Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this
substance.
After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with
water. Seek medical advice immediately and clearly identify substance. Continue to bathe eyes during transport to medical
practitioner.
After contact with the skin:
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious
cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.
After inhalation:
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops,
administer artificial respiration. Seek medical advice immediately and clearly identify substance.
After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly
identify substance.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
After inhalation: treat as early as possible using cortisone spray. Medical checks necessary up to a latency period of at least 24
hours. In the event of 1st degree burns use corticoid-externa. In the case of 2nd degree burns, use symptomatic treatment.
Further toxicology information must be observed.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons:
water jet .
Special hazards arising from the substance or mixture
Risk of hazardous gasses or fumes in the event of fire. Exposure to combustion products may be a health hazard! Hazardous
combustion products: carbon oxides , silicon oxides , nitrogen oxides , incompletely burnt hydrocarbons , toxic and very toxic
fumes .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air. Keep unprotected persons away.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Secure the area. Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid contact with eyes
and skin. Do not inhale gases/vapours/aerosols. If material is released indicate risk of slipping. Do not walk through spilled
material.
Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Close leak if possible without risk. Contain any fluid that
runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked
containers. Inform authorities if substance leaks into surface waters, sewerage or ground.
Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations. Do not flush away with water. For small
amounts: Absorb with a neutral (non-acidic / non-basic) liquid binding material such as diatomaceous earth and dispose of
according to government regulations. For large amounts: Liquids may be recovered using suction devices or pumps. If flammable,
only air driven or properly rated electrical equipment should be used. Clean any slippery coating that remains using a detergent /
soap solution or another biodegradable cleaner. Silicone fluids are slippery; spills are a safety hazard. Apply sand or other inert
granular material to improve traction.
Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.

Handling and storage

Precautions for safe handling
Precautions for safe handling:
Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction,
respiratory protection). Spilled substance increases risk of slipping. Observe information in section 8. Keep away from
incompatible substances.
Precautions against fire and explosion:
Observe the general rules for fire prevention.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
Observe local/state/federal regulations.
Advice for storage of incompatible materials:
Observe local/state/federal regulations.
Further information for storage:
Store in a dry and cool place.
Minimum temperature allowed during storage and transportation: -20 °C
Maximum temperature allowed during storage and transportation: 50 °C

Transport information

Land transport (ADR/RID)

UN number:
3267
Proper shipping name and description:
Corrosive liquid, basic, organic, n.o.s. (aminofunctional alkyl-disiloxane)
Class:
8
Packaging group:
II
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3267
Proper shipping name and description:
Corrosive liquid, basic, organic, n.o.s. (aminofunctional alkyl-disiloxane)
Class:
8
Packaging group:
II
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3267
Proper shipping name and description:
Corrosive liquid, basic, organic, n.o.s. (aminofunctional alkyl-disiloxane)
Class:
8
Packaging group:
II
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3267
Proper shipping name and description:
Corrosive liquid, basic, organic, n.o.s. (aminofunctional alkyl-disiloxane)
Class:
8
Packaging group:
II
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters
Maximum airborne concentrations at the workplace:
Aerosol - inhalable fraction 10,0 mg/m3
The aerosol limit specified is a recommendation should aerosol be formed during processing.

Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Observe standard industrial hygiene practices for the handling of chemical substances. Do not inhale gases/vapours/aerosols.
Use with adequate ventilation. Avoid contact with eyes and skin. Preventive skin protection recommended. Remove
contaminated, soaked clothing immediately. Clean work areas regularly. Provide emergency shower and eye-bath. Do not eat,
drink or smoke when handling.
Personal protection equipment:
Respiratory protection
In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. Suitable respiratory
equipment: Respirator with a full face mask, according to acknowledged standards such as EN 136.
Recommended Filter type: Combined filter type A-P2 (certain organic gases and vapors with boiling point > 65°C; particles),
according to acknowledged standards such as EN 14387
Observe the equipment manufacturer's information and wear time limits for respirators.
Eye protection
tight fitting protective goggles .
Hand protection
Gloves are required at all times when handling the material.
Recommended glove types: Protective gloves made of butyl rubber
thickness of the material: > 0,3 mm
Breakthrough time: > 480 min
Recommended glove types: Protective gloves made of nitrile rubber
thickness of the material: > 0,4 mm
Breakthrough time: 10 - 30 min
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion,
and the contact time. Note that, due to the numerous external influences (such as temperature), a chemically resistant protective
glove in daily use may have a service life that is considerably shorter than the measured break through time.
Skin protection
If handled uncovered: Chemical protective clothing, full-body liquid-tight protection if necessary. Please observe the instructions
regarding permeability time which are provided by the supplier.

Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.

Further information for system design and engineering measures
Observe national regulatory requirements.

Stability and reactivity

Reactivity; Chemical stability; Possibility of hazardous reactions

If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.

Conditions to avoid
none known

Incompatible materials
none known

Hazardous decomposition products
If stored and handled properly: none known . Measurements have shown the formation of small amounts of formaldehyde at
temperatures above about 150 °C (302 °F) through oxidation.

Disposal considerations

Waste treatment methods
Material
Recommendation:
Material that cannot be used, reprocessed or recycled should be disposed of in accordance with Federal, State, and local
regulations at an approved facility. Depending on the regulations, waste treatment methods may include, e.g., landfill or
incineration.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material.