Reaction mass of substituted-(naphthalen-1-methyl)heteromonocyclic chloride and propane-1,2-diol

Guidance on Safe Use

First-aid measures

EYE CONTACT

Get medical attention immediately. Immediately flush eyes with plenty of water,

occasionally lifting the upper and lower eyelids. Check for and remove any contact

lenses. Continue to rinse for at least 15 minutes. Chemical burns must be treated

promptly by a physician.

INHALATION

Get medical attention immediately. Remove victim to fresh air and keep at rest in a

position comfortable for breathing. If it is suspected that vapours/mists are still present, the

rescuer should wear an appropriate mask or self-contained breathing apparatus. If

not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial

respiration or oxygen by trained personnel. It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery

position and get medical attention immediately. Maintain an open airway. Loosen

tight clothing such as a collar, tie, belt or waistband.

SKIN CONTACT

Flush contaminated skin with plenty of water. Remove contaminated clothing and

shoes. Wash contaminated clothing before reusing. Continue to rinse for at least 15

minutes. Chemical burns must be treated promptly by a physician. Clean shoes

thoroughly before reuse. Get medical attention immediately.

INGESTION

Get medical attention immediately. Wash out mouth with water. Remove dentures if

any. Remove victim to fresh air and keep at rest in a position comfortable for

breathing. Do not induce vomiting unless directed to do so by medical personnel. If

vomiting occurs, the head should be kept low so that vomit does not enter the lungs.

Chemical burns must be treated promptly by a physician. Never give anything by

mouth to an unconscious person. If unconscious, place in recovery position and get

medical attention immediately. Maintain an open airway. Loosen tight clothing such

as a collar, tie, belt or waistband.

PROTECTION OF FIRST AIDERS

No action shall be taken involving any personal risk or without suitable training. If it

is suspected that vapours/mists are still present, the rescuer should wear an appropriate

mask or self-contained breathing apparatus. It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing

thoroughly with water before removing it, or wear gloves.

Fire-fighting measures

SUITABLE  EXTINGUISHING MEDIA

Use dry chemical, CO2, water spray (fog) or foam.

UNSUITABLE  EXTINGUISHING MEDIA

Do not use water jet.

HAZARDS FROM SUBSTANCE

Low Fire Hazard; liquids may burn upon heating to temperatures at or above the flash point.

HAZARDOUS COMBUSTION PRODUCTS

Decomposition products may include the following materials: Carbon monoxide, Carbon dioxide and Oxides of Nitrogen

SPECIAL PRECAUTIONS FOR FIREFIGHTERS

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool. Fire-fighters should wear proper protective equipment.

Accidental release measures

NON-EMERGENCY PERSONNEL

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilt material.

No flares, smoking or flames in hazard area. Do not breathe vapour or mist.

Provide adequate ventilation. Wear appropriate respirator when ventilation is

inadequate. Put on appropriate personal protective equipment.

EMERGENCY RESPONDERS

If specialised clothing is required to deal with the spillage, take note of any

information in the exposure control section on suitable and unsuitable materials.

ENVIRONMENTAL PRECAUTIONS

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

SMALL SPILL CLEAN-UP MEASURES

Dilute with plenty of water. Absorb with an inert material and place in an appropriate

waste disposal container. Do not absorb in sawdust or other combustible material.

Use spark-proof tools and explosion-proof equipment.

LARGE SPILL CLEAN-UP MEASURES

Prevent entry into sewers, water courses, basements or confined areas. Contain

and collect spillage with non-combustible, absorbent material e.g. sand, earth,

vermiculite or diatomaceous earth and place in container for disposal according to

local regulations.

Handling and storage

GENERAL ADVICE

Eating, drinking and smoking should be prohibited in areas where this substance is

handled, stored and processed. Workers should wash hands and face before

eating, drinking and smoking. Remove contaminated clothing and protective

equipment before entering eating areas.

PROTECTIVE MEASURES

Put on appropriate personal protective equipment. Do not get in

eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Use only

with adequate ventilation. Wear appropriate respirator when ventilation is

inadequate. Do not enter storage areas and confined spaces unless adequately

ventilated. Keep in the original container, kept tightly closed when not in use.  

Empty containers retain product residue and can be hazardous. Do not reuse container.

STORAGE CONDITIONS

Store in original container protected from direct sunlight in a dry, cool and well-ventilated

area, away from incompatible materials and food and drink.

Separate from oxidizing materials and acids. Keep container tightly closed and sealed until ready for use.

Containers that have been opened must be carefully resealed and kept upright to prevent leakage.

Do not store in unlabelled containers. Use appropriate containment to avoid environmental

contamination.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

Chemical name:

Reaction mass of substituted-(naphthalen-1-methyl)heteromonocyclic chloride and propane-1,2-diol

Language:

English

Labels:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

Chemical name:

Reaction mass of substituted-(naphthalen-1-methyl)heteromonocyclic chloride and propane-1,2-diol

Language:

English

Labels:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

Chemical name:

Reaction mass of substituted-(naphthalen-1-methyl)heteromonocyclic chloride and propane-1,2-diol

Labels:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

Chemical name:

Reaction mass of substituted-(naphthalen-1-methyl)heteromonocyclic chloride and propane-1,2-diol

Labels:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S

Remarks

SpecialProvisions

Exposure controls / personal protection

TECHNICAL PROTECTION MEASURES

Use only with adequate ventilation. Use process enclosures, local exhaust

ventilation or other engineering controls to keep worker exposure to airborne

contaminants below any recommended or statutory limits.

Ensure that eyewash stations and safety showers are close to the workstation location.

ORGANISATIONAL PROTECTION MEASURES

Wash hands, forearms and face thoroughly after handling the substance, before

eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing.

HAND PROTECTION

When handling this substance,  use chemical gauntlet gloves.

The choice of work glove depends on work conditions, use PVC for light handling conditions.

The applicable European standard can be found in EN 374.

BODY PROTECTION

When handling this substance,  use a chemical resistant suit and rubber boots.

The applicable European standard can be found in EN ISO 20345.

EYE PROTECTION

Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.

RESPIRATORY PROTECTION

A respirator is not needed under normal and intended conditions of substance use.

ENVIRONMENTAL PROTECTION MEASURES

Emissions from ventilation or work process equipment should be checked to ensure

they comply with the requirements of environmental protection legislation. In some

cases, fume scrubbers, filters or engineering modifications to the process

equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

INCOMPATIBLE CONDITIONS

Stable under normal conditions. avoid extremes of temperatUre

INCOMPATIBLE MATERIALS

Contact with strong oxidisers.

HAZARDOUS DECOMPOSITION PRODUCTS

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Disposal considerations

METHODS OF DISPOSAL

The generation of waste should be avoided or minimised wherever possible. Empty

containers or liners may retain some product residues. This material and its

container must be disposed of in a safe way. Significant quantities of waste substance

residues should not be disposed of via the foul sewer but processed in a suitable

effluent treatment plant. Dispose of surplus and non-recyclable products via a

licensed waste disposal contractor. Disposal of this substance.

Avoid dispersal of spilt material and runoff and contact with soil,

waterways, drains and sewers.

HAZARDOUS WASTE

Yes, European waste packaging code: 16 09 03

PACKAGING DISPOSAL

The generation of waste should be avoided or minimised wherever possible. Waste

packaging should be recycled. This material and its container must be disposed of in a safe way. Care should be

taken when handling emptied containers that have not been cleaned or rinsed out.

Empty containers or liners may retain some product residues. Avoid dispersal of

spilt material and runoff and contact with soil, waterways, drains and sewers.