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Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
February 2010
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment
Qualifier:
no guideline followed
Principles of method if other than guideline:
Differrential scanning calorimetry and visual observation
GLP compliance:
no
Type of method:
differential scanning calorimetry
Specific details on test material used for the study:
5 differents test item were used
Melting / freezing pt.:
>= -10 - <= 35 °C
Decomposition:
no
Remarks on result:
other: pressure not specified but assumed to be ambient

DSC results:

Melting peaks were observed only on the DSC analysis of sample 4: two peaks observed around 20°C and 35°C.

For other samples, DSC analysis didn't give reliable results.

The DSC measurement was not an appropriate method to determine the test item melting point.

Additionals studies:

First test: -10°C for 10 hours

The freezing point of sample 2 was <-10°C.

The freezing point of sample 1 was determined to be between -10°C and 20°C.

Second test: 4°C for 5 hours

Sample 1 didn't change and was still solid.

Third test: heating in a water bath

Sample 1 still at solid state was heated in the water bath.

The test item started to melt at 30°C.

Conclusions:
It was very difficult to determine the melting point of test item.
From tests performed with 5 different samples, the following range was stated: -10°C - 35°C.
Executive summary:

The study was performed to determine the melting point of test item using DSC and heating/cooling phase with visual observation.

It was very difficult to determine the melting point of test item.

From tests performed with 5 different samples, the following range was stated: -10°C - 35°C.

Description of key information

A melting range was stated as: -10°C - 35°C

Key value for chemical safety assessment

Additional information

The data comes from an internal report provided by supplier.