Tetrakis(triphenylphosphine)palladium

Guidance on Safe Use

First-aid measures

4.1 Description of first aid measures

General advice : Do not leave the victim unattended.If inhaled : If unconscious, place in recovery position and get medical

attention immediately.

In case of eye contact : Remove contact lenses.

Protect unharmed eye.

If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear.

Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person.

If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

None known.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment : No information available.

Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media : Water mist

Water spray jet

Foam

Carbon dioxide (CO2)

Dry chemical

Unsuitable extinguishing

media

: High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water

courses.

Hazardous combustion products

: Carbon oxides

Metal oxides

5.3 Advice for firefighters

Special protective equipment

for firefighters

: No special protective equipment required.

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must

be disposed of in accordance with local regulations.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Avoid dust formation.

6.2 Environmental precautions

Environmental precautions : Prevent product from entering drains.

If the product contaminates rivers and lakes or drains inform

respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Pick up and arrange disposal without creating dust.

Sweep up and shovel.

6.4 Reference to other sections

For personal protection see section 8., For disposal considerations see section 13.

Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the application area.

Advice on protection against

fire and explosion

: Provide appropriate exhaust ventilation at places where dust

is formed.

Hygiene measures : General industrial hygiene practice. Wash hands before

breaks and at the end of workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage

areas and containers

: Containers which are opened must be carefully resealed and

kept upright to prevent leakage. Electrical installations / working materials must comply with the technological safety standards.

Storage class (TRGS 510) : 13, Non Combustible Solids

Further information on storage stability

: Keep in a dry place. No decomposition if stored and applied

as directed.

7.3 Specific end use(s)

Specific use(s) : No data available

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

8.1 Control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Engineering measures

Handle only in a place equipped with local exhaust (or other appropriate exhaust).

Personal protective equipment

Eye protection : Wear safety glasses with side shields or goggles.

Hand protection

Material : Nitrile rubber

Break through time : 240 min

Glove thickness : 0,38 mm

Manufacturer : Mapa

Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Respiratory protection : ABEK-P3-filter

Filter type : Combined particulates, inorganic and acidic gas/vapour,

ammonia/amines and organic vapour type (ABEK-P)

In case of inadequate ventilation wear respiratory protection.

Stability and reactivity

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability

No decomposition if stored and applied as directed.

10.3 Possibility of hazardous reactions

Hazardous reactions : Stable under recommended storage conditions.

Dust may form explosive mixture in air.

10.4 Conditions to avoid

Conditions to avoid : None known.

10.5 Incompatible materials

Materials to avoid : None known.

10.6 Hazardous decomposition products

No data available

Disposal considerations

13.1 Waste treatment methods

Product : Dispose of in accordance with the European Directives on

waste and hazardous waste.According to the European Waste Catalogue, Waste Codes

are not product specific, but application specific.

Waste codes should be assigned by the user, preferably in

discussion with the waste disposal authorities.

The product should not be allowed to enter drains, water

courses or the soil.

Contaminated packaging : Dispose of contaminated packaging as if unused product.