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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point, other
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016-07-12 to 2016-07-18
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.6315 (Flammability)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 3679 (Determination of flash point - Rapid equilibrium closed cup method)
Version / remarks:
2004 (E), Second Edition – 2004-04-01, P1-18
Deviations:
no
Qualifier:
according to guideline
Guideline:
ASTM D3278 (Standard test methods for flash point of liquids by small scale closed-cup apparatus)
Version / remarks:
89, P1-7.
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
Date of inspection: 17/06/2015; Date of issue: 24/09/2015
Type of method:
equilibrium method closed cup
Flash point apparatus:
Setaflash apparatus
Key result
Flash point:
79 °C
Atm. press.:
1 013 hPa

Results of the flash point determination are shown in the following table:

Temperature (ºC)

Observations

21.0

No flash

26.0

No flash

31.0

No flash

36.0

No flash

41.0

No flash

46.0

No flash

51.0

No flash

56.0

No flash

61.0

No flash

66.0

No flash

71.0

No flash

71.0 (fresh sample)

No flash

76.0

No flash

81.0

A blue flash spread across the sample cup

81.0 (fresh sample)

A blue flash spread across the sample cup

76.0 (fresh sample)

No flash

77.0 (fresh sample)

No flash

78.0 (fresh sample)

No flash

79.0 (fresh sample)

A blue flash spread across the sample cup

79.0 (fresh sample)

A blue flash spread across the sample cup

77.0 (fresh sample)

No flash

 

Atmospheric pressure: 100.8 kPa

Corrected flash point: 79.1°C

Conclusion

The flash point of the test item has been determined to be 79 ± 2°C.

Interpretation of results:
GHS criteria not met
Conclusions:
A flash point value of 79 ± 2°C at 1013 hPa was determined for the substance using a relevant test method and in compliance with GLP. The result is considered to be reliable.

Description of key information

Flash point: 79 ± 2°C at 1013 hPa (ISO 3679)

Key value for chemical safety assessment

Flash point at 101 325 Pa:
79 °C

Additional information

A measured flash point value of 79 ± 2°C at 1013 hPa was determined for the substance using a rapid equilibrium closed-cup method in accordance with ISO 3679 and in compliance with GLP. The result is considered to be reliable.

A measured flash point of 79 ± 2°C and a boiling point value of 271.5°C indicate that the substance should not be classified for flammability in accordance with Regulation (EC) No. 1272/2008. However, in accordance with the Global Harmonized System of classification and labelling of Chemicals, the substance is classified as a Combustible liquid Category 4.