Registration Dossier

Administrative data

First-aid measures

General information:
Immediately remove any clothing contaminated by the product.
Take affected persons out of danger area and instruct to lie down.
Do not leave affected persons unsupervised.
Symptoms of poisoning may occur after several hours. Medical observation for at least 48 hours after the accident is recommended.
Personal protection for the person providing first aid.
If exposed or concerned get medical advice / attention.

After inhalation:
Supply fresh air, keep warm.
Seek medical treatment.

After skin contact:
Instantly wash with water and soap and rinse thoroughly.
If skin irritation or rash occurs get medical advice / attention.
Wash contaminated clothing before reuse.

After eye contact:
Rinse opened eye for several minutes under running water. Then consult doctor.

After swallowing:
Rinse out mouth and then drink plenty of water.
Call a doctor immediately.

Most important symptoms and effects, both acute and delayed:
No further relevant information available.

Indication of any immediate medical attention and special treatment needed:
symptomatic treatment

Fire-fighting measures

Extinguishing media

Suitable extinguishing agents:
Carbon dioxide (CO2), extinguishing powder or water spray/fog.
Fight larger fires with water spray/fog or alcohol-resistant foam.

For safety reasons unsuitable extinguishing agents:
Water with a full water jet.

Special hazards arising from the substance or mixture:
Carbon monoxide (CO) and Carbon dioxide (CO2).

Advice for firefighters
Protective equipment:
Wear self-contained breathing apparatus.

Additional information:
Cool endangered containers with water spray jet.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
If without risk possible, move drums with material away from dangerous area.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Wear protective equipment.
Keep unprotected persons away.
Ensure adequate ventilation.
Remove all ignition sources.
Avoid contact with skin, eyes and clothes.

Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.

Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable containers.
Dispose of the material collected according to regulations.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.

Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Avoid breathing vapours.
Keep away from heat and direct sunlight.
Do not get in eyes, on skin, or on clothing.

Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.

Conditions for safe storage, including any incompatibilities

Storage
Requirements to be met by storerooms and containers:
Observe all local and national regulations for storage of water polluting products.
Store only in the original container.

Information about storage in one common storage facility:
Do not store together with oxidising and acidic materials.
Do not store together with alkalis (caustic solutions).

Further information about storage conditions:
Store container in a well ventilated position.
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
Protect from humidity and keep away from water.

Store in the dark.

Specific end use(s):
No further relevant information available.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.

Control parameters
Components with critical values that require monitoring at the workplace:
Not required.

Additional information:
The lists that were valid during the compilation were used as basis.

Exposure controls
Personal protective equipment
General protective and hygienic measures:
Keep away from foodstuffs, beverages and food.
Instantly remove any contaminated garments.
Do not carry cleaning cloths impregnated with the product in trouser pockets.
Contaminated work clothing should not be allowed out of the workplace.
Do not eat, drink or smoke while working.
Do not breathe vapours.
Do not get in eyes, on skin, or on clothing.
Wash hands during breaks and at the end of the work.
Use skin protection cream for preventive skin protection.

Breathing equipment:
Use breathing protection in case of insufficient ventilation.

Protection of hands:
Impervious gloves
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Check the permeability prior to each renewed use of the glove.
To avoid skin problems reduce the wearing of gloves to the required minimum.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation / the chemical mixture.

Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Penetration time of glove material:
Protective gloves should be replaced at first signs of wear.
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye protection:
Safety glasses

Body protection:
Protective work clothing
Body protection must be chosen depending on activity and possible exposure.

Stability and reactivity

Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.

Possibility of hazardous reactions:
Polymerisation may start at higher temperatures

Conditions to avoid
No further relevant information available.

Incompatible materials:
Strong oxidizing agents
Strong acids
Alkaline materials
Catalysts

Hazardous decomposition products:
Carbon monoxide (CO) and Carbon dioxide (CO2)

Disposal considerations

Waste treatment methods
Recommendation:
Disposal of used product according to substances being absorbed.

European waste catalogue:
Waste disposal key numbers from EWC have to be assigned depending on origin and processing.

Uncleaned packagings
Recommendation:
Disposal must be made according to official regulations.