Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
Pay attention to self-protection.
Do not leave affected persons unattended.
Take off all contaminated clothing immediately.
Inhalation
See that there is fresh air.
Place patients at risk of losing consciousness in stabilized lateral position; artificial respiration as required
If breathing is irregular or stopped, administer artificial respiration.
Call a physician immediately.
Skin contact
Wash off with plenty of water and soap immediately.
Consult a doctor in the event of permanent skin irritation.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses if this can be easily done.
Protect unharmed eye.
Call a physician immediately.
Ingestion
Only when patient fully conscious:
Flush mouth immediately, then drink plenty of water.
Call a physician immediately.
If a person vomits when lying on his back, place him in the recovery position.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms
Gastrointestinal discomfort
Nausea
headache
Irritation of mucous membranes
Numbness
Local irritation
Hazards
Risk of serious damage to eyes.
4.3. Indication of any immediate medical attention and special treatment needed
Symptomatic treatment.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media:
Water spray
Carbon dioxide (CO2)
Dry powder
Alcohol-resistant foam

Unsuitable extinguishing media:
High volume water jet

5.2. Special hazards arising from the substance or mixture
In case of fire or thermal decomposition production of
carbon monoxide, carbon dioxide
toxic gases/vapours
metal oxides
see section 10.Closed container may rupture if strongly heated.
Cool down container with a water jet from a safe distance.

5.3. Advice for firefighters
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
wear a self contained respiratory apparatus
full protective suit

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protective equipment; see section 8.
Keep out unprotected persons.
Avoid contact with skin, eyes and clothing.
Do not inhale vapours / aerosols.
Assure sufficient ventilation.
Use respiratory apparatus where there are vapour/gas effects.

6.2. Environmental precautions
Do not allow entrance in sewage water, drainage systems, stretches of water, soil.
Prevent spreading over a wide area (e.g. by containment or oil barriers).
Notify responsible authorities in case of gas leakage or if product gets into stretches of water, soil, or drainage systems.

6.3. Methods and material for containment and cleaning up
Assure sufficient ventilation.
Take up mechanically or with a non-combustible absorbent material.
Fill into marked, sealable containers.
To be disposed of in compliance with existing regulations.
see section 13.

Suitable binder: Sand, diatomaceous earth, acid binder, universal absorbent
6.4. Reference to other sections
Wear personal protective equipment; see section 8.
Disposal considerations; see section 13.

Handling and storage

7.1. Precautions for safe handling
Wear personal protective equipment; see section 8.
Avoid contact with skin and eyes.
Avoid breathing vapors/dust/mist.
Keep container tightly closed.
Keep in a dry, cool place.
Protect from sunlight, warmth and heat.
Provide good ventilation or extraction.
Vapors are heavier than air.
Ensure that spaces including floor areas are well ventilated.
Avoid formation of aerosol.

7.2. Conditions for safe storage, including any incompatibilities
Advice on protection against fire and explosion
Vapours can form explosive mixtures with air.
Keep away from sources of ignition - No smoking.
Ensure explosion proofness.
Take measures to prevent the build up of electrostatic charge.
No sparking tools should be used.
Storage
Store in original container.
Keep containers tightly closed in a cool, well-ventilated place.
Protect from water and humidity.
Protect from heat and exposure to direct sunlight
Keep contents under nitrogen.
TRbF (technical regulations flammable liquids)
Further information
Keep contents under nitrogen.
Advice on common storage
Store separately from oxidants
Do not store together with: alkalis.
Keep away from food and drink.
Comply with storage regulations and regulations prohibiting storage of hazardous substances in non-stationary containers in the same room (TRGS 510).

German storage class
3 - Flammable liquids

7.3. Specific end use(s)
We are unaware of any specific end uses which go beyond the data reported in Section 1.

Transport information

Land transport (ADR/RID)

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.(titanium tetraisobutanolate)
Chemical name:
titanium tetraisobutanolate
Language:
English
Class:
3
Packaging group:
III
Special Provisions:
Yes
Remarks:
Special precautions for user:
ADR: Tunnel Restriction Code: (D/E)
ADR: Special provision 640E
RID: Special provision 640E

Inland waterway transport (ADN(R))

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.(titanium tetraisobutanolate)
Chemical name:
titanium tetraisobutanolate
Language:
English
Class:
3
Packaging group:
III
Remarks
Special precautions for user: Yes
Special provision 640E

Marine transport (IMDG)

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.(titanium tetraisobutanolate)
Chemical name:
titanium tetraisobutanolate
Class:
3
Packaging group:
III
EmS code:
F-E, S-E
Remarks
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code:
for transportapproval see regulatory information

Air transport ICAO/IATA

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.(titanium tetraisobutanolate)
Chemical name:
titanium tetraisobutanolate
Class:
3
Packaging group:
III
Remarks
Special precautions for user: Yes
IATA-C: ERG-Code 3L
Maximum Net Quantity per Package 220 L
IATA-P: ERG-Code 3L
Maximum Net Quantity per Package 60 L
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters
see section 8.2.
8.2. Exposure controls
Engineering measures
Provide good ventilation or extraction.
Provide washing facilities in the workplace.
Provide for installation of emergency shower and eye bath.
see also section 7.
Personal protective equipment
Respiratory protection
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:
use respiratory equipment with suitable filter (combined filter A-P2) or wear a self contained respiratory apparatus
Hand protection
Chemical-resistant protective gloves (EN 374)
for example
Glove material Nitrile rubber
Material thickness >= 0.4 mm
Break through time > 8 h
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.
Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).
Eye protection
close-fitting protective goggles (e.g. closed goggles) or face protection
Skin and body protection
Wear suitable protective clothing.
Select materials and equipment for physical protection depending on the concentration and volume of hazardous substances and the workplace involved.
Hygiene measures
Remove immediately all contaminated clothing.
Wash contaminated clothing before re-use.
Avoid contact with the skin and the eyes.
Do not inhale vapours / aerosols.
Wash face and/or hands before break and end of work.
Do not eat, drink or smoke during use.
Keep away from food, drink and animal feedingstuffs.
Environmental exposure controls
Emissions from venting and processing equipment should be checked in order to ensure that the requirements of the Environmental Protection Law are satisfied.
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.
See sections 6 and 7.

Stability and reactivity

10.1. Reactivity
no data available
10.2. Chemical stability
no data available
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions Reacts with:
oxidizing agents
alkalis
water
humidity

When heated above flashpoint and/or with spraying or atomization, a flammable mixture may form with air.

10.4. Conditions to avoid
To avoid thermal decomposition, do not overheat.
Protect from moisture.10.5. Incompatible materials
Oxidizing agents, alkalis, water, humidity10.6. Hazardous decomposition products
Decomposition products on contact with water/air humidity
decomposition products In the case of fire
carbon monoxide, carbon dioxide
toxic gases/vapours
metal oxides

Disposal considerations

13.1. Waste treatment methods
Product
Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility.
Uncleaned packaging
Contaminated packages must be emptied as good as possible. They may then be recycled after proper cleaning. Packages that cannot be cleaned must be disposed of in the same way as the substance. Uncontaminated packaging may be taken for recycling.
Code of waste EWC
07 01 08
waste from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.