Registration Dossier
Registration Dossier
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EC number: 222-222-9 | CAS number: 3390-61-2
Auto flammability
Administrative data
Link to relevant study record(s)
- Endpoint:
- auto-ignition temperature (liquids)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2015-12-14 to 2014-12-17
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- GLP compliance:
- yes (incl. QA statement)
- Key result
- Auto-ignition temperature:
- 483 °C
- Atm. press.:
- 1 013 hPa
- Conclusions:
- An autoflammability value of 483±3°C at 1013 hPa was determined for the substance in accordance with a relevant test method and in compliance with GLP. The result is considered to be reliable.
Reference
Preliminary test:
Volume of test item injected in the oven: 70µL
Assay No. |
Temperature of the assay (°C) |
Auto ignition |
Maximal temperature of the air recorded in the centre of the flask after auto ignition (°C) |
Atmospheric pressure (kPa) |
Relative humidity (%) |
|||
Observed |
Corrected |
Y/N |
Lag (S) |
Observed |
Corrected |
|||
1 |
100 |
100 |
No |
/ |
/ |
/ |
98.4 |
38 |
2 |
149 |
149 |
No |
/ |
/ |
/ |
98.4 |
39 |
3 |
203 |
203 |
No |
/ |
/ |
/ |
98.5 |
39 |
4 |
255 |
255 |
No |
/ |
/ |
/ |
98.6 |
40 |
5 |
303 |
303 |
No |
/ |
/ |
/ |
99.0 |
37 |
6 |
350 |
349 |
No |
/ |
/ |
/ |
99.0 |
38 |
7 |
400 |
399 |
No |
/ |
/ |
/ |
98.9 |
39 |
8 |
450 |
449 |
No |
/ |
/ |
/ |
98.9 |
38 |
9 |
504 |
503 |
Yes |
10 |
550 |
549 |
98.9 |
38 |
10 |
493 |
492 |
Yes |
50 |
532 |
531 |
98.9 |
40 |
11 |
483 |
482 |
No |
/ |
/ |
/ |
98.9 |
42 |
The auto ignition temperature was situated between 482°C and 492°C (corrected values). This range is given for information, the final result is given by the main test in following section.
Main test:
Volume of test item injected in the oven: 70µL
Assay No. 1
Assay No. |
Temperature of the assay (°C) |
Auto ignition |
Maximal temperature of the air recorded in the centre of the flask after auto ignition (°C) |
Atmospheric pressure (kPa) |
Relative humidity (%) |
|||
Observed |
Corrected |
Y/N |
Lag (S) |
Observed |
Corrected |
|||
1 |
486 |
485 |
Yes |
32 |
495 |
494 |
99.4 |
43 |
2 |
484 |
483 |
No |
/ |
/ |
/ |
99.5 |
41 |
3 |
485 |
484 |
No |
/ |
/ |
/ |
99.5 |
44 |
Assay No. 2
Assay No. |
Temperature of the assay (°C) |
Auto ignition |
Maximal temperature of the air recorded in the centre of the flask after auto ignition (°C) |
Atmospheric pressure (kPa) |
Relative humidity (%) |
|||
Observed |
Corrected |
Y/N |
Lag (S) |
Observed |
Corrected |
|||
1 |
484 |
483 |
Yes |
71 |
500 |
499 |
99.4 |
45 |
2 |
483 |
482 |
No |
/ |
/ |
/ |
99.4 |
46 |
Assay No. 3
Assay No. |
Temperature of the assay (°C) |
Auto ignition |
Maximal temperature of the air recorded in the centre of the flask after auto ignition (°C) |
Atmospheric pressure (kPa) |
Relative humidity (%) |
|||
Observed |
Corrected |
Y/N |
Lag (S) |
Observed |
Corrected |
|||
1 |
483 |
482 |
No |
/ |
/ |
/ |
99.5 |
47 |
2 |
484 |
483 |
No |
/ |
/ |
/ |
99.5 |
46 |
3 |
485 |
484 |
No |
/ |
/ |
/ |
99.5 |
46 |
4 |
486 |
485 |
Yes |
46 |
498 |
497 |
99.5 |
46 |
Assay No. 4
Assay No. |
Temperature of the assay (°C) |
Auto ignition |
Maximal temperature of the air recorded in the centre of the flask after auto ignition (°C) |
Atmospheric pressure (kPa) |
Relative humidity (%) |
|||
Observed |
Corrected |
Y/N |
Lag (S) |
Observed |
Corrected |
|||
1 |
486 |
485 |
No |
/ |
/ |
/ |
99.3 |
34 |
2 |
487 |
486 |
No |
/ |
/ |
/ |
99.3 |
36 |
3 |
488 |
487 |
Yes |
23 |
496 |
495 |
99.3 |
36 |
Assay No. 5
Assay No. |
Temperature of the assay (°C) |
Auto ignition |
Maximal temperature of the air recorded in the centre of the flask after auto ignition (°C) |
Atmospheric pressure (kPa) |
Relative humidity (%) |
|||
Observed |
Corrected |
Y/N |
Lag (S) |
Observed |
Corrected |
|||
1 |
487 |
486 |
Yes |
66 |
503 |
502 |
99.3 |
39 |
2 |
485 |
484 |
No |
/ |
/ |
/ |
99.9 |
39 |
3 |
486 |
485 |
No |
/ |
/ |
/ |
99.1 |
42 |
Conclusion:
Only the runs with an auto ignition observed for each assay are summarised in the following table.
Assay No. |
Auto-ignition temperature (°C) |
Auto-ignition |
Maximal temperature of the air recorded in the centre of the flask after auto ignition (°C) |
Atmospheric pressure (kPa) |
Relative humidity (%) |
||
Observed |
Corrected |
Lag (s) |
Observed |
Corrected |
|||
1 |
486 |
485 |
32 |
495 |
494 |
99.4 |
43 |
2 |
484 |
483 |
71 |
500 |
499 |
99.4 |
45 |
3 |
486 |
485 |
46 |
498 |
497 |
99.5 |
46 |
4 |
488 |
487 |
23 |
496 |
495 |
99.3 |
36 |
5 |
487 |
486 |
66 |
503 |
502 |
99.1 |
42 |
The auto-ignition temperature of the test item was 483±3°C (corrected temperature)
Description of key information
Autoignition temperature: 483°C (EU Method A.15)
Key value for chemical safety assessment
- Autoflammability / Self-ignition temperature at 101 325 Pa:
- 483 °C
Additional information
An autoignition temperature of 483±3°C was determined in a reliable study conducted according to an appropriate test protocol, and in compliance with GLP.
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