Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
In case of inhalation
- Move to fresh air in case of accidental inhalation of fumes from overheating or combustion.
- Oxygen or artificial respiration if needed.
In case of skin contact
- Wash off with soap and water.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- If eye irritation persists, consult a specialist.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- If symptoms persist, call a physician.
Most important symptoms and effects, both acute and delayed
In case of inhalation
Effects
- No adverse effects are normally expected.
In case of skin contact
Effects
- No adverse effects are normally expected.
In case of eye contact
Effects
- Contact with eyes may cause irritation.
- Redness
In case of ingestion
Symptoms
- Ingestion may provoke the following symptoms:
- Nausea
- Vomiting
- Diarrhoea
Indication of any immediate medical attention and special treatment needed
Notes to physician
- None

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Unsuitable extinguishing media
- None
Special hazards arising from the substance or mixture
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF), Fluorophosgene
Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Ensure adequate ventilation.
- Material can create slippery conditions.
- Sweep up to prevent slipping hazard.
- Keep away from open flames, hot surfaces and sources of ignition.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up
- Soak up with inert absorbent material.
- Suitable material for picking up.
- Dry sand
- Earth
- Shovel into suitable container for disposal.
Reference to other sections
- Refer to protective measures listed in sections 7 and 8 of SDS

Handling and storage

Precautions for safe handling
- Ensure adequate ventilation.
- Use personal protective equipment.
- Keep away from heat and sources of ignition.
- To avoid thermal decomposition, do not overheat.
- Take measures to prevent the build up of electrostatic charge.
- Clean and dry piping circuits and equipment before any operations.
- Ensure all equipment is electrically grounded before beginning transfer operations.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Keep away from heat and sources of ignition.
- Keep in properly labelled containers.
- Keep away from combustible material.
- Keep away from incompatible products
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.
Packaging material
Suitable material
- glass
- Plastic materials.
Specific end use(s)
- Contact your supplier for additional information

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Exposure controls
Control measures
Engineering measures
- Provide local ventilation appropriate to the product decomposition risk (see section 10).
- Refer to protective measures listed in sections 7 and 8.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- In case of decomposition (see section 10), use an air breathing apparatus with face mask.
- Use only respiratory protection that conforms to international/ national standards.
Hand protection
- Wear protective gloves.
Suitable material
- Nitrile rubber
- PVC
- Neoprene gloves
- butyl-rubber
- Take note of the information given by the producer concerning permeability and break through times, and of special
workplace conditions (mechanical strain, duration of contact).
Eye protection
- Tightly fitting safety goggles
Skin and body protection
- Wear work overall and safety shoes.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.

Stability and reactivity

Reactivity
- No dangerous reaction known under conditions of normal use.
Chemical stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- To avoid thermal decomposition, do not overheat.
- Keep away from flames and sparks.
Incompatible materials
- Alkali metals (molten form)
- Aluminum and magnesium in powder form above 100°C
10.6 Hazardous decomposition products
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
- Hydrogen chloride gas

Disposal considerations

Waste treatment methods
Product Disposal
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- Dispose of in accordance with local regulations.
Advice on cleaning and disposal of packaging
- Empty containers can be landfilled, when in accordance with the local regulations.