Registration Dossier

Physical & Chemical properties

Vapour pressure

Currently viewing:

Administrative data

Link to relevant study record(s)

Referenceopen allclose all

Endpoint:
vapour pressure
Type of information:
calculation (if not (Q)SAR)
Adequacy of study:
weight of evidence
Study period:
9th - 19th September, 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
23rd March 2006
Deviations:
no
GLP compliance:
not specified
Type of method:
other: estimation using the Grain-Watson method
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: 7703200
- Expiration date of the lot/batch: 2019-02-28
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
<= 4.7 Pa
Test no.:
#2
Temp.:
50 °C
Vapour pressure:
<= 46 Pa

DSC plots are attached.

Conclusions:
The test item has an estimated vapour pressure of <= 4.7 Pa at 20 °C.
Executive summary:

The vapour pressure of the test item was determined in accordance with OECD TG 104. The experimentally-determined vapour pressure of the test item at 20°C was not in the recommended range of 1 to 1000 mbars for DSC measurements. Therefore an estimation procedure in accordance with OECD TG 104 was used (Grain-Watson method). This method is applied for vapour pressures between 10E03 to 10E-07 mbar. The estimated vapour pressure is <= 4.7 Pa at 20 °C and <=46 Pa at 50 °C.

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
2017-06-13 - 2017-06-13
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
not specified
Type of method:
static method
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
0.45 Pa
Conclusions:
The vapour pressure was 0.45 Pa at 20 °C.
Executive summary:

The vapour pressure of the test item was measured according to EU Method A.4 (Static method). The vapour pressure was 0.45 Pa at 20 °C.

Description of key information

Based on a weight of evidence approach the test item has an estimated vapour pressure of 0.45 Pa at 20°C.

Key value for chemical safety assessment

Vapour pressure:
0.45 Pa
at the temperature of:
20 °C

Additional information

The vapour pressure of the test item was determined in accordance with OECD TG 104. The experimentally-determined vapour pressure of the test item at 20°C was not in the recommended range of 1 to 1000 mbars for DSC measurements. Therefore an estimation procedure in accordance with OECD TG 104 was used (Grain-Watson method). This method is applied for vapour pressures between 10E03 to 10E-07 mbar. The estimated vapour pressure is <= 4.7 Pa at 20°C and <=46 Pa at 50°C.

A measured vapour pressure is available for Phosphoric acid, C4 and C12-14(even numbered) alkyl esters. Since this substance contains similar chain lengths as the C8 -12 esters, and in addition, a significant proportion of C4 esters, this measured result is considered to be more representative of the likely vapour pressure of the substance and is adopted for exposure assessment.