Registration Dossier

Administrative data

First-aid measures

- General advice: Take affected persons out of danger area and lay down.
Immediately remove any clothing soiled by the product.
In case of irregular breathing or respiratory arrest provide artificial respiration.
- Following inhalation: Supply fresh air.
- Following skin contact: Immediately rinse with water.
If skin irritation continues, consult a doctor.
- Following eye contact: Rinse opened eye for several minutes under running water.
Remove contact lenses, if present and easy to do. Continue rinsing.
- Following ingestion: Rinse out mouth and then drink plenty of water.
- Most important symptoms and effects: No further relevant information available.

Fire-fighting measures

- Suitable extinguishing media: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
- Unsuitable extinguishing media: Water with full jet
- Special hazards arising from the substance or mixture: Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Carbon monoxide
Carbon dioxide
Nitrogen oxides (NOx)
- Advice for fire fighter:
Protective equipment: Wear self-contained respiratory protective device.
Additional information
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage system.

Accidental release measures

- Personal precautions / Protective equipment and emergency procedures: Ensure adequate ventilation.
Wear protective equipment. Keep unprotected persons away.
- Environmental precautions: Do not allow to enter sewers/ surface or ground water.
- Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of the material collected according to regulations.

Handling and storage

- Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols
Information about fire and explosion protection: No special measures required.
- Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
Information about storage in one common storage facility: Store away from oxidising agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.

Transport information

Land transport (ADR/RID)

UN number:
2206
Proper shipping name and description:
UN 2206, ISOCYANATES, TOXIC, N.O.S. (DIETHYL TOLUENEDIISOCYANATE)
Chemical name:
DIETHYL TOLUENEDIISOCYANATE
Language:
English
Class:
6.1
Classification code:
6.1
Packaging group:
II
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2206
Proper shipping name and description:
UN 2206, ISOCYANATES, TOXIC, N.O.S. (DIETHYL TOLUENEDIISOCYANATE)
Chemical name:
DIETHYL TOLUENEDIISOCYANATE
Language:
English
Class:
6.1
Classification code:
6.1
Packaging group:
II
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2206
Proper shipping name and description:
ISOCYANATES, TOXIC, N.O.S. (DIETHYL TOLUENEDIISOCYANATE)
Chemical name:
DIETHYL TOLUENEDIISOCYANATE
Class:
6.1
Packaging group:
II
EmS code:
F-A, S-A
Labels:
6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2206
Proper shipping name and description:
ISOCYANATES, TOXIC, N.O.S. (DIETHYL TOLUENEDIISOCYANATE)
Chemical name:
DIETHYL TOLUENEDIISOCYANATE
Class:
6.1
Packaging group:
II
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

1. Technical protection measures
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
2. Organisational protection measures
Personal protective equipment:
General protective and hygienic measures:
Do not eat, drink, smoke or sniff while working.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Store protective clothing separately.
The usual precautionary measures are to be adhered to when handling chemicals.
3. Hand protection: Protective gloves
Only use chemical-protective gloves with CE-labelling of category III.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
4. Feet protection
No additional information available
5. Body protection
Protective work clothing
6. Eye protection
Tightly sealed goggles
7. Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

Stability and reactivity

1. Reactivity : No further relevant information available.
2. Chemical stability : No decomposition if used and stored according to specifications.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
3. Possibility of hazardous reactions : No dangerous reactions known.
4. Conditions to avoid : No further relevant information available.
5. Incompatible materials : No further relevant information available.
6. Hazardous decomposition products: No dangerous decomposition products known.

Disposal considerations

Waste treatment methods
· Recommendation: Must be specially treated adhering to official regulations.
Uncleaned packaging
· Recommendation: Disposal must be made according to official regulations.