Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

Description of necessary first-aid measures
General advice : Show the safety data sheet to the doctor in attendance.
First aider needs to protect himself.
Place affected clothing in a sealed bag for subsequent decontamination.
Plan first aid action before beginning work with this product.

Inhalation : Remove person to fresh air. If signs/symptoms continue, get medical attention.

Skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and water.
Wash immediately and thoroughly for a prolonged period (at least 15 minutes).
Call a physician if irritation develops or persists.

Eye contact : Rinse with running water whilst keeping the eyes wide open (at least 15
minutes)
If eye irritation persists, consult a specialist.

Ingestion : Do NOT induce vomiting.
Rinse mouth with water.
Consult a physician if necessary.

Most important symptoms and effects, both acute and delayed
Symptoms : Redness
Itching

Fire-fighting measures

Extinguishing media
Suitable extinguishing media : In case of fire, use water/water spray/water jet/carbon dioxide/sand/foam/alcohol resistant foam/chemical powder for extinction.

Unsuitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Special hazards arising from the substance or mixture
Specific hazards during firefighting : Harmful or toxic vapours are released.
For further information, refer to section 10 of the safety data sheet: "Stability and Reactivity".

Advice for firefighters
Special protective equipment for firefighters : Self-contained breathing apparatus (EN 133)
Full protective suit

Specific fire fighting methods : Standard procedure for chemical fires.
Contain the extinguishing fluids by bunding (the product is hazardous for the environment).
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Avoid contact with the skin and the eyes.
Use personal protective equipment.
For further information refer to section "Exposure controls/personal protection".
If spillage occurs on the public highway, indicate the danger and notify the authorities (police, fire brigade).

Environmental precautions : Do not allow uncontrolled discharge of product into the environment.
Contain the spilled material by bunding.

Methods for Cleaning or Taking Up
Recovery : Keep in properly labelled containers.
Keep in suitable, closed containers for disposal.

Decontamination/cleaning : Wash off with plenty of water.

Disposal : Dispose of contents/ container to an approved waste disposal plant.

Handling and storage

Handling
Technical measures : Avoid dust formation.

Advice on safe handling and usage : Provide adequate ventilation.
Do NOT handle without gloves.
Handle in accordance with good industrial hygiene and safety practice.

Storage
Storage conditions
Recommended : Keep in a dry, cool place.

Packaging Measures
Packaging Measures : Polyethylene or polypropylene drums.
Packaging materials - Recommended : Plastic materials (polyethylene).

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
Not regulated for transport.
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Inland waterway transport (UN RTDG/ADN(R))

UN number:
Not regulated for transport.
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Marine transport (UN RTDG/IMDG)

UN number:
Not regulated for transport.
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Air transport (UN RTDG/ICAO/IATA)

UN number:
Not regulated for transport.
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Exposure controls / personal protection

Control measures
Engineering measures : Facilities and equipment easily cleanable.
Provide adequate ventilation.
Dust must be extracted directly at the point of origin.

Personal protective equipment
Respiratory protection : Use a respirator with an approved filter if a risk assessment indicates this is
necessary.

Hand protection : The selected protective gloves have to satisfy the specifications of EU
Directive 89/686/EEC and the standard EN 374 derived from it.
Where there is a risk of contact with hands, use appropriate gloves
Please observe the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into consideration
the specific local conditions under which the product is used, such as the
danger of cuts, abrasion, and the contact time.
Gloves must be inspected prior to use.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
Glove material: PVC

Eye protection : Safety glasses with side-shields

Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Remove and wash contaminated clothing.
Protective suit
Safety shoes

Hygiene measures : Emergency equipment immediately accessible, with instructions for use.
Ensure that eyewash stations and safety showers are close to the workstation location.
Regular cleaning of equipment, work area and clothing.
Use clean, well-maintained personal protection equipment.
Store personal protection equipment in a clean location away from the work area.
Keep working clothes separately.
Contaminated work clothing should not be allowed out of the workplace.
Wash hands before breaks and immediately after handling the product.
Shower or bathe at the end of working.
When using do not eat, drink or smoke.

Protective measures : The protective equipment must be selected in accordance with current CEN standards and in cooperation with the supplier of the protective equipment.
Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the potential hazards and/or risks that may occur during use.

General advice : Do not allow uncontrolled discharge of product into the environment.
Contain the spilled material by bunding.

Stability and reactivity

Chemical stability : Stable under normal conditions.

Hazardous reactions
Conditions to avoid : Thermal decomposition > 367 °C

Materials to avoid : No dangerous reaction known with common products.

Decomposition products : Oxides of phosphorus
(Carbon oxides (CO + CO2)).

Disposal considerations

Product Disposal
Prohibition : Do not empty into drains.

Advice on Disposal : Dispose of as hazardous waste in compliance with local and national regulations.
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.

Advice on cleaning and disposal of packaging
Advice : Completely empty the packaging prior to decontamination.

Other data : Dispose of in accordance with local regulations.

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