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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
Qualifier:
according to guideline
Guideline:
other: OECD 113
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Trimorpholinophosphine oxide
EC Number:
224-662-7
EC Name:
Trimorpholinophosphine oxide
Cas Number:
4441-12-7
Molecular formula:
C12H24N3O4P
IUPAC Name:
trimorpholinophosphine oxide
Test material form:
solid

Results and discussion

Small-scale preliminary testsopen allclose all
Key result
Parameter:
sensitiveness to impact: impact energy (J)
Remarks on result:
negative (not further specified)
Key result
Parameter:
sensitiveness to friction: friction load (N)
Remarks on result:
negative (not further specified)
Key result
Parameter:
thermal sensitivity - Koenen test: limiting diameter (mm)
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

Thermal stability:

One DSC measurement showed an endothermal effect in the temperature range of 185 -200 °C and an exothermal effect in the temperature range of 320 -425 °C.

Explosive properties:

a) a test of thermal sensitivity:

Three tests were performed with a circular nozzle plate with a hole of 2 mm diameter. No explosion was observed.

b) a test of mechanical sensitivity with respect to shock:

The test item was sieved (mesh size 0.5 mm) before the measurement. No explosion within 6 tests using a mass of 10 kg falling from a height of 0.4 m was observed.

c) a test of mechanical sensitivity with respect to friction:

The test item was sieved (mesh size 0.5 mm) before the measurement. No explosion occured within 6 tests using a pinload of 360 N, only a discoloration of the test material was seen in all tests.

Additionally, the physical state of the test material excludes the enrichment of high-energy components caused by evaporation of volatile solvents.

The test item had no explosive properties.

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
The test item had no explosive properties.