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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

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Endpoint:
thermal stability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
7 May 2013
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess, Ministerium für Umwelt, Energie, Landwirtschaft und Verbraucherschutz, Wiesbaden, Germany
Key result
Operating temp.:
>= 230 - <= 410 °C

Two DSC-measurements in closed glass crucibles showed an endothermal effect in the temperature range of 200 - 230 °C. An exothermal effect was observed in the temperature range 230 - 410 °C with an energy of 969 J/g and 1098 J/g, respectively.

Endpoint:
thermal stability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 to 24 November 2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess, Ministerium für Umwelt, Energie, Landwirtschaft und Verbraucherschutz, Wiesbaden, Germany
Key result
Operating temp.:
>= 235 - <= 420 °C

Two DSC-measurements in closed glass crucibles showed an endothermal effect in the temperature range of 190 - 225 °C and an exothermal effect in the temperature range of 235 - 420 °C with an energy release of 770 J/g and 810 J/g, respectively. No further endethermal or exothermal effects were observed up to the final temperature of 500 °C.

An optical inspection showed a black residue after the measurement.

The results of the DSC measurements are summarised in table below.

 

Thermal stability (DSC measurement)

Ident-No.

Weight / mg

Final temperature / °C

Type of effect

Temperature range / °C

Enthalpy / J/g

Remarks

35316

9.87

500

endethermal

exothermal

190 - 225

235 - 415

n.r.

-770

closed glass

crucible

35319

10.23

500

endethermal

exothermal

190 - 225

235 - 420

n.r.

-810

closed glass

crucible

 

Description of key information

The substance (technical purity) showed an endothermal effect in the temperature range of 190 - 225 °C and an exothermal effect in the temperature range of 235 - 420 °C with an energy release of 770 J/g and 810 J/g, respectively.

The substance (pure) showed an endothermal effect in the temperature range of 200 - 230 °C and an exothermal effect in the temperature range 230 - 410 °C with an energy of 969 J/g and 1098 J/g, respectively.

Additional information

Justification for classification or non-classification