered to when handling chemicals.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
· Protective gloves
· Only use chemical-protective gloves with CE-labelling of category III.
· The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
· Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
· The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
· Nitrile rubber
Penetration time of glove material
· The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· 480 min
Eye protection: Safety glasses
Body protection: Protective work clothing
Stability and reactivity
Attention: Potassium reacts spontaneous with water to perform potassium hydroxide and hydrogen gas which burns spontaneous with air (possibility of explosion).
1 Reactivity No further relevant information available.
2 Chemical stability No decomposition if used and stored according to specifications.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
3 Possibility of hazardous reactions: Reacts violently with water.
4 Conditions to avoid: Exposure to moisture
5 Incompatible materials:
Oxidizing agents, Carbon oxides, Reacts violently with water., Reacts with water to generate Hydrogen gas.
6 Hazardous decomposition products: No dangerous decomposition products known besides hydrogen gas which burns spontaneously with air (possibility of explosion).
1 Reactivity No further relevant information available.
2 Chemical stability No decomposition if used and stored according to specifications.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
3 Possibility of hazardous reactions: Reacts violently with water.
4 Conditions to avoid: Exposure to moisture
5 Incompatible materials:
Oxidizing agents, Carbon oxides, Reacts violently with water., Reacts with water to generate Hydrogen gas.
6 Hazardous decomposition products: No dangerous decomposition products known besides hydrogen gas which burns spontaneously with air (possibility of explosion).
Disposal considerations
Attention: Potassium reacts spontaneous with water to perform potassium hydroxide and hydrogen gas which burns spontaneous with air (possibility of explosion).
Waste treatment methods
· Recommendation: Must be specially treated adhering to official regulations.
Uncleaned packaging
· Recommendation: Disposal must be made according to official regulations.
Before disposal the potassium has to be destroyed by quenching with cooled isopropanole in an cooled vessel under inert conditions. After quenching all potassium, the remainig basic solution has to be neutralised and disposed according to official regulations.
Waste treatment methods
· Recommendation: Must be specially treated adhering to official regulations.
Uncleaned packaging
· Recommendation: Disposal must be made according to official regulations.
Before disposal the potassium has to be destroyed by quenching with cooled isopropanole in an cooled vessel under inert conditions. After quenching all potassium, the remainig basic solution has to be neutralised and disposed according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
