Registration Dossier

Administrative data

First-aid measures

Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Rinse mouth and then drink plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms: No significant reaction of the human body to the product known.
Indication of any immediate medical attention and special treatment needed
Treatment: Symptomatic treatment (decontamination, vital functions).

Fire-fighting measures

Suitable extinguishing media:
water spray, dry powder, foam
Unsuitable extinguishing media for safety reasons:
carbon dioxide
Special hazards arising from the substance or mixture
carbon monoxide, Carbon dioxide
The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Keep containers cool by spraying with water if exposed to fire. In case of fire and/or explosion do not
breathe fumes. Collect contaminated extinguishing water separately, do not allow to reach sewage
or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with
official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Use personal protective clothing. Avoid contact with the skin, eyes and
clothing.
Environmental precautions
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Contain with dust binding material and dispose of.
For large amounts: Sweep/shovel up.
Avoid raising dust. Dispose of absorbed material in accordance with regulations. Collect waste in
suitable containers, which can be labeled and sealed. Clean contaminated floors and objects
thoroughly with water and detergents, observing environmental regulations.

Handling and storage

Precautions for safe handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of
stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift.
Protection against fire and explosion:
Avoid dust formation. Dust can form an explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from foods and animal feeds.
Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains AFIDOPYROPEN)
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains AFIDOPYROPEN)
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains AFIDOPYROPEN)
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains AFIDOPYROPEN)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

No occupational exposure limits known.
Personal protective equipment
Respiratory protection:
Respiratory protection not required.
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
The statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended. Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
No hazardous reactions if stored and handled as prescribed/indicated.
Conditions to avoid
See MSDS section 7 - Handling and storage.
Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods
Must be sent to a suitable incineration plant, observing local regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.