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Classification & Labelling & PBT assessment

GHS

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General Information

Implementation:
EU
Remarks:

Other petroleum gases, benzene or 1,3-butadiene < 0.1%,  carbon monoxide < 0.3%, pentane < 25%

Gases in Annex VI: 68476-26-6 / 68476-40-4 / 68476-49-3 / 68476-85-7 / 68476-86-8 / 68606-26-8 / 87741-01-3. Cas Number 68308-27-0 is not in Annex VI but have similar composition as Annex VI substances in this category resulting in the same classification. For purpose of C&L it is therefore grouped with the above Annex VI substances

Related composition

Related composition:
Boundary Composition & SIP

Classificationopen allclose all

Explosives
Reason for no classification:
data conclusive but not sufficient for classification
Flammable gases and chemically unstable gases
Hazard category:
Flam. Gas 1A
Hazard statement:
H220: Extremely flammable gas.
Aerosols
Reason for no classification:
data lacking
Reason for no classification:
hazard class not assessed
Oxidising gases
Reason for no classification:
data lacking
Gases under pressure
Hazard category:
Liquefied gas
Hazard statement:
H280: Contains gas under pressure; may explode if heated.
Flammable liquids
Reason for no classification:
data lacking
Flammable solids
Reason for no classification:
data lacking
Self-reactive substances and mixtures
Reason for no classification:
data lacking
Pyrophoric liquids
Reason for no classification:
data lacking
Pyrophoric solids
Reason for no classification:
data lacking
Self-heating substances and mixtures
Reason for no classification:
data lacking
Substances and mixtures which in contact with water emit flammable gases
Reason for no classification:
data lacking
Oxidising liquids
Reason for no classification:
data lacking
Oxidising solids
Reason for no classification:
data lacking
Organic peroxides
Reason for no classification:
data lacking
Corrosive to metals
Reason for no classification:
data lacking
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Reason for no classification:
data lacking
Acute toxicity - dermal
Reason for no classification:
data lacking
Acute toxicity - inhalation
Reason for no classification:
data lacking
Skin corrosion / irritation
Reason for no classification:
data lacking
Serious eye damage / eye irritation
Reason for no classification:
data lacking
Respiratory sensitisation
Reason for no classification:
data lacking
Skin sensitisation
Reason for no classification:
data lacking
Aspiration hazard
Hazard category:
Asp. Tox. 1
Hazard statement:
H304: May be fatal if swallowed and enters airways.
Reproductive toxicity
Reason for no classification:
data lacking
Effects on or via lactation
Reason for no classification:
data lacking
Germ cell mutagenicity
Reason for no classification:
data lacking
Carcinogenicity
Reason for no classification:
data lacking
1. Specific target organ toxicity - single (STOT-SE)
Hazard category:
STOT Single Exp. 3
Hazard statement:
H336: May cause drowsiness or dizziness.
Affected organs:
other: other: Narcosis, CNS
Route of exposure:
inhalation
1. Specific target organ toxicity - repeated (STOT-RE)
Reason for no classification:
data lacking
Hazardous to the aquatic environment (acute / short-term)
Reason for no classification:
data lacking
Hazardous to the aquatic environment (long-term)
Hazard category:
Aquatic Chronic 3
Hazard statement:
H412: Harmful to aquatic life with long lasting effects.
Hazardous to the ozone layer
Reason for no classification:
data lacking

Labelling

Signal word:
Danger

Hazard pictogram

GHS02: flame
GHS04: gas cylinder
GHS07: exclamation mark

Hazard statements

H220: Extremely flammable gas.
H280: Contains gas under pressure; may explode if heated.
H336: May cause drowsiness or dizziness.
H304: May be fatal if swallowed and enters airways.
H412: Harmful to aquatic life with long lasting effects.

Precautionary statements

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312: Call a POISON CENTER/doctor/.../if you feel unwell.
P331: Do NOT induce vomiting.
P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381: In case of leakage eliminate all ignition sources.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P410: Protect from sunlight.
P501: Dispose of contents/container to ...

Notes

Note J
Note K

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