Registration Dossier

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2017-12-12 - 2017-12-14 (Experimental phase)
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Version / remarks:
Test method A.16. "Relative self-ignition temperature for solids" as described in the Council Regulation (EC) No 440/2008 of 30 May 2008 laying down test methods pursuant to Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH).
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
[8,20-dihydro-8,20-diphenyl-5,24:12,17-diimino-7,10:22,19-dinitrilodibenz[f,p][1,2,4,9,11,12,14,19]octaazacycloicosinato(2-)-N25,N26,N27,N28]iron
EC Number:
256-526-8
EC Name:
[8,20-dihydro-8,20-diphenyl-5,24:12,17-diimino-7,10:22,19-dinitrilodibenz[f,p][1,2,4,9,11,12,14,19]octaazacycloicosinato(2-)-N25,N26,N27,N28]iron
Cas Number:
50293-39-5
Molecular formula:
C32H18FeN12
IUPAC Name:
[8,20-dihydro-8,20-diphenyl-5,24:12,17-diimino-7,10:22,19-dinitrilodibenz[f,p][1,2,4,9,11,12,14,19]octaazacycloicosinato(2-)-N25,N26,N27,N28]iron
Test material form:
solid
Remarks:
dark

Results and discussion

Relative self-ignition temperature (solids)
Key result
Relative self-ignition temperature:
280 °C

Applicant's summary and conclusion

Conclusions:
The self-ignition temperature was determined in a GLP study according to EU method A.16 without deviations on the registered substance itself. Hence, there is no indication given that the results are not reliable. The test item reaches 400 °C by self heating. The test item has a Relative Self-lgnition Temperature of 280 °C according to the definition in the Council Regulation (EC) No 440/2008, method A. 16.
Executive summary:

Auto flammability was determined according to EU method A.16 in a study classified as Klimisch 1.The test item reaches 400 °C by self heating. The test item has a Relative Self-lgnition Temperature of 280 °C.