Registration Dossier

Diss Factsheets

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: well performed study according to accepted standard

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2015
Report date:
2015

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Hydrogen hydroxy[2-hydroxy-3-[(2-hydroxy-3-nitrobenzylidene)amino]-5-nitrobenzenesulphonato(3-)]chromate(1-), compound with 3-[(2-ethylhexyl)oxy]propylamine (1:1)
EC Number:
287-267-9
EC Name:
Hydrogen hydroxy[2-hydroxy-3-[(2-hydroxy-3-nitrobenzylidene)amino]-5-nitrobenzenesulphonato(3-)]chromate(1-), compound with 3-[(2-ethylhexyl)oxy]propylamine (1:1)
Cas Number:
85455-32-9
Molecular formula:
C13H7CrN3O10S.C11H25NO.H
IUPAC Name:
Hydrogen hydroxy[2-hydroxy-3-[(2-hydroxy-3-nitrobenzy-lidene)amino]-5-nitrobenzenesulphonato(3-)]chromate(1-), compound with 3-[(2-ethylhexyl)oxy]propylamine (1:1)

Results and discussion

Small-scale preliminary tests
Parameter:
other: Explosive (not specified)
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Applicant's summary and conclusion

Interpretation of results:
non explosive
Remarks:
Migrated information
Conclusions:
The test item had no explosive properties in the sense of the European Commission Regulation
(EC) No. 440/2008, Method A.14.
Executive summary:

The substance was tested for explosive properties according the EU method A.14.

Two DSC-measurements in closed glass crucibles with the test item showed an exothermal effect in the temperature range of

190 – 350 °C with enthalpies of -868 J/g and -839 J/g, respectively. The measurements were terminated at 400 °C.

Mechanical sensitivity (friction):

The dried test item was sieved (mesh size 0.5 mm) before the measurement. No explosion occurred within 6 tests using a pinload of 360 N.

Mechanical sensitivity (shock):

The dried test item was sieved (mesh size 0.5 mm) before the measurement. No explosion within 6 tests using a mass of 10 kg falling from a height of 0.4 m was observed, only a decomposition was detected (odour).

Thermal sensitivity: Three tests with dried test item were performed with a circular nozzle plate with a hole of 2 mm diameter. No explosion was observed.