Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

- After inhalation: Remove to fresh air. Keep patient warm. Seek immediately medical advice.

- After skin contact: Remove contaminated clothing. Wash with plenty of water.

- After eye contact: Wash immediately with plenty of water for 15 min or Diphotérine®. Alert a physician.

- After swallowing: Do not make the victim vomit. Do not give anything orally. Alert a physician.

- Instructions for the physician: Treat according to symptoms. Keep the victim under medical surveillance.

Fire-fighting measures

Suitable extinguishing media: CO2, powder, foam.

Special risks : toxic gases when in contact with fire : COx, HBr.

Inadvisable media : water jet

Special protective equipment for fire-fighting : Wear a complete protection equipment and a self-contained respiratory apparatus.

Other information: Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

Person related precautionary measures : Use personal protective equipment. Avoid breathing dusts. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.

Environmental-protection measures: Wear gloves, mask with cartridge (ABP) adapted for chemical uses

Procedures for cleaning / absorption: Keep out of drains, prevent entry in natural environment; Recover with an appropriate material, clean the place with an absorbing product and put the whole in a container. Ventilate the place and wash the spreaded zone

Handling and storage

HANDLING
Avoid contact with skin, eyes.
Avoid exposure to dusts.

STORAGE
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Packaging group:
III
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,4-Dibromobenzene)
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Class:
9
Packaging group:
III
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,4-Dibromobenzene)
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Class:
9
Packaging group:
III
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,4-Dibromobenzene)
Remarksopen allclose all

Additional transport information

Additional transport information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

Exposure controls / personal protection

Personal protective equipment:
 Respiratory protection: Dust respirator, Cartridge (AB+P) mask or a self contained respiratory apparatus
 Eye protection: Chemical safety goggles
 Hand protection: Suitable gloves (nitrile, latex, vinyle) adapted to chemical uses (EN374)
 Body protection : Standard working suit

Industrial hygiene : Wear the protective equipment. Handle under fumehood. Do not eat nor drink at the workplace. Wash hands and face after handling.

Stability and reactivity

- Stability : stable in standard conditions of use.
- Conditions to be avoided : Heat, flame, sparks, moisture.
- Hazardous decomposition products: COx, HBr.
- Products to be avoided: Strong oxydising agents.
- Hazardous reaction : possibility of thermal decomposition

Disposal considerations