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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
08 - 09 February 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7220 (Boiling Point / Boiling Range)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
differential scanning calorimetry

Test material

Constituent 1
Chemical structure
Reference substance name:
Vinyl propionate
EC Number:
203-293-5
EC Name:
Vinyl propionate
Cas Number:
105-38-4
Molecular formula:
C5H8O2
IUPAC Name:
ethenyl propanoate
impurity 1
Reference substance name:
Unknown impurities.
Molecular formula:
Not available as unknown impurities.
IUPAC Name:
Unknown impurities.
impurity 2
Chemical structure
Reference substance name:
Water
EC Number:
231-791-2
EC Name:
Water
Cas Number:
7732-18-5
Molecular formula:
H2O
IUPAC Name:
Oxidane
Test material form:
liquid: volatile
Details on test material:
Batch No: 57161235
Storage: Room temperature (approx. 20°C)

Results and discussion

Boiling point
Key result
Boiling pt.:
94.7 °C
Atm. press.:
1 013 hPa
Decomposition:
no

Any other information on results incl. tables

In the temperature range of 30°C – 110°C, an endothermic effect (boiling) could be detected. For the correction of the boiling temperature to standard pressure a correction value f = 4.75 was used for the temperature range from 90°C to 100°C. The lowest measured onset temperature was corrected to the standard pressure to be 94.19°C and the highest onset temperature to be 95.18°C. As the corrected onset temperatures in both tests do not deviate by more than 0.5 K from their mean value of 94.69°C, the test item has a boiling point of 94.7°C.

No further thermal effects were observed up to the test end temperature of 500°C. The detailed results of the DSC-measurements are given in the table in the field 'Overall remarks'.

Applicant's summary and conclusion

Conclusions:
The test item Vinyl propionate (CAS 105-38-4) has a boiling point of 94.7°C at atmospheric pressure (1013 hPa) as determined by differential scanning calorimetry according to Regulation EC No. 440/2008 Method A.2. and OECD Test Guideline 103 (1995).
Executive summary:

The test item Vinyl propionate (CAS 105 -38 -4) has a boiling point of 94.7°C at atmospheric pressure (1013 hPa) as determined by differential scanning calorimetry according to Regulation EC No. 440/2008 Method A.2. and OECD Test Guideline 103 (1995).