Registration Dossier

Administrative data

First-aid measures

4.1 Description of first aid measures
General information: Immediately remove any clothing soiled by the product.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: If symptoms persist consult doctor.
4.2 Most important symptoms and effects, both acute and delayed:
No further relevant information available.
Eyes: Dust may irritate eyes !
Hazards and systemic effects: No specific hazards known.
Possible routes of intake: Intake by swallowing or inhalation of dust.
Chronic effects: No chronic effects known.
4.3 Indication of any immediate medical attention and special treatment needed No specific antidote. Symptomatic treatment.

Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents: No restriction in large fires.
5.2 Special hazards arising from the substance or mixture: The possibility of formation of explosive dust/air mixtures under certain conditions should be basically considered during handling and processing.
In case of fire, the following can be released:
Carbon monoxide (CO)
Nitrogen oxides (NOx)
Sulphur dioxide (SO2)
5.3 Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
Chemical resistant protective suit. Under the protective suit a fire protective suit according to EN 469 should be applied.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
Avoid contact with eyes and skin and clothes.
Do not breathe dust.
Access only for trained personnel with personal protective equipment.
Use respiratory protective device against the effects of fumes/dust/ aerosol.
Avoid spillage of product into the environment.
Avoid formation of dust.
6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
6.3 Methods and material for containment and cleaning up:
Pick up mechanically. If formation of dust cannot be avoided use respiratory filter device. Dispose contaminated material as waste

Handling and storage

7.1 Precautions for safe handling: Empty containers must not be used for other products.
Contaminated protective equipment should be cleaned before taking it off.
Ensure good ventilation/exhaustion at the workplace.
Fill only in dedicated and assigned containers.
Keep containers tightly sealed.
7.2 Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles: Store in a dry location, keep away from humidity. Store in a cool location.
Suitable materials: Precious steel
Glass
Enamel
Steel with plastic inliner.
Information about storage in one common storage facility: Store away from oxidising agents.
7.3 Specific end use(s): This product is exclusively dedicated for the application as isolated and transported intermediate under strictly controlled conditions according to Article 18 of Regulation EC 1907/2006.

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,2'-dithiodianiline)
Chemical name:
2,2'-dithiodianiline
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,2' -dithiodianiline) , MARINE POLLUTANT
Chemical name:
2,2' -dithiodianiline
Language:
English
Class:
9
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,2' -dithiodianiline) , MARINE POLLUTANT
Chemical name:
2,2' -dithiodianiline
Class:
9
Packaging group:
III
EmS code:
F-A,S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,2'-dithiodianiline)
Chemical name:
2,2'-dithiodianiline
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Additional information about design of technical facilities: Take care of sufficient ventilation. Avoid formation of dust.
Waste gases should be led into the atmosphere only via appropriate separators, scrubbers or incinerators.
Exposure controls: This product is exclusively dedicated for the application as isolated and transported intermediate under strictly controlled conditions according to Article 18 of Regulation EC 1907/2006.
Personal protective equipment
General protective and hygienic measures: Contaminated protective suit shall be cleaned before taking it off. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work.
Store protective clothing separately.
Respiratory protection: Particle fi lter. The fi lter grade (P1 - P3) has to be established depending on work-place related limit values and the actual exposition.
Protection of hands: Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
For the permanent contact gloves made of
the following materials are suitable: Butyl rubber, BR; Nitrile rubber, NBR; Neoprene gloves.
Check for tightness before use. Replace damaged gloves.
Eye protection: Safety glasses.
Body protection: Selection of personal protective suits depending on amount and concentration of hazardous material and on possible exposition at the working place.
Limitation and supervision of exposure into the environment: Avoid spillage of product into the environment.
Use this material only in closed systems and devices. In case of open plant systems use local exhaust and collecting trays. Follow emission limit values. Measures in case of unwanted emissions should be established.
Risk management measures: General protective and hygienic measures have to be observed.
Handling and use of this material/formulation only under controlled conditions in closed systems.
Employees who use this material/formulation must be trained and demonstrably instructed about possible risks for man and environment.
Measures for prevention of hazards in case of unwanted leakage shall be implemented.

Stability and reactivity

Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Sensitive to: Water: Protect from moisture.
10.3 Possibility of hazardous reactions: The possibility of formation of explosive dust/air mixtures under certain conditions should be principally considered during handling and processing.
10.4 Conditions to avoid: See section handling and storage.
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition products:
Nitrogen oxides
Sulphur dioxide
Carbon monoxide and carbon dioxide

Disposal considerations

13.1 Waste treatment methods
Recommendation:
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations. If possible recovery or recycling.
Uncleaned packaging
Recommendation: Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning. Contaminated containers or containers with residual amounts must be
treated as hazardous wastes.
Appropriate disposal: Empty container completely. Storage in a safe place after emptying.