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Physical & Chemical properties

Boiling point

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Administrative data

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
25-Aug-2015 to 25-Nov-2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling point/boiling range)
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7220 (Boiling Point / Boiling Range)
GLP compliance:
no
Type of method:
differential scanning calorimetry
Key result
Boiling pt.:
>= 240 - <= 246 °C
Atm. press.:
1 013 hPa

Results

The thermograms of the DSC runs PN9977 and PN10011 shows tn the temperature range of approximately 110 - 300 °C an endothermic effect could be observed, which can be assigned to the boiling of the test item.

Results of the DSC measurements

No.

 

Sample weight (mg)

Onset of effect (°C)

Range of effect (°C)

Weight loss (mg)

Atmospheric pressure (hPa)

PN9977

5.79

245.86

110 - 310 (endo)

5.80

1010.8

PN10011

8.30

239.78

160 -290 (endo)

8.35

1014.4

 

For the correction of the boiling temperature to standard pressure the test item was assigned to chemical group 2 (e.g. Hydrocarbons). A correction value φ = 5.05 was used for the temperature range from 240 °C to 250 °C. The lowest measured onset temperature is corrected to the standard pressure to be 239.73 °C and the highest onset temperature to be 245.97 °C. As the corrected onset temperatures in both tests deviate by more than 0.5 K from their mean value of 242.85 °C, the test item has a boiling range from 240 °C to 246 °C.

No further thermal effects were observed up to the test end temperature of 500 °C.

Final Results

The test substnace has a boiling range from 240 °C to 246 °C at atmospheric pressure (1013 hPa) as determined by differential scanning calorimetry according to Regulation EC No. 440/2008 Method A.2. and OECD Test Guideline 103 (1995).

Conclusions:
A boiling point range >= 240 °C and <= 246 °C (at 1013 hPa) was determined for the test substance according to E.U. Method A.2.

Description of key information

Boiling point range: >= 240 °C and <= 246 °C at 1013 hPa (EU Method A.2, differential scanning calorimetry)

Key value for chemical safety assessment

Additional information