Registration Dossier

Administrative data

First-aid measures

Eye Contact: Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required.

Ingestion: Call a physician immediately. Clean mouth with water.

Inhalation: Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Immediate medical attention is required.

Notes to Physician: Treat symptomatically

Fire-fighting measures

Suitable Extinguishing Media: Water spray. Carbon dioxide (CO2). Dry chemical. chemical foam.

Extinguishing media which must not be used for safety reasons: No information available.

Special hazards arising from the substance or mixture: Thermal decomposition can lead to release of irritating gases and vapors

Advice for fire-fighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Ensure adequate ventilation

Environmental precautions: Prevent further leakage or spillage if safe to do so

Methods and material for containment and cleaning up: Wear self-contained breathing apparatus and protective suit. Sweep up or vacuum up spillage and collect in suitable container for disposal. Do not let this chemical enter the environment

Handling and storage

Precautions for Safe Handling: Do not breathe dust. Do not breathe vapors or spray mist. Do not get in eyes, on skin, or on clothing. Do not ingest. Use only in area provided with appropriate exhaust ventilation.

Conditions for safe storage, including any incompatibilities: Keep in a dry, cool and well-ventilated place. Keep container tightly closed.

The substance must be handled under strictly controlled conditions as laid out in Article 18 paragraph 4 REACH-regulation. DETAILED information on risk management measures recommended to the user in
accordance with Art. 18 paragraph 4 and ECHA REACH Guidance on intermediates (2010), Annex 3 and Practical Guide 16 (2014) is attached to section 13 of the IUCLID dossier.

Transport information

Land transport (ADR/RID)

UN number:
3416
Proper shipping name and description:
CHLOROACETOPHENONE, LIQUID
Chemical name:
4-CHLORO ACETOPHENONE
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
II
Labels:
6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3416
Proper shipping name and description:
CHLOROACETOPHENONE, LIQUID
Chemical name:
4-CHLORO ACETOPHENONE
Language:
English
Class:
6.1
Classification code:
T1
Packaging group:
II
Labels:
6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3416
Proper shipping name and description:
CHLOROACETOPHENONE, LIQUID
Chemical name:
4-CHLORO ACETOPHENONE
Class:
6.1
Packaging group:
II
EmS code:
F-A, S-A
Labels:
6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3416
Proper shipping name and description:
Chloroacetophenone, liquid
Chemical name:
4-CHLORO ACETOPHENONE
Class:
6.1
Packaging group:
II
Labels:
6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure limits. This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Biological limit values: This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies.
Derived No Effect Level (DNEL): No information available
Exposure limits: This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.


Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies.
Derived No Effect Level (DNEL) No information available
Predicted No Effect Concentration (PNEC): No information available
Engineering Measures: Ensure adequate ventilation, especially in confined areas Ensure that eyewash stations and safety showers are close to the workstation location
Personal protective equipment:
Eye Protection: Goggles
Hand Protection: Protective gloves
Skin and body protection: Wear appropriate protective gloves and clothing to prevent skin exposure
Respiratory Protection: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced

Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice


The substance must be handled under strictly controlled conditions as laid out in Article 18 paragraph 4 REACH-regulation. DETAILED information on risk management measures recommended to the user in
accordance with Art. 18 paragraph 4 and ECHA REACH Guidance on intermediates (2010), Annex 3 and Practical Guide 16 (2014) is attached to section 13 of the IUCLID dossier.

Stability and reactivity

Chemical Stability: Stable under normal conditions

Possibility of Hazardous Reactions:
Hazardous Polymerization No information available.
Hazardous Reactions. No information available.

Conditions to Avoid: Incompatible products.

Incompatible Materials: Strong oxidizing agents, Strong bases.

Hazardous Decomposition Products: Hydrogen chloride gas. Carbon monoxide (CO). Carbon dioxide (CO2).

Disposal considerations

Disposal Regulation: As per MPCB with local regulation