Registration Dossier

Administrative data

First-aid measures

DESCRIPTION OF FIRST AID MEASURES
If inhaled:
- Move to fresh air in case of accidental inhalation of fumes from overheating or combustion.
- Oxygen or artificial respiration if needed.
In case of eye contact:
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- If eye irritation persists, consult a specialist.
In case of skin contact:
- Wash off with soap and water.
If swallowed:
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- If symptoms persist, call a physician.

MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Inhalation
- Symptoms: Dizziness, narcosis
Skin contact
- May cause skin irritation and/or dermatitis.
Eye contact
- Contact with eyes may cause irritation.
- Redness
Ingestion
- Ingestion may provoke the following symptoms:
- Symptoms: Nausea, Vomiting, Diarrhoea

INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
- None.

Fire-fighting measures

1.Extinguishing media
1.1 Suitable extinguishing media
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
1.2. Unsuitable extinguishing media
- None.

2. Special hazards arising from the substance or mixture
- The product is not flammable.
- Not explosive
- The pressure in sealed containers can increase under the influence of heat.
- Explosive reaction may occur on heating or burning.
- Thermal decomposition can lead to release of toxic and corrosive gases.

3. Advice for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition

Accidental release measures

1. Personal precautions, protective equipment and emergency procedures
1.1. Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
1.2. Advice for emergency responders
- Ensure adequate ventilation.
- Sweep up to prevent slipping hazard.
- Keep away from open flames, hot surfaces and sources of ignition.

2. Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.

3. Methods and materials for containment and cleaning up
- Soak up with inert absorbent material.
- Suitable material for picking up
- Earth
- Dry sand
- Shovel into suitable container for disposal.

Handling and storage

1. Precautions for safe handling
- No special handling advice required.
- Ensure adequate ventilation.
- Use personal protective equipment.
- Keep away from heat and sources of ignition.
- To avoid thermal decomposition, do not overheat.
- Take measures to prevent the build up of electrostatic charge.
- Clean and dry piping circuits and equipment before any operations.
- Ensure all equipment is electrically grounded before beginning transfer operations.

2. Conditions for storage, including incompatibilities
2.1. Storage
- No special storage conditions required.
- Keep in properly labelled containers.
- Keep in a cool, well-ventilated place.
- Keep away from direct sunlight.
- Keep away from heat and sources of ignition.
- Vapours are heavier than air and may spread along floors.
- Keep away from combustible material.
- Keep away from Incompatible products.
- Provide tight electrical equipment well protected against corrosion.
- Refer to protective measures listed in sections 7 and 8.
2.2. Packaging material
2.2.1. Suitable material
- Stainless steel
- Carbon steel
- Warning! Container under pressure.

Transport information

Land transport (UN RTDG/ADR/RID)

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Special provisions / remarks
Remarks:
not regulated

Inland waterway transport (UN RTDG/ADN(R))

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Special provisions / remarks
Remarks:
not regulated

Marine transport (UN RTDG/IMDG)

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Special provisions / remarks
Remarks:
not regulated

Air transport (UN RTDG/ICAO/IATA)

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Special provisions / remarks
Remarks:
not regulated
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Exposure controls / personal protection


1. Respiratory protection
- Use respirator when performing operations involving potential exposure to vapour of the product.
- The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used.
- Remove respiratory and skin/eye protection only after vapours have been cleared from the area.
- Use only respiratory protection that conforms to international/ national standards.
2. Hand protection
- Latex gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
3. Eye protection
- Tightly fitting safety goggles
4. Skin and body protection
- Long sleeved clothing
- Safety shoes
5. Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.

Stability and reactivity

1. Reactivity:
- No dangerous reaction known under conditions of normal use.
2. Chemical stability:
- Stable under recommended storage conditions.
3. Possibility of hazardous reactions:
- No dangerous reaction known under conditions of normal use.
4. Conditions to avoid:
- To avoid thermal decomposition, do not overheat.
- Keep away from flames and sparks.
5. Incompatible materials:
- Oxidizing agents, Do not mix with polymerisation initiators.
6. Hazardous decomposition products:
- Gaseous hydrogen fluoride (HF)., Fluorophosgene, Gaseous hydrogen chloride (HCl)., Carbon monoxide

Disposal considerations

1. Waste treatment methods:
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- In accordance with local and national regulations.
2. Contaminated packaging:
- Purge the container with nitrogen and direct the gas to a treatment plant.
- Empty containers can be landfilled, when in accordance with the local regulations.