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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
20 March 2017 - 11 April 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Version / remarks:
version 2006
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Version / remarks:
version 2009
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: vapour pressure balance
Key result
Test no.:
#1
Temp.:
130 °C
Vapour pressure:
< 0.003 Pa
Remarks on result:
other: See Remarks
Remarks:
Limit of detection of the apparatus is 10-3 Pa and no significative loss of mass was observed at 130°C and thus at which the test item was not decomposed.
Test no.:
#2
Temp.:
20 °C
Vapour pressure:
< 0.003 Pa
Remarks on result:
other: See Remarks
Remarks:
extrapolation
Key result
Transition / decomposition:
no
Remarks:
No degradation of the test item was observed. No significative losses of mass were recorded during the different assays.

The mass of sample weighed for each assay was reported in the table below. The sample was placed in a Knudsen effusion cell. Then the cell was placed in the apparatus.

 Assay N°  T°C  Mass of the test item (mg)  Knudsen effusion cell aperture size (µm)  Taken into account or not
 1  85  4.87 279.9  Yes 
 2  100  4.87 279.9  Yes
 3  115 4.87 279.9  Yes
 130  4.87  279.9 Yes 

No degradation of the test item was observed. No significative losses of mass were recorded during the different assays. The limit of detection of the apparatus is 10-3 Pa and the losses of mass recorded correponded to vapour pressures lower than 10-3 Pa and were not considered as reliable.

As a consequence, we can consider that the vapour pressure of the test item was lower than 10-3 Pa at 130 °C (temperature at which no significative loss of mass was observed and thus at which the test item was not decomposed). By extrapolation, the vapour pressure of the test item was considered to be largely lower than 10-3 Pa at 20 °C.

Conclusions:
The vapour pressure of the test item was lower than 10-3 Pa at 130 °C and thus the vapour pressure of the test item was considered to be largely lower than 10-3 Pa at 20 °C.

Description of key information

The vapour pressure of the test item was considered to be largely lower than 10-3 Pa at 20 °C according to experimental test carried out under OECD guideline 104 (effusion method: vapour pressure balance).

Key value for chemical safety assessment

Additional information

The vapour pressure of the test item was lower than 10-3 Pa at 130 °C and thus the vapour pressure of the test item was considered to be largely lower than 10-3 Pa at 20 °C.