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First-aid measures

General advice

Take care of your own personal safety.

Remove victims from hazardous area.

Take off all contaminated clothing immediately.

Keep patient warm and at rest.

Do not leave victims unattended.

Inhalation

Move victims into fresh air.

Place person on side in stable position if unconscious until medical assistance arrives or the patient can be transported to a medical facility for treatment and evaluation.

In case of difficulties in breathing, supply oxygen.

Employ artificial respiration if breathing ceases.

Consult a physician immediately.

Skin contact

In the event of frostbite, rinse copiously with water.

Do not remove clothing that adheres due to freezing.

Cover with sterile dressing and seek medical advice.

Eye contact

Flush affected eye immediately with water at ambient temperature.

Do not force eyelids open.

Consult an ophthalmologist.

Ingestion

Ingestion by swallowing is not considered a possible mode of exposure.

Notes to physician

Oxygen-displacing gas.

No specific antidote known.

cardio-vascular monitoring.

Symptomatic treatment.

Fire-fighting measures

Suitable extinguishing media

CO2, dry powder

Extinguishing media which must not be used for safety reasons

high volume water jet

Specific hazards during fire fighting

Closed container may rupture if strongly heated.

In case of fire cool endangered containers with water.

Heavier than air vapour.

Formation of flammable or explosive vapour/air mixtures possible.

Keep all ignition sources out of area

Special protective equipment for fire-fighters

wear a self contained respiratory apparatus

full protective suit, if necessary

Accidental release measures

Personal precautions

Wear personal protective equipment; see section 8.

Avoid contact with skin and eyes.

Do not inhale vapours / aerosols.

Leave room immediately.

Heavier than air vapour.

Ensure adequate ventilation.

Ensure good room ventilation at floor level too.

Keep away from sources of ignition - No smoking.

Environmental precautions

Do not allow entrance in sewage water, drainage systems, stretches of water, soil.

Avoid penetration into drainage system or in rooms situated at a lower level because of danger of explosion.

Methods for cleaning up

taking special safety precautions

Confine and allow to evaporate.

Handling and storage

Handling

Safe handling advice

Wear personal protective equipment; see section 8.

Avoid contact with skin and eyes.

Do not inhale vapours / aerosols.

Provide good ventilation or extraction.

Ensure good room ventilation at floor level too.

Priority should be given to closed-system units.

Observe special instructions applicable to compressed gases.

Advice on protection against fire and explosion

Take precautionary measures against static charges, keep away from sources of ignition.

Explosion protection equipment required.

Temperature class

T 2

Storage

Requirements for storage areas and containers

Keep containers tightly closed in a cool, well-ventilated place.

With exclusion of air/oxygen

Suitable materials       stainless steel, Unalloyed steel

Unsuitable materials       aluminium, copper and their alloys

Advice on common storage

Observe prohibition against storing together!

Storage stability

< 50 °C  

Recommended storage temperature

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
1010
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
1010
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Marine transport (UN RTDG/IMDG)

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Air transport (UN RTDG/ICAO/IATA)

UN number:
1010
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Exposure controls / personal protection

Engineering measures

If contact with gases or vapours cannot be excluded: Provide good ventilation or extraction.

Priority should be given to closed-system units.

Occupational exposure controls

Further information

ACGIH (American Conference of Governmental Industry Hygienists)

Personal protective equipment

Respiratory protection

In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:

If concentrations in the breathed air are low:

Respirator with brown AX-type filter

Put on Respiratory protective equipment independent of surrounding air with high gas/vapour concentrations.

Hand protection

Chemical-resistant protective gloves (EN 374)

Glove material       suitable protective gloves e.g. nitrile-butadiene rubber (NBR) gloves, heat insulating

Selection of protective gloves to meet the requirements of specific workplaces.

Suitability for specific workplaces should be clarified with protective glove manufacturers.

The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.

Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).

Eye protection

close-fitting protective goggles (e.g. closed goggles) or face protection

Skin and body protection

Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.

Hygiene measures

Do not inhale vapours / aerosols.

Remove contaminated or saturated clothing.

Smoking, eating and drinking should be prohibited in the application area.

Wash face and/or hands before break and end of work.

Use barrier cream regularly.

Protective measures

Wear suitable protective clothing.

full protective suit, if necessary

Stability and reactivity

Conditions to avoid

Keep away from heat and sources of ignition.

Materials to avoid

strong oxidizing agents, oxygen

Hazardous decomposition products

not known

Thermal decomposition

Explosive decomposition caused by external ignition sources at temperatures of above 70'C and a pressure of more than 7 bar.

Hazardous reactions

Formation of flammable or explosive vapour/air mixtures possible.

Disposal considerations

With respect to local regulations, e.g. incineration via flare system.

No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.

The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.

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