Hydrogen hydroxy[2-hydroxy-3-[(2-hydroxy-3-nitrobenzylidene)amino]-5-nitrobenzenesulphonato(3-)]chromate(1-), compound with 3-[(2-ethylhexyl)oxy]propylamine (1:1)

Explosiveness

Administrative data

Endpoint:

explosiveness

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2015

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

other: well performed study according to accepted standard

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2015

Report date:

2015

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.14 (Explosive properties)

GLP compliance:

no

Test material

Test material information

Constituent 1

Reference substance name:

Hydrogen hydroxy[2-hydroxy-3-[(2-hydroxy-3-nitrobenzylidene)amino]-5-nitrobenzenesulphonato(3-)]chromate(1-), compound with 3-[(2-ethylhexyl)oxy]propylamine (1:1)

EC Number:

287-267-9

EC Name:

Hydrogen hydroxy[2-hydroxy-3-[(2-hydroxy-3-nitrobenzylidene)amino]-5-nitrobenzenesulphonato(3-)]chromate(1-), compound with 3-[(2-ethylhexyl)oxy]propylamine (1:1)

Cas Number:

85455-32-9

Molecular formula:

C13H7CrN3O10S.C11H25NO.H

IUPAC Name:

Hydrogen hydroxy[2-hydroxy-3-[(2-hydroxy-3-nitrobenzy-lidene)amino]-5-nitrobenzenesulphonato(3-)]chromate(1-), compound with 3-[(2-ethylhexyl)oxy]propylamine (1:1)

Results and discussion

Small-scale preliminary tests

Parameter:

other: Explosive (not specified)

Remarks:

migrated information

Remarks on result:

negative (not further specified)

Applicant's summary and conclusion

Interpretation of results:

non explosive

Remarks:

Migrated information

Conclusions:

The test item had no explosive properties in the sense of the European Commission Regulation
(EC) No. 440/2008, Method A.14.

Executive summary:

The substance was tested for explosive properties according the EU method A.14.

Two DSC-measurements in closed glass crucibles with the test item showed an exothermal effect in the temperature range of

190 – 350 °C with enthalpies of -868 J/g and -839 J/g, respectively. The measurements were terminated at 400 °C.

Mechanical sensitivity (friction):

The dried test item was sieved (mesh size 0.5 mm) before the measurement. No explosion occurred within 6 tests using a pinload of 360 N.

Mechanical sensitivity (shock):

The dried test item was sieved (mesh size 0.5 mm) before the measurement. No explosion within 6 tests using a mass of 10 kg falling from a height of 0.4 m was observed, only a decomposition was detected (odour).

Thermal sensitivity: Three tests with dried test item were performed with a circular nozzle plate with a hole of 2 mm diameter. No explosion was observed.