Registration Dossier

Administrative data

First-aid measures

Description of first aid measures:
General advice:
Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely.
Inhalation:
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.
Skin contact:
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.
Eye contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.
Ingestion:
Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth.

Most important symptoms and effects, both acute and delayed:
Symtoms: No symptoms known or expected.

Indication of any immediate medical attention and special treatment needed:
Treatment:
Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote.

Fire-fighting measures

Extinguishing media:
Suitable:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable: High volume water jet

Special hazards arising from the substance or mixture:
In the event of fire the following may be released:, Hydrogen chloride (HCl), Hydrogen cyanide (hydrocyanic acid), Carbon monoxide (CO), Sulphur dioxide (SO2), Nitrogen oxides (NOx)

Advice for firefighters:
Special protective equipment for firefighters:
In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.
Further information:
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Precautions: Avoid dust formation. Avoid contact with spilled product or contaminated surfaces. Remove all sources of ignition. Use personal protective equipment.

Environmental precautions:
Do not allow to get into surface water, drains and ground water.

Methods and materials for containment and cleaning up:
Methods for cleaning up:
Avoid dust formation and electrical charging (sparking) because dust explosion might occur. Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal.

Handling and storage

Precautions for safe handling:
Advice on safe handling:
Avoid dust formation. Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion:
Take measures to prevent the build up of electrostatic charge. Keep away from heat and sources of ignition. Dust may form explosive mixture in air.
Hygiene measures:
Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands before breaks and immediately after handling the product. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt).

Conditions for safe storage, including any incompatibilities:
Requirements for storage areas and containers:
Keep containers tightly closed in a dry, cool and well-ventilated place. Store in original container. Store in a place accessible by authorized persons only. Keep away from direct sunlight.
Advice on common storage:
Keep away from food, drink and animal feedingstuffs.
Suitable materials:
Polyethylene film within an outer package

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (TEFURYLTRIONE)
Chemical name:
TEFURYLTRIONE
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
Packaging: 9 + EHS
Bulk: 9 + EHS
Haz ID 90
SpecialProvisionsopen allclose all
Remarks:
Environm. Hazardous Mark: YES
Special Provisions:
Tunnel Code E

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (TEFURYLTRIONE)
Chemical name:
TEFURYLTRIONE
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
Packaging: 9 + EHS
Bulk: 9 + EHS
Haz ID 90
Remarks
Environm. Hazardous Mark: YES

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (TEFURYLTRIONE)
Chemical name:
TEFURYLTRIONE
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9, P
Marine pollutant
Remarks
Marine pollutant = true

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (TEFURYLTRIONE)
Chemical name:
TEFURYLTRIONE
Class:
9
Packaging group:
III
Labels:
Packaging: 9 + EHS
Remarks
Environm. Hazardous Mark: YES

Additional transport information

Additional transport information
Transport in bulk according to Annex II of MARPOL and the IBC Code:
No transport in bulk according to the IBC Code.

Exposure controls / personal protection

Control parameters:
Tefuryltrione, CAS-No. 473278-76-1, Control parameter: 0.02 mg/m³ (TWA)

Exposure controls:
Respiratory protection:
Wear respirator with a particle filter mask (protection factor 4) conforming to European norm EN149FFP1 or equivalent. Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer's instructions regarding wearing and maintenance.
Hand protection:
Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness of 0,4 mm). Wash when contaminated and dispose of when contaminated inside, when perforated or when contamination on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.
Eye protection:
Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection:
Wear standard coveralls and Category 3 Type 5 suit. If there is a risk of significant exposure, consider a higher protective type suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.

Stability and reactivity

Reactivity:
Thermal decomposition:
Stable under normal conditions.

Chemical stability:
Stable under recommended storage conditions.

Possibility of hazardous reactions:
No dangerous reaction known under conditions of normal use. Stable under recommended storage conditions.

Conditions to avoid:
Exposure to light.

Incompatible materials:
Store only in the original container.

Hazardous decomposition products:
No decomposition products expected under normal conditions of use.

Disposal considerations

Waste treatment methods:
Product:
In accordance with current regulations and, if necessary, after consultation with the site operator and/or with the responsible authority, the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging:
Not completely emptied packagings should be disposed of as hazardous waste.
Waste key for the unused product:
02 01 08* agrochemical waste containing dangerous substances