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Diss Factsheets

Physical & Chemical properties

Boiling point

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Administrative data

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Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: in-house data disclosed on AkzoNobel Technical Bulletin noting a vapor pressure graph for TEB
Principles of method if other than guideline:
no method information
GLP compliance:
no
Other quality assurance:
other: 9001:2015, 14001:2015, and RC14001:2013
Type of method:
other: no method information
Boiling pt.:
95 °C
Atm. press.:
760 mm Hg
Remarks on result:
other: no other information

in-house unreported data notes vapor pressure graph from 20-95 oC and ca. 40 -760 mm Hg

Conclusions:
The boiling point of TEB is reported as 95 oC @ 760 mm Hg.
Executive summary:

The boiling point of TEB is reported as 95 oC @ 760 mm Hg.

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
documentation insufficient for assessment
Principles of method if other than guideline:
no method information
Type of method:
other: no method information
Specific details on test material used for the study:
reported as 99.3 % pure
Boiling pt.:
94 - 95 °C
Atm. press.:
760 Torr
Remarks on result:
other: no other information
Conclusions:
The boiling point of 99.3 % pure triethylborane is reported as 94-95 oC.
Executive summary:

The boiling point of 99.3 % pure triethylborane is reported as 94-95 oC.

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
test procedure in accordance with generally accepted scientific standards and described in sufficient detail
Principles of method if other than guideline:
The boiling points were determined in an ebulliometer equipped with a platinum resistance thermometer.
Type of method:
ebulliometer
Specific details on test material used for the study:
purity reported at 99.8 %
Boiling pt.:
95 °C
Atm. press.:
760 mm Hg
Remarks on result:
other: no other information
Conclusions:
The boiling point is reported as 95 oC.
Executive summary:

The boiling point is reported as 95 oC.

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
documentation insufficient for assessment
Remarks:
no method/purity information, Antoine equation derived from unpublished vp data
Principles of method if other than guideline:
no information, unpublished vp data used to derive Antoine equation
Type of method:
other: no information
Boiling pt.:
94.98 °C
Atm. press.:
760 Torr
Remarks on result:
other: calculated from Antoine equation

Antoine equation derived from unpublished vp data:

log P (torr) = 7.413 - 1544.2(245.74 + t(oC))

Conclusions:
bp calculated from Antoine equation is 94.98 oC
Executive summary:

bp calculated from Antoine equation is 94.98 oC

Description of key information

The boiling point is ca. 95 +/- 1 oC

Key value for chemical safety assessment

Boiling point at 101 325 Pa:
95 °C

Additional information

further supported by many other literature references