Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

General advice
- Show this safety data sheet to the doctor in attendance.
- First aider needs to protect himself.
- Place affected clothing in a sealed bag for subsequent decontamination.
In case of inhalation
- Negligible or unlikely exposure pathways
- If inhaled, remove to fresh air.
- Consult a physician if necessary.
In case of skin contact
- Take off contaminated clothing and shoes immediately.
- Wash off with plenty of water.
In case of eye contact
- Rinse with running water whilst keeping the eyes wide open (at least 15 minutes)
In case of ingestion
- Do NOT induce vomiting.
- Rinse mouth with water.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
- Water spray
- Foam
- Carbon dioxide (CO2)
- Multi-purpose powders
Unsuitable extinguishing media
- High volume water jet
Special hazards arising from the substance or mixture
- Combustible. However, does not present any particular risk in the event of a fire.
- On combustion, toxic gases are released.
Advice for firefighters
Special protective equipment for firefighters
- In the event of fire, wear self-contained breathing apparatus.
- Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing
Further information
- Standard procedure for chemical fires.
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
- Wear suitable protective equipment.
- Personal protective equipment
- Wear suitable gloves.
- Tightly fitting safety goggles
- Avoid contact with the skin and the eyes.
Environmental precautions
- Stop the leak. Turn leaking containers leak-side up to prevent the escape of liquid.
- Contain the spilled material by bunding.
- Do not let product enter drains.
- Do not allow uncontrolled discharge of product into the environment.
Methods and materials for containment and cleaning up
Recovery
- Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
- Keep in suitable, closed containers for disposal.
- Keep in properly labelled containers.
Decontamination/cleaning
- Wash non-recoverable remainder with large amounts of water.
- Clean contaminated surface thoroughly.
- Recover the cleaning water for subsequent disposal.
Disposal
- Dispose of in accordance with local regulations.
Additional advice
- Material can create slippery conditions.
- Dry polymerized residues may be cleaned up with a high pressure water jet.

Handling and storage

Precautions for safe handling
- Provide adequate ventilation.
- Handle in accordance with good industrial hygiene and safety practice.
- Avoid exceeding the given occupational exposure limits (see section 8).
Hygiene measures
- The user is responsible for monitoring the working environment in accordance with local laws and regulations.
- Use clean, well-maintained personal protection equipment.
- Contaminated work clothing should not be allowed out of the workplace.
- Emergency equipment immediately accessible, with instructions for use.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Take all necessary measures to avoid accidental discharge of products into drains and waterways due to the
rupture of containers or transfer systems.
- Stable under normal conditions.
- Keep container tightly closed.
- Keep in a dry, cool and well-ventilated place.
- Keep away from heat and sources of ignition.
- Keep away from incompatible materials to be indicated by the manufacturer
- Keep away from: Hazardous reactions may occur on contact with certain chemicals. (Refer to the list of incompatible
materials section 10: "Stability-Reactivity").
Packaging material
Suitable material
- Plastic materials.
Remarks
- Store in original container.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Control measures
Engineering measures
- Provide adequate ventilation.
- Extract at emission point.
Individual protection measures
Respiratory protection
- Use a respirator with an approved filter if a risk assessment indicates this is necessary.
Hand protection
- Where there is a risk of contact with hands, use appropriate gloves
- The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN
374 derived from it.
- Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
- Gloves must be inspected prior to use.

Eye protection
- Safety glasses with side-shields
Skin and body protection
- Full protective suit
- Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures
- The user is responsible for monitoring the working environment in accordance with local laws and regulations.
- Use clean, well-maintained personal protection equipment.
- Contaminated work clothing should not be allowed out of the workplace.
- Emergency equipment immediately accessible, with instructions for use.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
Protective measures
- Emergency equipment immediately accessible, with instructions for use.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Selection of appropriate personal protective equipment should be based on an evaluation of the performance
characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of
use, and the potential hazards and/or risks that may occur during use.
Environmental exposure controls
- Contain the spilled material by bunding.
- Do not let product enter drains.
- Do not allow uncontrolled discharge of product into the environment.

Stability and reactivity

Chemical stability
- Stable under recommended storage conditions

Possibility of hazardous reactions
Polymerisation
- Hazardous polymerisation may occur.

Conditions to avoid
- Direct sunlight.
- Keep away from heat and sources of ignition.
- Loss of dissolved oxygen
- Loss of polymerization inhibitor

Incompatible materials
- Strong oxidizing agents
- Peroxides
- Acids
- polymerisation initiators
- Water-reactive substances

Hazardous decomposition products
- On combustion or on thermal decomposition (following the evaporation of water) releases:
- (Carbon oxides (CO + CO2)).
- Nitrogen oxides (NOx)

Disposal considerations

Product Disposal
Prohibition
- Avoid release to the environment.
- Dispose of in accordance with local regulations.
Advice on cleaning and disposal of packaging
- Completely empty the packaging prior to decontamination.
- Carefully drain and then steam clean.
- Recycle following cleaning.
- Dispose of contents/ container to an approved waste disposal plant.
- Dispose of in accordance with local regulations.
Measure for waste avoidance or recovery
- Do not dispose of the product at a rubbish tip.