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Administrative data

Endpoint:
oxidising liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 07 April 2017 to 10 April 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.21 (Oxidising Properties (Liquids))
Version / remarks:
(EC) 440/2008
Deviations:
no
Qualifier:
equivalent or similar to guideline
Guideline:
UN Manual of Tests and Criteria: Test O.2 (Test for oxidizing liquids)
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
1,3,5-tris(5-isocyanatopentyl)-1,3,5-triazinane-2,4,6-trione
Cas Number:
119934-71-3
Molecular formula:
C21 H30 N6 O6
IUPAC Name:
1,3,5-tris(5-isocyanatopentyl)-1,3,5-triazinane-2,4,6-trione
Constituent 2
Chemical structure
Reference substance name:
2-methylpropyl N-(5-isocyanatopentyl)-N-(5-isocyanatopentylcarbamoyl)carbamate
Molecular formula:
C18 H30 N4 O5
IUPAC Name:
2-methylpropyl N-(5-isocyanatopentyl)-N-(5-isocyanatopentylcarbamoyl)carbamate
Test material form:
liquid: viscous
Details on test material:
Appearance: colourless or light yellow viscous liquid
Storage conditions: at room temperature, container tightly closed, flushed with nitrogen.
Specific details on test material used for the study:
substance was tested as received

Study design

Contact with:
powdered cellulose

Results and discussion

Test results (Oxidising liquids)open allclose all
Key result
Sample tested:
reference mixture with 65% nitric acid + cellulose (1:1 ratio)
Parameter:
mean pressure rise time
Result:
3.74 s
Key result
Sample tested:
test mixture 1:1
Parameter:
mean pressure rise time
Result:
13.13 s

Any other information on results incl. tables

Pressure rise time range for the reference substance: from 3.313 to 4.332 s

Pressure rise time range for the substance: from 11.069 to 15.815 s

None of the 5 results for the substance differed by more than 30% from the arithmetic mean.

None of the 5 results for the reference substance differed by more than 30% from the arithmetic mean.

Applicant's summary and conclusion

Interpretation of results:
other: not classified under CLP/GHS
Conclusions:
The substance has no oxidizing properties.
Executive summary:

In a GLP study according to EC A.21 and UN Test O.2, it was determined that the substance has no oxidizing properties. The 1:1 (by mass) mixture of the substance and cellulose was observed to have a mean pressure rise time greater than that of a 1:1 (by mass) mixture of 65% nitric acid and cellulose.