Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
EYES: Remove any contact lenses. Wash immediately and abundantly with water for at least 15 minutes, opening the eyelids well. Consult a doctor if the problem persists.

SKIN: Remove contaminated clothing from behind. Wash immediately and abundantly with water. If irritation persists, consult a doctor. Wash the contaminated clothing before re-use.
INHALATION: Bring the subject to the open air. If breathing is difficult, call a doctor immediately.
INGESTION: Consult a doctor immediately. Induce vomiting only as directed by your doctor. Do not give anything by mouth if the subject is unconscious and if not authorized by the doctor.

Most important symptoms and effects, both acute and delayed
INGESTION: possible heartburn and abdominal pain.
EXPOSURE BY INHALATION: possible irritation of the mucosa of the upper airways.
SKIN CONTACT: skin reddening possible.
CONTACT WITH EYES: possible burning sensation and conjunctival redness.

Indication of any immediate medical attention and special treatment needed
Provide emergency shower with visocular basin

Fire-fighting measures

SUITABLE EXTINGUISHING MEANS
The extinguishing media are: carbon dioxide and chemical powder. For leaks and spillages of the product that have not been ignited, nebulized water can be used to disperse the flammable vapors and protect the people involved in stopping the leak.
UNSUITABLE EXTINGUISHING MEDIA
Do not use jets of water.
The water is not effective to extinguish the fire, however it can be used to cool the closed containers exposed to the flame preventing fires and explosions.
HAZARDS DUE TO EXPOSURE IN THE EVENT OF FIRE
The product, if involved in an important quantity in a fire, can greatly aggravate it. Avoid breathing combustion products.
In case of thermal decomposition due to the effect of high temperatures, substances harmful to human health can develop: COx and HCl mainly.
GENERAL INFORMATIONS
In the event of fire, immediately cool the containers to avoid the risk of explosion (decomposition of the product, overpressure) and the development of substances potentially hazardous to health. Always wear full fire protection equipment. If possible without risk, remove containers containing the product from fire
EQUIPMENT
Normal fire fighting clothing, such as an open circuit compressed air breathing apparatus (EN 137), flame retardant (EN469), flame retardant gloves (EN 659) and fire brigade boots (HO A29 or A30).

Accidental release measures

Personal precautions, protective equipment and procedures in case of emergency
For those who do not intervene directly
Alert personnel responsible for managing such emergencies. Move away from the accident area if you are not in possession of the personal protective equipment.
For those who intervene directly
Remove all personnel not adequately equipped to cope with the emergency.
Wear appropriate protective equipment (including personal protective equipment referred to in Section 8 of the safety data sheet) to prevent contamination of skin, eyes and personal clothing. Block the loss if there is no danger.
Making the area affected by the accident accessible to workers only after adequate reclamation has taken place. Ventilate the premises affected by the accident.
Prevent the product from entering sewers, surface water or groundwater.
Aspirate the leaked product into a suitable container. If the product is flammable, use an explosion-proof device. Evaluate the compatibility of the container to be used with the product. Absorb the rest with inert absorbent material (vermiculite, sand). Provide sufficient ventilation of the place affected by the leak.

Handling and storage

Ensure an adequate grounding system for systems and people. Avoid contact with eyes and skin. Do not inhale any vapors or mists. Do not eat, drink or smoke during use. Wash hands after use. Avoid dispersion of the product in the environment.
Keep away from heat, sparks and naked flames, do not smoke or use matches or lighters. Without adequate ventilation, the vapors can accumulate on the ground and ignite even at a distance, if triggered, with risk of backfire. Avoid the accumulation of electrostatic charges. To avoid the risk of fire and explosion, never use compressed air during handling. Open the containers carefully, as they can be pressurized.
Keep only in the original container. Store in a ventilated place, away from sources of ignition. Keep the containers tightly closed. Keep the product in clearly labeled containers. Avoid overheating. Avoid violent shocks. Keep containers away from incompatible materials.
Store in a cool, well-ventilated place, away from heat, open flames, sparks and other sources of ignition.

Transport information

Land transport (ADR/RID)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.A.S. (3-chloropropoxytrimethylsilane)
Language:
English
Class:
3
Packaging group:
III
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.A.S. (3-chloropropoxytrimethylsilane)
Language:
English
Class:
3
Packaging group:
III
Labels:
3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.A.S. (3-chloropropoxytrimethylsilane)
Class:
3
Packaging group:
III
EmS code:
F-E, S-E
Labels:
3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.A.S. (3-chloropropoxytrimethylsilane)
Class:
3
Packaging group:
III
Labels:
3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Considering that the use of adequate technical measures should always take priority over personal protection equipment, ensure good ventilation in the workplace through effective local aspiration.
For the selection of personal protective equipment, if necessary ask your chemical suppliers for advice.
The individual protection devices must bear the CE marking which certifies their compliance with the regulations in force.
HAND PROTECTION
Protect your hands with work gloves of category II Viton®, Silver Shield® / 4H®, Teflon®. (see standard EN 374).
The following must be considered for the final choice of the work glove material: compatibility, degradation, break time and permeation.
SKIN PROTECTION
Wear work clothes with long sleeves and safety footwear for professional use in category II (see Directive 89/686 / EEC and EN ISO 20344). Wash with soap and water after removing protective clothing.
Evaluate the opportunity to provide antistatic clothing in the case of the work environment present a risk of explosiveness.
PROTECTION OF EYES
It is advisable to wear tightly fitting goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (eg TLV-TWA) of the substance or one or more of the substances present in the product is exceeded, it is advisable to wear a mask with type A filter (see standard EN 14387). If there are gases or vapors of a different nature and / or gases or vapors with particles (aerosols, fumes, mists, etc.), combined filters must be provided.
The use of means of protection of the respiratory tract is necessary if the technical measures adopted are not sufficient to limit the exposure of the worker to the threshold values ​​taken into consideration. However, the protection offered by the masks is limited.
In the event that the substance considered is odorless or its olfactory threshold is higher than the relative TLV-TWA and in the event of an emergency, wear an open circuit compressed air breathing apparatus (see standard EN 137) or a breathing apparatus outdoor air (see standard EN 138). For the correct choice of the respiratory protection device, refer to the EN 529 standard.
ENVIRONMENTAL EXPOSURE CONTROLS
Emissions from production processes, including those from ventilation equipment, should be monitored for compliance with environmental protection legislation.

Stability and reactivity

The product is stable under normal conditions of use.
Sensitive to moisture.
Stable in recommended temperature and storage conditions, especially if stored in tightly closed containers.
The 3-chloropropoxitrimethylsilane reacts rapidly with water to form 3-chloro-1-propanol and trimethylsilanol ((CH3) 3SiOH).
Avoid exposure to: air, heat, light, humidity.
Avoid contact with: strong oxidizing agents.
In case of thermal decomposition due to the effect of high temperatures, substances harmful to human health can develop: COx and HCl mainly.

Disposal considerations

Reuse, if possible. Product residues are to be considered hazardous special waste. The hazardousness of the waste that partially contains this product must be evaluated according to the laws in force.
Disposal must be entrusted to a company authorized to manage waste, in compliance with national and possibly local regulations.
The transport of waste may be subject to ADR.
CONTAMINATED PACKAGING
Contaminated packaging must be sent for recovery or disposal in accordance with national waste management regulations.