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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Description of first aid measures
· General information:
Personal protection for the First Aider.
Immediately remove any clothing soiled by the product.
· After inhalation:
Take affected persons into fresh air and keep quiet.
Call a doctor immediately.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact:
Call a doctor immediately.
Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Drink plenty of water and provide fresh air. Call for a doctor immediately.

Most important symptoms and effects, both acute and delayed
No further relevant information available.

Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

Extinguishing media
· Suitable extinguishing agents:
Fire-extinguishing powder
Carbon dioxide

Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Hydrogen chloride (HCl)
Phosgene gas
During heating or in case of fire poisonous gases are produced.

Advice for firefighters
· Protective equipment:
Wear fully protective suit.
Mouth respiratory protective device.
Wear self-contained respiratory protective device.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.

Environmental precautions:
Do not allow to penetrate the ground/soil.
Do not allow to enter sewers/ surface or ground water.

Methods and material for containment and cleaning up:
Send for recovery or disposal in suitable receptacles.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralising agent.
Dispose contaminated material as waste.
Ensure adequate ventilation.

Handling and storage

Precautions for safe handling
Keep receptacles tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection: Keep respiratory protective device available.

Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility:
Store away from water.
Store away from oxidising agents.
Amine

Further information about storage conditions:
Protect from humidity and water.
Keep container tightly sealed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN3265
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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.

Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Do not eat, drink, smoke or sniff while working.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use self-contained respiratory protective device.

· Protection of hands:Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
Fluorocarbon rubber (Viton)
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to
be observed.
· Not suitable are gloves made of the following materials:
Strong material gloves
Leather gloves
Natural rubber, NR
Nitrile rubber, NBR
Butyl rubber, BR
PVC gloves

Eye protection:Tightly sealed goggles

Body protection:
Use protective suit.
Protective work clothing

Stability and reactivity

Reactivity No further relevant information available.

Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.

Possibility of hazardous reactions
Reacts with water.
Reacts with alkali (lyes).
Reacts with amines.
Reacts with oxidising agents.

Conditions to avoid No further relevant information available.

Incompatible materials: No further relevant information available.

Hazardous decomposition products:
Hydrogen chloride (HCl)
Phosgen

Disposal considerations

Waste treatment methods
· Recommendation
After prior treatment product has to be disposed of in an incinerator for hazardous waste adhering to
the regulations pertaining to the disposal of particularly hazardous waste.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.