Registration Dossier

Administrative data

First-aid measures

DESCRIPTION OF FIRST AID MEASURES
- General Information: Take off all contaminated clothing immediately. In case of feeling unwell: Obtain medical attention. Show this safety data sheet to the doctor in attendance.
- After Inhalation: Move to fresh air.
- After contact with skin: Wash off with plenty of water. Remove soiled clothing.
- After contact with eyes: Rinse with plenty of water immediately, also under the eyelid, for at least 15 minutes. Remove contact lenses, if applicable. Call a physician immediately.
- After ingestion: Drink 1 or 2 glasses of water. Induce vomiting immediately and call a physician.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
No information available.

INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
No information available. lf necessary, contact poison centre.

Fire-fighting measures

EXTINGUISHING MEDIA
- Suitable extinguishing media: Use extinguishing measures that are appropriate to the environment.
- Extinguishing media which must not be used for safety reasons: None known.

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
The product is not flammable; Manganese oxide: Heating causes the release of oxygen.

ADVICE FOR FLREFLGHTERS:
Additional information: In the event of fire, wear self-contained breathing apparatus. Collect contaminated firefighting water separately. Prevent product from entering drains. Contaminated extinguishing water and soil must be disposed of in accordance with official regulations.

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
Provide adequate ventilation and/or exhaust ventilation. Do not breathe dust. Use personal protective equipment.

ENVIRONMENTAL PRECAUTIONS:
Do not let product enter drains. Do not contaminate surface water. Should not be released into the environment. Contact the responsible authority immediately if the product ends up in the soil, a body of water, or the sewer system.

METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
Mop up whilst dry. Clean contaminated surface thoroughly.

REFERENCE TO OTHER SECTIONS:
- Suitable protective equipment
- Disposal in accordance with the official regulations

Handling and storage

PRECAUTIONS FOR SAFE HANDLING
- Advice on safe handling: Handle in accordance with good industrial hygiene and safety practice.
- Advice on protection against fire and explosion: No special precautions required.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
- Requirements for storage rooms and vessels: Containers keep tightly closed. Keep in a dry place.
- Specific end use(s): No data available

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE. SOLID, N.O.S. (Copper oxide)
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Special Provisions:
355
Remarks:
Limited quantity: 5 kg
Transport category: 3
Hazard No: 90
Tunnel restriction code: E

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper oxide)
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9
Remarks
Special Provisions: 335
Limited quantity: 5 kg

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper oxide)
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarks
Special Provisions: 335, 966. 967
Limited quantity: 5 kg

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANGE, SOLID, N.O.S. (Copper oxide)
Class:
9
Packaging group:
III
Labels:
9
Remarks
IATA-packing instructions - Passenger: 956
IATA-max. quantity - Passenger: 400 kg
IATA-packing instructions - Cargo: 956
IATA-max. quantity - Cargo: 400 kg
Other applicable information (air transport): Passenger-LQ: Y956

Additional transport information

Additional transport information
Environmental hazards: yes
Special precautlons for user: No data available.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: not applicable

Exposure controls / personal protection

CONTROL PARAMETERS
- Exposure limits:

- Workers - Hazard via inhalation route: DNEL (systemic effects, long term exposure) = 160 µg Hopcalite/ m^3
- Occupational exposure limits (TRGS 900) : 0.2 mg Mn/m^3 (inhalable fraction)
- Scientific Committee on Occupational Exposure Limits (SCOEL) : 0.01 mg Cu/m^3 (respirable fraction)

- Workers - Hazard via dermal route: DNEL (systemic effects, long term exposure) = 4.5 mg Hopcalite/ kg bw/ day


EXPOSURE CONTROLS
- Occupational exposure controls: Provide adequate ventilation and/or exhaust ventilation.
- Protective and hygiene measures: When using do not eat or drink. Wash hands before breaks and at the end of the workday.
- Respiratory protection: Respirator must be worn if exposed to dust. Respirator with P3 filter
- Hand protection: Protective gloves: Chemical-resistant. The manufacturer recommends the following glove materials: Nitrile rubber or butyl rubber. Safety gloves should be selected for the actual conditions of use and in accordance with the instructions for use provided by the manufacturer.
- Eye protection: Tightly Fitting safety goggles.
- Skin protection: Wear suitable protective clothing.

Stability and reactivity

Reactivity: no data available.
Chemical stability: stable under proper storage and handling.
Possibility of hazardous reactions: no dangerous reactions occur under normal storage conditions and in normal use.
Conditions to avoid: none known.
Incompatible materials: reducing agents.
Hazardous decomposition products: none known.
Further information:
- copper oxide: hygroscopic
- manganese oxide: oxidising agents

Disposal considerations

WASTE TREATMENT METHODS
- Advice on disposal: Disposal in accordance with the official regulations.
- Recommendation Waste disposal number of waste from residues/unused products: Wastes from inorganic chemical processes; wastes from the MFSU of salts and their solutions and metallic oxides; metallic oxides containing heavy metals; classified as hazardous waste.
- Recommendation: Wastes from inorganic chemical processes; wastes from the MFSU of salts and their solutions and metallic oxides; metallic oxides containing heavy metals; classified as hazardous waste.
- Recommendation Waste disposal number of contaminated packaging: waste packaging; absorbents, wiping cloths, filter materials and protective clothing not otherwise specified; packaging (including separately collected municipal packaging waste); packaging containing residues of or contaminated by dangerous substances, classified as hazardous waste.
- Contaminated packaging: Empty containers must be completely drained to the state of the art before being disposed of. Disposal in accordance with the official regulations.