3-((bis(diisopropylamino)phosphanyl)oxy)propanenitrile

Guidance on Safe Use

First-aid measures

- General Information: Immediately remove any clothing soiled by the product. Personal protection for the First Aider. May cause sensitization by skin contact.

- Following inhalation: Take affected persons into fresh air and keep quiet. If problems persist consult a doctor.

- Following skin contact: Take off contaminated clothing and wash before reuse. Immediately wash with water and soap and rinse thoroughly. Seek medical attention in case of problems or if problems persist.

- Following eye contact: Rinse opened eye for several minutes under running water. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention in case of problems or if problems persist.

- Following swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately.

- Most important symptoms and effects: No further relevant information available.

- Indication of any immediate medical attention and special treatment needed: First Aid, decontamination, treatment of symptoms.

Fire-fighting measures

- Suitable extinguishing media: Use fire extinguishing methods suitable to surrounding conditions. Water haze, Water spray, Foam, Fire-extinguishing powder, Carbon dioxide (CO2)

- Unsuitable extinguishing media: Water with full jet.

- Special hazards arising from the substance or mixture: The product is combustible.

- Advice for fire fighter: Wear self-contained respiratory protective device. Use appropriate protective equipment.

- Additional information: Move undamaged containers from immediate hazard area if it can be done safely.

Accidental release measures

- Personal precautions: Avoid formation of aerosols. Do not eat, drink, smoke or sniff while working. Avoid contact with the skin. Wear protective clothing. Ensure that washing facilities are available at the work place. Keep away from ignition sources.

- Environmental precautions: Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. Dumping into the environment must be prevented.

- Methods and material for containment and cleaning up: Keep away from ignition sources. Waste disposal according to official state regulations.

Handling and storage

- Precautions for safe handling: Do not eat, drink, smoke or sneeze at the workplace. Avoid contact with eyes or skin. Wear personal protective equipment. Wash contaminated clothing prior to re-use. If technical suction or ventilation measures are not possible or insufficient, respiratory protection must be worn. Handle with care. Avoid jolting, friction and impact. Ensure adequate ventilation.

- Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Usual measures for fire prevention. Take precautionary measures against electrostatic discharges. Ground/bond container and receiving equipment. The product is combustible.

- Conditions for safe storage, including any incompatibilities:

Storage:

Requirements to be met by storerooms and receptacles: Store only in the original container. Keep container tightly closed in a well-ventilated place.

Information about storage in one common storage facility: Keep away from food, drink and animal feeding stuffs.

Further information about storage conditions: Ensure that local, federal and national legislation on storage conditions are observed.

Storage class: 3 Flammable liquid substances (DE, TRGS 510)

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN1993

Shipping information

Proper shipping name and description:

1993 FLAMMABLE LIQUID, N.O.S.

Chemical name:

2-Cyanoethyl N,N, N', N'-tetraisopropylphosphorodiamidite

Language:

English

Labels:

3, Flammable liquids
Symbol (flammable liquid Hazard Class 3 transportation label)

Special provisions / remarks

Special provisions:

Transport/Additional information:
ADR:
Limited quantities (LQ): 1 L
Excepted quantities (EQ): Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
Transport category 2
Tunnel restriction code: D/E

IMDG
Limited quantities (LQ): 1 L
Excepted quantities (EQ): Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
UN "Model Regulation": UN 1993 FLAMMABLE LIQUID, N.O.S. (2-CYANOETHYL N,N, N',N'-TETRAISOPROPYLPHOSPHORODIAMIDITE), 3, II

Remarks:

Special precautions for user: Warning: Flammable liquids.
Danger code (Kemler): 30
EMS Number: F-E,S-E

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN1993

Shipping information

Proper shipping name and description:

1993 FLAMMABLE LIQUID, N.O.S.

Chemical name:

2-Cyanoethyl N,N, N', N'-tetraisopropylphosphorodiamidite

Labels:

3, Flammable liquids
Symbol (flammable liquid Hazard Class 3 transportation label)

Special provisions / remarks

Remarks:

Special precautions for user: Warning: Flammable liquids.
Danger code (Kemler): 30
EMS Number: F-E,S-E

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN1993

Shipping information

Proper shipping name and description:

1993 FLAMMABLE LIQUID, N.O.S.

Chemical name:

2-Cyanoethyl N,N, N', N'-tetraisopropylphosphorodiamidite

Labels:

3, Flammable liquids
Symbol (flammable liquid Hazard Class 3 transportation label)

Special provisions / remarks

Remarks:

Special precautions for user: Warning: Flammable liquids.
Danger code (Kemler): 30
EMS Number: F-E,S-E

Additional transport information

Additional information

Special provisions / remarks / other:

Transport/Additional information:

Limited quantities (LQ): 1 L
Excepted quantities (EQ): Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
Transport category 2
Tunnel restriction code: D/E

IMDG
Limited quantities (LQ): 1 L
Excepted quantities (EQ): Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
UN "Model Regulation": UN 1993 FLAMMABLE LIQUID, N.O.S. (2-CYANOETHYL N,N, N',
N'-TETRAISOPROPYLPHOSPHORODIAMIDITE), 3, II

Exposure controls / personal protection

Technical protection measures: Technical measures and the application of adequate working methods take priority over the use of personal protection equipment.

General protective and hygienic measures: Avoid contact with the eyes and skin. Take off contaminated clothing and wash before reuse. Ensure that washing facilities are available at the work place. Be sure to clean skin thoroughly after work and before breaks. Do not eat, drink, smoke or sniff while working.

Hand protection: Tested protective gloves are to be worn. When handling chemical substances, chemical protective gloves must be worn with CE label including a four digit code. Type of chemical protective gloves to choose depends on the concentration and quantity of dangerous substances as well as on work place specifications. In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the gloves. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Recommendation: Nitrile rubber, NBR

Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Body protection: Protective work clothing

Eye protection: Safety glasses with side shields

Respiratory protection: If technical suction or ventilation measures are not possible or are insufficient, protective breathing apparatus must be worn. The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If the concentration is exceeded, a self-contained breathing apparatus must be used!

Limitation and supervision of exposure into the environment: Dumping into the environment must be prevented.

Stability and reactivity

1. Reactivity: The product is stable under standard conditions (temperature, pressure) of storage and handling.

2. Chemical stability: The product is stable under standard conditions (temperature, pressure) of storage and handling.

3. Possibility of hazardous reactions: No dangerous reactions known.

4. Conditions to avoid: No further relevant information available.

5. Incompatible materials: No further relevant information available.

Disposal considerations

Waste treatment methods

Recommendation:

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

Waste disposal according to official state regulations.

Dumping into the environment must be prevented.

Uncleaned packaging:

Recommendation:

Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning.

Packagings that may not be cleansed are to be disposed of in the same manner as the product.